In this work,two aza-BODIPY derivatives,3,5-diphenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(CJF)and 3,5-di(p-bromophenyl)-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(2Br-CJF)acted as model molecules to form the self-assembly...In this work,two aza-BODIPY derivatives,3,5-diphenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(CJF)and 3,5-di(p-bromophenyl)-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(2Br-CJF)acted as model molecules to form the self-assembly monolayers on the solid-liquid interface.With the utilizing of scanning tunnelling microscope(STM),we demonstrated that intermolecular Br…F-BF interactions existed in 2Br-CJF self-assembly structure and played an important role in strengthening the stability of 2Br-CJF self-assembly structure.This result is supported by density functional theory(DFT)calculation.展开更多
基金financially supported by the National Basic Research Program of China(No.2016YFA0200700)the National Natural Science Foundation of China(Nos.21773041,21972031)+3 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB36000000)the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal UniversityNational Science Foundation of Zhejiang Province of China(No.Y20B020032)Project of Ningbo Science and Technology Innovation 2025.
文摘In this work,two aza-BODIPY derivatives,3,5-diphenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(CJF)and 3,5-di(p-bromophenyl)-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(2Br-CJF)acted as model molecules to form the self-assembly monolayers on the solid-liquid interface.With the utilizing of scanning tunnelling microscope(STM),we demonstrated that intermolecular Br…F-BF interactions existed in 2Br-CJF self-assembly structure and played an important role in strengthening the stability of 2Br-CJF self-assembly structure.This result is supported by density functional theory(DFT)calculation.
