Theories based on the isotropic Heisenberg model have been adjusted to the study of magnetic properties in exchange coupled unsymmetrical trinuclear complexes.Program for theoretical fitting of the variable-temperatur...Theories based on the isotropic Heisenberg model have been adjusted to the study of magnetic properties in exchange coupled unsymmetrical trinuclear complexes.Program for theoretical fitting of the variable-temperature magnetic susceptibility has been set up to produce coupling constants and spin states of the magnetic centers.Calculation has been carried out on a series of Co(Ⅱ)complexes containing mixed thiolato and phosphine ligands:Co3(mp)2(mpH)2(PR3)3(R=Et,R=Bu) and Co3(bdt)3 (PBu3)3.It has been found that all these studied complexes are anti-ferromagnetically coupled.Coupling constant shows the strength of the exchange interaction,which is determined by many factors.Relation between the spin state and the coordination circumstance of Co(Ⅱ) was discussed too.展开更多
文摘Theories based on the isotropic Heisenberg model have been adjusted to the study of magnetic properties in exchange coupled unsymmetrical trinuclear complexes.Program for theoretical fitting of the variable-temperature magnetic susceptibility has been set up to produce coupling constants and spin states of the magnetic centers.Calculation has been carried out on a series of Co(Ⅱ)complexes containing mixed thiolato and phosphine ligands:Co3(mp)2(mpH)2(PR3)3(R=Et,R=Bu) and Co3(bdt)3 (PBu3)3.It has been found that all these studied complexes are anti-ferromagnetically coupled.Coupling constant shows the strength of the exchange interaction,which is determined by many factors.Relation between the spin state and the coordination circumstance of Co(Ⅱ) was discussed too.