The specific heat of the nanostructured crystals, the glass, the liquid and the crystals for a ZrAlNiCuCo alloy has been measured by using the differential scanning calorimeter. The specific heat value and its tempera...The specific heat of the nanostructured crystals, the glass, the liquid and the crystals for a ZrAlNiCuCo alloy has been measured by using the differential scanning calorimeter. The specific heat value and its temperature coefficient of the nanostructured crystals are larger than that of the relaxed glass and of the crystals. Through measuring crystallization enthalpies and specific heat of the alloy in different states, the enthalpy differences among the crystals, the liquid and the nanostructured crystals are calculated and the interface energies of nanostructured crystals are estimated. The stability and the grain size limit of the nanostructured crystals are discussed.展开更多
The crystal structure of the compound EDA Ni(dmit) 2 3 (EDA=2 diethylamino 1,3 dithioanylium; dmit=1,3 dithiole 2 thione 4,5 dithiolate)C 25 H 14 NNi 3S 32 , has been determined by single...The crystal structure of the compound EDA Ni(dmit) 2 3 (EDA=2 diethylamino 1,3 dithioanylium; dmit=1,3 dithiole 2 thione 4,5 dithiolate)C 25 H 14 NNi 3S 32 , has been determined by single crystal X ray diffraction at 300K. The crystal is triclinic with space group P1, a=11.252, b=12.192(2), c=20.055(6) , α=108.127(2), β=106.287(8), γ=90.005(9)°; V=2498.3(3) 3, Z=2, M r=1530.38, D c =2.03(2) g/cm 3. Final R and R w values were 0.0603 and 0.0704, respectively. The structure consists of thick layers of stacked Ni(dmit) 2 entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm -1 and activation energy of 0.11 eV.展开更多
The random closed packing fraction of hard balls of three different sizes were measured by use of the Archimedes method. This packing fraction increases as the kind of balls with different sizes increases. The packing...The random closed packing fraction of hard balls of three different sizes were measured by use of the Archimedes method. This packing fraction increases as the kind of balls with different sizes increases. The packing fraction is related to the mixing entropy of an ideal solution in respect to the holes among the hard balls. The composition zone of La-Al-Ni amorphous alloy made by cooling the alloy melt with a cooling rate of 90 Ks(-1) is located at same zone of the largest values of packing fraction and mixing entropy of hard balls in the ternary system, where the proportion of atom sizes of La, Al and Ni is similar to that of hard balls. The packing fraction and the mixing entropy are qualitatively considered as one of the criteria of the glass forming ability of alloys.展开更多
文摘The specific heat of the nanostructured crystals, the glass, the liquid and the crystals for a ZrAlNiCuCo alloy has been measured by using the differential scanning calorimeter. The specific heat value and its temperature coefficient of the nanostructured crystals are larger than that of the relaxed glass and of the crystals. Through measuring crystallization enthalpies and specific heat of the alloy in different states, the enthalpy differences among the crystals, the liquid and the nanostructured crystals are calculated and the interface energies of nanostructured crystals are estimated. The stability and the grain size limit of the nanostructured crystals are discussed.
文摘The crystal structure of the compound EDA Ni(dmit) 2 3 (EDA=2 diethylamino 1,3 dithioanylium; dmit=1,3 dithiole 2 thione 4,5 dithiolate)C 25 H 14 NNi 3S 32 , has been determined by single crystal X ray diffraction at 300K. The crystal is triclinic with space group P1, a=11.252, b=12.192(2), c=20.055(6) , α=108.127(2), β=106.287(8), γ=90.005(9)°; V=2498.3(3) 3, Z=2, M r=1530.38, D c =2.03(2) g/cm 3. Final R and R w values were 0.0603 and 0.0704, respectively. The structure consists of thick layers of stacked Ni(dmit) 2 entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm -1 and activation energy of 0.11 eV.
文摘The random closed packing fraction of hard balls of three different sizes were measured by use of the Archimedes method. This packing fraction increases as the kind of balls with different sizes increases. The packing fraction is related to the mixing entropy of an ideal solution in respect to the holes among the hard balls. The composition zone of La-Al-Ni amorphous alloy made by cooling the alloy melt with a cooling rate of 90 Ks(-1) is located at same zone of the largest values of packing fraction and mixing entropy of hard balls in the ternary system, where the proportion of atom sizes of La, Al and Ni is similar to that of hard balls. The packing fraction and the mixing entropy are qualitatively considered as one of the criteria of the glass forming ability of alloys.
