The thermolysis of (EtO)_2P(O)SCF_3 was measured by ^(31)P-NMR with external standard method. Kinetic parameters of the reaction, i.e., order, rate constant, pre-exponential, activation energy were obtained. For const...The thermolysis of (EtO)_2P(O)SCF_3 was measured by ^(31)P-NMR with external standard method. Kinetic parameters of the reaction, i.e., order, rate constant, pre-exponential, activation energy were obtained. For constant external-standard method, It is better to choose the value of ^(31)P peak area of standard substance slightly greater than the middle value of the area of the measured compounds.展开更多
文摘The thermolysis of (EtO)_2P(O)SCF_3 was measured by ^(31)P-NMR with external standard method. Kinetic parameters of the reaction, i.e., order, rate constant, pre-exponential, activation energy were obtained. For constant external-standard method, It is better to choose the value of ^(31)P peak area of standard substance slightly greater than the middle value of the area of the measured compounds.
