The 800℃ isothermal section in the Al-Zn-Zr system was investigated using the equilibrated alloy method and the solid/liquid diffusion couple approach by means of scanning electron microscopy equipped with energy dis...The 800℃ isothermal section in the Al-Zn-Zr system was investigated using the equilibrated alloy method and the solid/liquid diffusion couple approach by means of scanning electron microscopy equipped with energy dispersive spectroscopy, X-ray powder diffraction and electron probe microanalysis. Thirteen three-phase regions are experimentally confirmed in the ternary system. A ternary compound Zn50Al25Zr25 named as T phase exists stably in the 800℃ isothermal section. Its composition range varies widely (16.84-55.1 at.% Zn, 18.02-56.3 at.% Al and 26.0-28.53 at.% Zr), and it can be in equilibrium with all the binary compounds. The maximum solubilities of Zn in Zr3Al, Zr2Al, Zr3Al2, Zr4Al3, ZrAl, Zr2Al3, ZrAl2 and ZrAl3 are 7.5, 0.84, 0.33, 0.89, 0.91, 1.12, 0.64 and 3.8 at.%, respectively. The maximum solubilities of Al in Zn3Zr, Zn2Zr and ZnZr are 1.6, 1.3 and 13.6 at.%, respectively.展开更多
To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energ...To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energy-dispersive spectrometry,X-ray diffractometry and electron probe microanalysis.Experimental results show that there are six three-phase regions on the Co-Mo-Zn isothermal section at 600℃and nine three-phase regions on the Co-Mo-Zn isothermal section at 450℃.No ternary compound is found in these two isothermal sections.Both the maximum solubilities of Mo in the Co-Zn compounds(γ-Co5 Zn21,γ1-Co Zn7,γ2-Co Zn13 andβ1-Co Zn)and that of Zn inε-Co3 Mo are no more than 1.5 at.%.The maximum solubilities of Zn inμ-Co7 Mo6 are determined to be 2.1 at.%and 2.7 at.%at 600 and 450℃,respectively.In addition,the maximum solubilities of Co in MoZn7 and MoZn22 are 0.5 at.%and 4.7 at.%at 450℃,respectively.展开更多
基金Projects(51771160,51471140)supported by the National Natural Science Foundation of China
文摘The 800℃ isothermal section in the Al-Zn-Zr system was investigated using the equilibrated alloy method and the solid/liquid diffusion couple approach by means of scanning electron microscopy equipped with energy dispersive spectroscopy, X-ray powder diffraction and electron probe microanalysis. Thirteen three-phase regions are experimentally confirmed in the ternary system. A ternary compound Zn50Al25Zr25 named as T phase exists stably in the 800℃ isothermal section. Its composition range varies widely (16.84-55.1 at.% Zn, 18.02-56.3 at.% Al and 26.0-28.53 at.% Zr), and it can be in equilibrium with all the binary compounds. The maximum solubilities of Zn in Zr3Al, Zr2Al, Zr3Al2, Zr4Al3, ZrAl, Zr2Al3, ZrAl2 and ZrAl3 are 7.5, 0.84, 0.33, 0.89, 0.91, 1.12, 0.64 and 3.8 at.%, respectively. The maximum solubilities of Al in Zn3Zr, Zn2Zr and ZnZr are 1.6, 1.3 and 13.6 at.%, respectively.
基金Project(51771160)supported by the National Natural Science Foundation of ChinaProject(2018JJ4057)supported by the Scientific Research Fund of Hunan Provincial Science and Technology Department,China
文摘To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energy-dispersive spectrometry,X-ray diffractometry and electron probe microanalysis.Experimental results show that there are six three-phase regions on the Co-Mo-Zn isothermal section at 600℃and nine three-phase regions on the Co-Mo-Zn isothermal section at 450℃.No ternary compound is found in these two isothermal sections.Both the maximum solubilities of Mo in the Co-Zn compounds(γ-Co5 Zn21,γ1-Co Zn7,γ2-Co Zn13 andβ1-Co Zn)and that of Zn inε-Co3 Mo are no more than 1.5 at.%.The maximum solubilities of Zn inμ-Co7 Mo6 are determined to be 2.1 at.%and 2.7 at.%at 600 and 450℃,respectively.In addition,the maximum solubilities of Co in MoZn7 and MoZn22 are 0.5 at.%and 4.7 at.%at 450℃,respectively.
