Palladium-catalyzed Mizoroki-Heck reaction is a powerful and efficient method for construction of Csp2–Csp2 bonds.Herein,four palladium complexes(I—IV)with N,O-bidentate ligands(L1—L4)based on N-oxide units from cy...Palladium-catalyzed Mizoroki-Heck reaction is a powerful and efficient method for construction of Csp2–Csp2 bonds.Herein,four palladium complexes(I—IV)with N,O-bidentate ligands(L1—L4)based on N-oxide units from cyclic secondary amines were easily synthesized and successfully applied in Mizoroki-Heck reaction of aryl bromides with electron-deficient olefins.X-ray diffraction analyses indicated the palladium(II)atom of II took the distorted square planar geometry and was four-coordinated by nitrogen and oxygen atoms from two ligands(L2).Two free chloride ions were presented as counter anions in complex II.But the palladium(II)center of IV was coordinated by nitrogen and oxygen atoms from one ligand(L4)as well as two chlorine atoms,which exhibited the nearly square-planar geometry.The study on catalytic properties of palladium complexes revealed that complex II exhibited high activity superior to the other complexes.The coupling reactions of a series of aryl bromides and olefin derivatives proceeded in the presence of 2—5 mol%palladium complex II,giving the desired products in good to excellent yields.The advantages of this method such as good compatibility of functional groups,high yields,and short reaction times made it more attractive for constructing Csp2–Csp2 bonds in the synthesis of functional molecules and materials.展开更多
Four novel palladium（（Ⅱ）） complexes coordinated by phosphorus atoms from both 3,5-disubstituted-1H- 1,2,4-diazaphospholes in monodentate fashion were developed as efficient catalyst for the Mizoroki- Heck reactio...Four novel palladium（（Ⅱ）） complexes coordinated by phosphorus atoms from both 3,5-disubstituted-1H- 1,2,4-diazaphospholes in monodentate fashion were developed as efficient catalyst for the Mizoroki- Heck reaction of aryl halides with electron-deficient olefins. The coupling reaction of awl halide bearig different functional groups with olefin derivatives took place and the corresponding products were isolated in good to excellent yields under optimal conditions. The procedure exhibits good functional group tolerance and wide substrate scope. This Mizoroki-Heck reaction was further achieved using Pd（OAc）2 and 3,5-di-isopropyl-1H-1,2,4-diazaphospholes as combined catalyst, which provide the convenient and alternative method in organic synthesis展开更多
Power battery technology is essential to ensuring the overall performance and safety of electric vehicles.Non-invasive char-acteristic curve analysis(CCA)for lithium-ion batteries is of particular importance.CCA can p...Power battery technology is essential to ensuring the overall performance and safety of electric vehicles.Non-invasive char-acteristic curve analysis(CCA)for lithium-ion batteries is of particular importance.CCA can provide characteristic data for further applications such as state estimation and thermal runaway warning without disassembling the batteries.This paper summarizes the characteristic curves consisting of incremental curve analysis,differential voltage analysis,and differential thermal voltammetry from the perspectives of exploring the aging mechanism of batteries and constructing the data-driven model.The process of quantitative analysis of battery aging mechanism is presented and the steps of constructing data-driven models are induced.Moreover,the recent progress and application of the main features and methodologies are discussed.Finally,the applicability of battery CCA is discussed by converting non-quantifiable battery information into transportable data covering macrostate and micro-reaction information.Combined with the cloud-based battery management platform,the above-mentioned battery characteristic curves could be used as a valuable dataset to upgrade the next-generation battery management system design.展开更多
基金the Natural Science Foundation of Shanxi Province(No.201901D111276)Innovative Program of Graduate Education in Shanxi Province(No.2023KY464)for financial support ofthis work.
文摘Palladium-catalyzed Mizoroki-Heck reaction is a powerful and efficient method for construction of Csp2–Csp2 bonds.Herein,four palladium complexes(I—IV)with N,O-bidentate ligands(L1—L4)based on N-oxide units from cyclic secondary amines were easily synthesized and successfully applied in Mizoroki-Heck reaction of aryl bromides with electron-deficient olefins.X-ray diffraction analyses indicated the palladium(II)atom of II took the distorted square planar geometry and was four-coordinated by nitrogen and oxygen atoms from two ligands(L2).Two free chloride ions were presented as counter anions in complex II.But the palladium(II)center of IV was coordinated by nitrogen and oxygen atoms from one ligand(L4)as well as two chlorine atoms,which exhibited the nearly square-planar geometry.The study on catalytic properties of palladium complexes revealed that complex II exhibited high activity superior to the other complexes.The coupling reactions of a series of aryl bromides and olefin derivatives proceeded in the presence of 2—5 mol%palladium complex II,giving the desired products in good to excellent yields.The advantages of this method such as good compatibility of functional groups,high yields,and short reaction times made it more attractive for constructing Csp2–Csp2 bonds in the synthesis of functional molecules and materials.
基金Financial support from Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No. 2015157)Teaching Reform Project of Shanxi Normal University(No. SD2014JGKT-52)Undergraduate Training Programs for Innovation and Entrepreneurship of Modern College of Arts and Sciences, Shanxi Normal University(No. WL2015CXCY-YJ-26)
文摘Four novel palladium（（Ⅱ）） complexes coordinated by phosphorus atoms from both 3,5-disubstituted-1H- 1,2,4-diazaphospholes in monodentate fashion were developed as efficient catalyst for the Mizoroki- Heck reaction of aryl halides with electron-deficient olefins. The coupling reaction of awl halide bearig different functional groups with olefin derivatives took place and the corresponding products were isolated in good to excellent yields under optimal conditions. The procedure exhibits good functional group tolerance and wide substrate scope. This Mizoroki-Heck reaction was further achieved using Pd（OAc）2 and 3,5-di-isopropyl-1H-1,2,4-diazaphospholes as combined catalyst, which provide the convenient and alternative method in organic synthesis
基金The National Key Research and Development Program of China(2018YFB0104001-01)National Natural Science Foundation of China(No.52102470).
文摘Power battery technology is essential to ensuring the overall performance and safety of electric vehicles.Non-invasive char-acteristic curve analysis(CCA)for lithium-ion batteries is of particular importance.CCA can provide characteristic data for further applications such as state estimation and thermal runaway warning without disassembling the batteries.This paper summarizes the characteristic curves consisting of incremental curve analysis,differential voltage analysis,and differential thermal voltammetry from the perspectives of exploring the aging mechanism of batteries and constructing the data-driven model.The process of quantitative analysis of battery aging mechanism is presented and the steps of constructing data-driven models are induced.Moreover,the recent progress and application of the main features and methodologies are discussed.Finally,the applicability of battery CCA is discussed by converting non-quantifiable battery information into transportable data covering macrostate and micro-reaction information.Combined with the cloud-based battery management platform,the above-mentioned battery characteristic curves could be used as a valuable dataset to upgrade the next-generation battery management system design.
