Organic materials with redox-active centers are regarded as promising candidates for rechargeable batteries in recent years for their light weight, low cost, environmental friendliness and structural diversity [1–4]....Organic materials with redox-active centers are regarded as promising candidates for rechargeable batteries in recent years for their light weight, low cost, environmental friendliness and structural diversity [1–4]. Organic materials, such as conducting polymers (polyacetylene, polypyrrole, polyaniline, etc.)[5], conjugated carbonyl compounds (quinone compounds, imides, etc.)[6–9] and nitroxide radical (N-O.)[10,11] compounds have been attempted as cathode materials in lithium-ion batteries (LIBs).展开更多
Oxocarbons(C_(n)O_(n),n=3,4,5,6,...)are a series of compounds that are only composed of carbonyl groups.The highly electrophilic carbon atoms in C_(n)O_(n)make their poor stability toward H_(2)O,and thus the synthesis...Oxocarbons(C_(n)O_(n),n=3,4,5,6,...)are a series of compounds that are only composed of carbonyl groups.The highly electrophilic carbon atoms in C_(n)O_(n)make their poor stability toward H_(2)O,and thus the synthesis of C_(n)O_(n)is very challenging.Here an oxidation-dehydration method is developed to successfully synthesize C_(4)O_(4)and C_(5)O_(5).The combination of nuclear magnetic resonance(^(13)C NMR,^(1)H NMR),mass spectra,and infrared spectra unambiguously proves the exact chemical structure of C_(4)O_(4)and C_(5)O_(5).When used as a cathode material in lithium-ion batteries(LIBs),C_(5)O_(5)could deliver a high discharge capacity of 698m Ah g-1(corresponding to an energy density of 1,256 Wh kg-1C_(5)O_(5)).Furthermore,ex-situ infrared spectra and density functional theory(DFT)calculations demonstrate that the carbonyl groups are redox active sites during discharge and charge processes.This work paves the way to achieve the synthesis and battery application of oxocarbons.展开更多
基金financially supported by the National Key R&D Program of China(2017YFA0206700)the National Natural Science Foundation of China(grant No.21822506&51671107)+1 种基金the 111 project of B12015the Natural Science Foundation of Tianjin(grant No.19JCJQJC62400)。
文摘Organic materials with redox-active centers are regarded as promising candidates for rechargeable batteries in recent years for their light weight, low cost, environmental friendliness and structural diversity [1–4]. Organic materials, such as conducting polymers (polyacetylene, polypyrrole, polyaniline, etc.)[5], conjugated carbonyl compounds (quinone compounds, imides, etc.)[6–9] and nitroxide radical (N-O.)[10,11] compounds have been attempted as cathode materials in lithium-ion batteries (LIBs).
基金supported by the National Key R&D Program of China(2022YFB2402200)the National Natural Science Foundation of China(21905143,22121005,22020102002,21835004)Frontiers Science Center for New Organic Matter of Nankai University(63181206)。
文摘Oxocarbons(C_(n)O_(n),n=3,4,5,6,...)are a series of compounds that are only composed of carbonyl groups.The highly electrophilic carbon atoms in C_(n)O_(n)make their poor stability toward H_(2)O,and thus the synthesis of C_(n)O_(n)is very challenging.Here an oxidation-dehydration method is developed to successfully synthesize C_(4)O_(4)and C_(5)O_(5).The combination of nuclear magnetic resonance(^(13)C NMR,^(1)H NMR),mass spectra,and infrared spectra unambiguously proves the exact chemical structure of C_(4)O_(4)and C_(5)O_(5).When used as a cathode material in lithium-ion batteries(LIBs),C_(5)O_(5)could deliver a high discharge capacity of 698m Ah g-1(corresponding to an energy density of 1,256 Wh kg-1C_(5)O_(5)).Furthermore,ex-situ infrared spectra and density functional theory(DFT)calculations demonstrate that the carbonyl groups are redox active sites during discharge and charge processes.This work paves the way to achieve the synthesis and battery application of oxocarbons.
