Characteristics of dissolved organic matter in lakes with different eutrophic levels in southeastern Hubei Province,China

Dissolved organic matter(DOM)plays a crucial role in both the carbon cycle and geochemical cycles of other nutrient elements,which is of importance to the management and protection of the aquatic environments.To achieve a more comprehensive understanding the characteristics of DOM in the Changjiang(Yangtze)River basin,water samples from four natural lakes(Xiandao,Baoan,Daye,and Qingshan)in southeastern Hubei Province in China with different eutrophication levels were collected and analyzed.The optical characteristics were analyzed using ultraviolet-visible spectrophotometry and excitation-emission matrix spectroscopy coupled with parallel factor analysis.The results show that:(1)two humic-like components(C1 and C2)and two protein-like substances(C3 and C4)of DOM were identified in all waterbodies;(2)C3 originated primarily from the degradation of microalgae and contributed substantially to humic-like components during transformation.C4 was widely present in the Changjiang River basin and its formation was related to microbial activity,rather than algal blooms or seasons.Influenced by the water mixing,the protein-like components were more likely to be transformed by microorganism,whereas humic-like components were more easily to be photobleached;(3)the concentration of DOM and the fluorescence intensity of humic-like components gradually increased with rising lake eutrophication levels.With respect to protein-like components,only C3 showed changes along the eutrophication gradients;(4)DOM showed a high affinity with permanganate index(COD Mn)and chlorophyll a(chl a)while the relationship was variable with phosphorus.This study helps us systematically understand the DOM characteristics,microbial activities,and pollutant transformation in the Changjiang River basin and provides reference to the ecological restoration of aquatic environments.

Trends in per capita ecological footprint and biocapacity in China 1949-2013

This paper proposes two concepts: the ecological footprint component index(EFCI) and the biocapacity component index(BCCI), based on the ecological footprint(EF) and Shannon entropy approaches. Per capita EFCI and BCCI in China 1949-2013 are analyzed using empirical mode decomposition(EMD). Nonlinear models of per capita EFCI and BCCI in China 1949-2013 are presented and their cycles and predictions from 2014 to 2023 are analyzed. The results over the last 65 years show:(1) EFCI in China has increased constantly with fluctuations, while BCCI has slowly decreased. Their annual change rates are 2.81% and-1.26%, respectively. The increasing EFCI indicates a gradual improvement in China's sustainable development potential; the decreasing BCCI indicates severe environmental and population challenges.(2) The cycles of per capita EFCI have periods of 5.4 and 16.3 years, while cycles of per capita BCCI have periods of 3.6, 13,and 21.7 years. The predictive models indicate that EFCI will first decrease, reaching 0.02725 in2014, and will subsequently increase to 0.03261 in 2021. BCCI will increase, reaching 0.01365 in2014 and 0.01541 in 2022. EFCI and BCCI will reach 0.03037 and 0.01537, respectively, in 2023.Policymakers should ensure that the EFCI and BCCI increase in 2023.