Going beyond both a simple perturbative theory and Hartree-Fock treatment,the Gutzwiller variational scheme is employed to clarify the possibility of electron site-pairing in doped C_(60).It is shown that this pairing...Going beyond both a simple perturbative theory and Hartree-Fock treatment,the Gutzwiller variational scheme is employed to clarify the possibility of electron site-pairing in doped C_(60).It is shown that this pairing can be induced by electron-phonon interaction rather than electron-electron interaction.Our results are supported by EPR experiments.展开更多
1 Results Low-temperature synthetic techniques called "chimie douce" have resulted in major developments in the field of solid state chemistry of transition metal oxides. The systematic study of oxide bronze...1 Results Low-temperature synthetic techniques called "chimie douce" have resulted in major developments in the field of solid state chemistry of transition metal oxides. The systematic study of oxide bronzes in the period 1950-1980 paved the way to further advances in the solid state chemistry of oxides, including the alkali metal intercalation(deintercalation chemistry by soft chemical and/or electrochemical methods. These techniques also gave access to new metastable compounds such as several new f...展开更多
基金Supported by the National Natural Science Foundation of China,and Advanced Material Committee of China.
文摘Going beyond both a simple perturbative theory and Hartree-Fock treatment,the Gutzwiller variational scheme is employed to clarify the possibility of electron site-pairing in doped C_(60).It is shown that this pairing can be induced by electron-phonon interaction rather than electron-electron interaction.Our results are supported by EPR experiments.
文摘1 Results Low-temperature synthetic techniques called "chimie douce" have resulted in major developments in the field of solid state chemistry of transition metal oxides. The systematic study of oxide bronzes in the period 1950-1980 paved the way to further advances in the solid state chemistry of oxides, including the alkali metal intercalation(deintercalation chemistry by soft chemical and/or electrochemical methods. These techniques also gave access to new metastable compounds such as several new f...