室外自然变负温下混凝土早期抗冻性及耐久性试验研究

研究了不同养护工艺对新疆地区冬季室外自然变负温下混凝土早期抗冻性及耐久性的影响。结果表明,室外自然变负温下(平均气温达到-15℃),添加复合抗冻剂的混凝土强度可保持稳定增长,同龄期下强度远高于未加复合抗冻剂的空白试件,并且随着龄期延长此优势更加明显,强度保留率明显提高。受冻前覆膜养护对提高早期抗冻性效果良好,覆膜养护有利于局部环境的温度及湿度保持恒定。

诗意的栖居——王文英校长和她的“百川园”

太仓市高新区第二小学是一座诗意盎然的"百川园"。在这个园子里,精神文化主要表现为"百川竞流,浪花朵朵"的学校教育哲学;行为文化主要表现为管理者、教职工、家长和孩子们主体力量激活后,对学校精神的践行和创造;物质文化主要表现为环境的美丽性、发展性、参与性、相融性。

垃圾焚烧灰熔融重构矿渣对水泥基材料性能的影响

研究了不同掺量下(10%、20%、30%、50%)的垃圾焚烧灰和重构矿渣对水泥基材料性能的影响,并通过扫描电镜(SEM)、X射线衍射(XRD)等测试技术分析了影响机理。研究结果表明:相比于纯水泥,垃圾焚烧灰掺量为50%的水泥基材料终凝时间缩短为75 min,标准稠度用水量增加至28.7%,重构矿渣掺量为50%的水泥基材料终凝时间延长至335 min,标准稠度用水量增加至29.8%。垃圾焚烧灰的活性较低,随着垃圾焚烧灰掺量的增加,水泥砂浆抗压强度先增大后减小,当其掺量为10%时,28 d抗压强度达到最大(51.5 MPa);重构矿渣的活性高于垃圾焚烧灰,在碱性环境的激发下,水化后期重构矿渣发生二次水化反应,生成较多的水化产物,掺重构矿渣的水泥砂浆强度先增大后减小,当重构矿渣掺量为20%时,28 d抗压强度达到最大值48.8 MPa。

Utilization of Red Mud as Raw Material in the Production of Field Road Cement

The total utilization amount of red mud is limited due to its high content of alkali,heavy metals and naturally occurring radioactive element.In order to rationalize the use of red mud,a typical field road cement using dealkalized red mud（content of alkali lower than 1%） as raw material was firstly prepared in this paper.Then,a preliminary research on the radioactivity of the red mud based field road cement has been carried out.For that reason,two samples of raw materials were prepared.One was with ordinary raw materials,as the control group（CG）,the other was with 23 w % red mud,as the experimental group（EG）.The clinkers were acquired by sintering the above two raw materials at 1 400 ℃.Subsequently,the two types of cement prepared by the above two kinds of clinkers were tested by measuring the normal consistency,setting time,mechanical strength and drying shrinkage.Meanwhile,the hydration products of the two types of cement were examined by XRD analysis at the curing age of 6 hours,1,3,7,and 28 days,respectively.The radioactivity of the two kinds of cement clinkers was then measured by gamma-ray spectrometry.The experimental results indicate that the main mineralogical phases components in the EG field road cement clinkers are C3S,C2S,and C4AF,the 28 days flexural and compressive strength of the EG field road cement mortars could be up to 8.45 and 53.2 MPa,respectively.The radioactive measuring results of the EG field road cement show that the value of radium equivalent activity index（Raeq） is 254.8 Bq/Kg-1,which is lower than the upper limit.

非遗视角下民间传说动漫化传承研究与实践

非遗动画作为一种具有创造性的艺术媒介,能给动画的题材和风格带来无限创新。同时,非遗与动画可以相互弥补各自在传播途径与文化内涵方面的不足。文章从动画题材、美术风格、衍生品设计等方面阐述以民间传说为题材创作非遗动画的可行性,以期实现非遗文化与动画产业的互惠共生。

Melting Reconstruction Features and Solidification Mechanism of Heavy Metal-containing Slag

The relationships between microstructure and melting temperature of slag containing different heavy metals （Zn, Cu, Pb and Cr） were studied. Furthermore, the corresponding solidification mechanism and rule of heavy metals were analyzed by microscopic tests during melting and reconstructing process. Based on preliminary results, three conclusions were derived. Firstly, pure slag would begin to melt when the temperature reached 1 180℃; however, Zn did not play any fluxing action. Secondly, upon adding Cu and Pb, the initial melting temperature of slag decreased by 5-8℃ and their fluxing effect was observed. Thirdly, the initial melting temperature and the reaction time for slag decreased by 22℃ and 6 s respectively after adding Cr; the fluxing action was significant under Cr. The results of X-ray diffraction （XRD） and Fourier transform infrared spectroscope （FTIR） analyses showed that the above heavy metals had little influence on the reconstruction of slag. Toxicity characteristic leaching procedure （TCLP） leaching tests showed a good solidification effect of the heavy metals with melting slag, fixation rate of Zn, Cu, Pb and Cr was 36.3%, 24.6%, 9.2% and 93.2%, respectively. The leaching toxicity of the heavy metals met the requirements for environmental emission after solidification treatment.

β-SiAlON Hollow Spheres Prepared from Coal Fly Ash Microspheres

β-SiAION hollow spheres were prepared by carbothermal reduction method, using coal fly ash （ 〈 15 μm, 43 - 77 μm, and 〉 100 μm） and active carbon in Some proportion （20% less than theoretical addition, theoretical addition and 10% excess theoretical addition） as starting materials, putting into alumina crucible in high temperature nitriding furnace after well mixed, and holding at 1 300 ℃, 1 350 ℃, 1 400 ℃, 1 450 ℃, and 1 500 ℃ for 6 h. Effects of temperature, particle size of the microsphere . and addition of active carbon on the phase composition and microstructure of the nitridized products were studied by means of XRD and SEM. The results show that the nitridation reaction starts at 1 300 ℃ ; excess active carbon is necessary to form β-SiAION hollow spheres, and particle size is the important parameter to form the hollow spheres nitridized products β-SiAION; at 1 500 ℃, when the active carbon is 10% in excess, the β-SiAlON hollow spheres, which were prepared using coal fly ash with particle size 〉 100 μm, are featured with rough surface, high hollowness and low density.

Research on Decalcification Degradation Process of Cement Stone

An accelerated laboratory method（saturated ammonium nitrate solution immersion method） was used to analyze the degradation of cement decalcification process. By studying the changes of intensity, volume, elastic modulus, quality, p H value, the Ca/Si, and mineral phase, it could be found that the first cement decalcification degradation process was the decalcification of calcium hydroxide, and then CSH gel, AFm, etc. The secondary ettringite deposition happened and the decalcification degradation depth was proportional to the square root of time. Moreover, the corresponding strength of cement would be gradually reduced, cement rock volume shrinkage occurred, p H values decreased, the surface elastic modulus decreased down to a certain level, and slightly changed and the Ca/Si was 3.1 from the beginning and lasted down to 1.3.