The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age ...The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral 40Ar/39Ar dating and report reliable 40Ar/39Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.展开更多
It is difficult to date pyroclastic rocks,for almost all the dating methods,due to the multiple sources during their formation.40Ar/39Ar incremental heating results on groundmass selected from the samples show that th...It is difficult to date pyroclastic rocks,for almost all the dating methods,due to the multiple sources during their formation.40Ar/39Ar incremental heating results on groundmass selected from the samples show that the age spectra are meaningless geologically.However,singe crystal total fusions of CO2 lasing on the sanidine separates could yield rational 40Ar/39Ar results and distinguish their sources in this study.Timing on three formations of the Moshishan Group,after avoiding the exotic and altered grains by lasing on the single sanidine separate,was reported in this paper.The lowermost portion of the Chawan Formation gives an age of 113.7±0.3 Ma;the lower part of the Xishantou Formation was formed 116.4±0.4 Ma ago and the bottom of the Gaowu Formation took its shape at 118.4±0.4 Ma.These new ages are much younger than the previous ones,suggesting that these thick volcanic formations had been formed in very short durations.展开更多
Four international standards,Ga1550,MMhb-1,Lp-6,Bern 4M,and one domesticstandard BT-1 have been intercalibrated.The repeated measurements on MMhb-1 with different massdemonstrate that MMhb-1 is inhomogeneous in age an...Four international standards,Ga1550,MMhb-1,Lp-6,Bern 4M,and one domesticstandard BT-1 have been intercalibrated.The repeated measurements on MMhb-1 with different massdemonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma.The results of Bern4M and Lp-6 reflect that they have an invariable value of^(40)Ar*/^(39)Ar_(k)(F)and the ages weobtained are consensus with their K-Ar age:Lp-6=127.7Ma;Bern 4M=18.2 Ma.Analyses of BT-1 agespectra,Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneousand invariable and keeps close chemically,with its trapped argon isotope composition close to theatmosphere.The dating results show that age values are reproducible and steady,total fusion age,step-heating age,plateau age and isochron age are in accord with each other within the error range(2σ).Therefore,we recommend 28.7 Ma as the calibrated age of BT-1.We also discuss the variationin neutron flux gradients of Beijing 49-2 reactor.It was found that the neutron flux gradientvaries considerably,and more monitors(standard samples)are needed to fix the trend of variation.The coefficient of the 49-2 reactor that transfers the ratio of production rate of^(37)Ar_(Ca)/^(39)Ar_(K) into Ca/K ratio is 1.78.This is different from that reported earlier,2.0,which may be caused by the reconstruction of the reactor.展开更多
基金This work was supported by the Ministry of Science and Technology of the People’s Republic of China(Grant No.2016YFC0600109)the Natural Science Foundations of China(Grant No.41521062,41503055).
文摘The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral 40Ar/39Ar dating and report reliable 40Ar/39Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.
基金Supported by National Natural Science Foundation of China (Grant Nos.40221402,40673048 and 90714007)
文摘It is difficult to date pyroclastic rocks,for almost all the dating methods,due to the multiple sources during their formation.40Ar/39Ar incremental heating results on groundmass selected from the samples show that the age spectra are meaningless geologically.However,singe crystal total fusions of CO2 lasing on the sanidine separates could yield rational 40Ar/39Ar results and distinguish their sources in this study.Timing on three formations of the Moshishan Group,after avoiding the exotic and altered grains by lasing on the single sanidine separate,was reported in this paper.The lowermost portion of the Chawan Formation gives an age of 113.7±0.3 Ma;the lower part of the Xishantou Formation was formed 116.4±0.4 Ma ago and the bottom of the Gaowu Formation took its shape at 118.4±0.4 Ma.These new ages are much younger than the previous ones,suggesting that these thick volcanic formations had been formed in very short durations.
基金supported by the National Natural Science Foundation of China(Grant No.40473031).
文摘Four international standards,Ga1550,MMhb-1,Lp-6,Bern 4M,and one domesticstandard BT-1 have been intercalibrated.The repeated measurements on MMhb-1 with different massdemonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma.The results of Bern4M and Lp-6 reflect that they have an invariable value of^(40)Ar*/^(39)Ar_(k)(F)and the ages weobtained are consensus with their K-Ar age:Lp-6=127.7Ma;Bern 4M=18.2 Ma.Analyses of BT-1 agespectra,Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneousand invariable and keeps close chemically,with its trapped argon isotope composition close to theatmosphere.The dating results show that age values are reproducible and steady,total fusion age,step-heating age,plateau age and isochron age are in accord with each other within the error range(2σ).Therefore,we recommend 28.7 Ma as the calibrated age of BT-1.We also discuss the variationin neutron flux gradients of Beijing 49-2 reactor.It was found that the neutron flux gradientvaries considerably,and more monitors(standard samples)are needed to fix the trend of variation.The coefficient of the 49-2 reactor that transfers the ratio of production rate of^(37)Ar_(Ca)/^(39)Ar_(K) into Ca/K ratio is 1.78.This is different from that reported earlier,2.0,which may be caused by the reconstruction of the reactor.
