Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6...Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6) A, β=121. 02(2)°, Z=8, V=4606. 2 A3, Dc= 1. 512 g/cm3, μ= 12. 724 cm-1, F(000) = 1766,Mr = 440. 6, Final R = 0. 061 and R. = 0. 071. X-ray crystal structure analysis revealedthat copper(I) is coordinated by two O and two N atoms. The Cu(I) atom displays anearly square planar coordination geometry.展开更多
Dibenzoyl peroxide undergoes oxidative addition with metallic copper powder and 2, 2’-bipyridine in a mixed solvent （methanol and tetrahydrofuran ） to afford copper（Ⅱ） complex [Cu（2, 2’-bipy） （C<sub>6&...Dibenzoyl peroxide undergoes oxidative addition with metallic copper powder and 2, 2’-bipyridine in a mixed solvent （methanol and tetrahydrofuran ） to afford copper（Ⅱ） complex [Cu（2, 2’-bipy） （C<sub>6</sub>H<sub>5</sub>COO）<sub>2</sub>]· H<sub>2</sub>O. The structure of the cornplex was solved by direct methods and refined by block-diagonal and full-ma-trix least-squares method to a final R of 0. 055 for 2654 independent reflections of I 】3σ（I）. Crystals are monoclinic,space group P2<sub>1</sub>/c , Mr= 479. 78 with cell parameters a= 6. 986（7） , b= 18. 833（1）, c= 17. 021（3）, β=97. 96（1）°, Z=4, Dc=1. 437g. cm￣（-3）, V= 2218. 1. Each copper ion is coordinated by the oxygen atoms of two benzoato groups and the nitrogen atoms of 2. 2’-bipyridine in a planar square geometry.展开更多
Reaction of 2-thenoyltrifluoroacetone with metal copper in methanol gave the complex [Cu(C_8H_4O_2SF_3)_2]. The X-ray crystal structure of the complex has been determined. The crystal is monoclinic, space group P2_1/c...Reaction of 2-thenoyltrifluoroacetone with metal copper in methanol gave the complex [Cu(C_8H_4O_2SF_3)_2]. The X-ray crystal structure of the complex has been determined. The crystal is monoclinic, space group P2_1/c, M_r= 505. 9 with cell parameters α= 10. 582(1) , b=11. 129(2), c=8. 044(3) A, β=104. 61(2)°, Z=2, V = 916. 7A￣3, D_c=1. 833 g·cm￣(-3), F(000) =426, μ= 9. 8 cm￣(-1). The Cu atom is coordinated by four O atoms to form square plane. The average bond length of Cu-O is 1. 905 A.展开更多
The complex[Cu (dppe)2](NO3)2 was prepared by the reaction of copper(Ⅱ) nitrate with bis(diphenylphosphino) ethane(dppe) in methanol and its crystal structure was determined by X-ray diffraction.The structure was so...The complex[Cu (dppe)2](NO3)2 was prepared by the reaction of copper(Ⅱ) nitrate with bis(diphenylphosphino) ethane(dppe) in methanol and its crystal structure was determined by X-ray diffraction.The structure was solved by direct methods and refined by block-diagonal and full-matrix least-squares methods to a final R of 0.043 for 4085 independent reflections of I>3σ(I).The crystal is monoclinic, space group P21/n,Mr=984.41 with cell parameters a=12.896(2),b=22.250(4),c=17.512(5)A,β=101.6(3)°, V=4922.3 A3,Z=4,Dc=1.590 g/cm3,F(000)=1900,μ=10.573 cm-1. In this complex, C52H48CuN2O6P4, dppe functions as a bidentate chelate ligand. The four phosphorus atoms from two dppe are coordinated to the distorted tetrahedral copper.展开更多
文摘Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6) A, β=121. 02(2)°, Z=8, V=4606. 2 A3, Dc= 1. 512 g/cm3, μ= 12. 724 cm-1, F(000) = 1766,Mr = 440. 6, Final R = 0. 061 and R. = 0. 071. X-ray crystal structure analysis revealedthat copper(I) is coordinated by two O and two N atoms. The Cu(I) atom displays anearly square planar coordination geometry.
文摘Dibenzoyl peroxide undergoes oxidative addition with metallic copper powder and 2, 2’-bipyridine in a mixed solvent （methanol and tetrahydrofuran ） to afford copper（Ⅱ） complex [Cu（2, 2’-bipy） （C<sub>6</sub>H<sub>5</sub>COO）<sub>2</sub>]· H<sub>2</sub>O. The structure of the cornplex was solved by direct methods and refined by block-diagonal and full-ma-trix least-squares method to a final R of 0. 055 for 2654 independent reflections of I 】3σ（I）. Crystals are monoclinic,space group P2<sub>1</sub>/c , Mr= 479. 78 with cell parameters a= 6. 986（7） , b= 18. 833（1）, c= 17. 021（3）, β=97. 96（1）°, Z=4, Dc=1. 437g. cm￣（-3）, V= 2218. 1. Each copper ion is coordinated by the oxygen atoms of two benzoato groups and the nitrogen atoms of 2. 2’-bipyridine in a planar square geometry.
文摘Reaction of 2-thenoyltrifluoroacetone with metal copper in methanol gave the complex [Cu(C_8H_4O_2SF_3)_2]. The X-ray crystal structure of the complex has been determined. The crystal is monoclinic, space group P2_1/c, M_r= 505. 9 with cell parameters α= 10. 582(1) , b=11. 129(2), c=8. 044(3) A, β=104. 61(2)°, Z=2, V = 916. 7A￣3, D_c=1. 833 g·cm￣(-3), F(000) =426, μ= 9. 8 cm￣(-1). The Cu atom is coordinated by four O atoms to form square plane. The average bond length of Cu-O is 1. 905 A.
文摘The complex[Cu (dppe)2](NO3)2 was prepared by the reaction of copper(Ⅱ) nitrate with bis(diphenylphosphino) ethane(dppe) in methanol and its crystal structure was determined by X-ray diffraction.The structure was solved by direct methods and refined by block-diagonal and full-matrix least-squares methods to a final R of 0.043 for 4085 independent reflections of I>3σ(I).The crystal is monoclinic, space group P21/n,Mr=984.41 with cell parameters a=12.896(2),b=22.250(4),c=17.512(5)A,β=101.6(3)°, V=4922.3 A3,Z=4,Dc=1.590 g/cm3,F(000)=1900,μ=10.573 cm-1. In this complex, C52H48CuN2O6P4, dppe functions as a bidentate chelate ligand. The four phosphorus atoms from two dppe are coordinated to the distorted tetrahedral copper.
