Soil and water losses through erosion have been serious in the black soil region of Northeast China. Therefore, a sloping cultivated land in Songnen Plain was selected as a case study to: 1) determine the 137Cs refere...Soil and water losses through erosion have been serious in the black soil region of Northeast China. Therefore, a sloping cultivated land in Songnen Plain was selected as a case study to: 1) determine the 137Cs reference inventory in the study area; 2) calculate erosion and deposition rates of black soil on different slope locations; 3) conduct a sensitivity analysis of some model parameters; and 4) compare overall outputs using four different models. Three transects were set in the field with five slope locations for each transect, including summit, shoulder-slope, back-slope, foot-slope, and toe-slope. Field measurements and model simulation were used to estimate a bomb-derived 137Cs reference inventory in the study area. Soil erosion and deposition rates were estimated using four 137Cs models and percentage of 137Cs loss/gain. The 137Cs reference value in the study area was 2 232.8 Bq m-2 with 137Cs showing a clear topographic pattern, decreasing from the summit to shoulder-slope, then increasing again at the foot-slope and reaching a maximum at the toe-slope. Predicted soil redistribution rates for different slope locations varied. Among models, the Yang Model (YANG-M) overestimated erosion loss but underestimated deposition. However, the standard mass balance model (MBM1) gave predictions similar to a mass balance model incorporating soil movement by tillage (MBM2). Sensitivity analysis of the proportion factor 7 and distribution pattern of 137Cs in the surface layer demonstrated the impact of 137Cs enrichment on calculation of the soil erosion rate. Factors influencing the redistribution of fallout 137Cs in landscape should be fully considered as calculating soil redistribution rate using 137Cs technique.展开更多
In order to study the effect of minerals on biomass pyrolysis, experiments on pyrolysis of corn straw with different pretreatment methods were performed by using a thermogravimetric analyzer（TGA） coupled with a Four...In order to study the effect of minerals on biomass pyrolysis, experiments on pyrolysis of corn straw with different pretreatment methods were performed by using a thermogravimetric analyzer（TGA） coupled with a Fourier transform infrared （FTIR） spectrometer. The pretreatment methods included water washing and acid washing. The experimental results show that acid washing can remove almost all K^＋ and 78% of Ca^2＋ , while water washing only removes most of K ^＋. The existence of K^＋ and Ca^2＋ obviously favors the formation of compounds containing carbonyl groups and CO2 , but it will decrease the yields of compounds containing C-O-C groups. However, the formation of H2O, CO and CH4 are slightly affected by the removal of inorganic ions. With regard to the structure of the metal ions-adsorbed cellulose characterized by IR analysis, it can be considered that there is an ＂ion force＂ between metal ions and cellulosic biomass. The results of thermal kinetic analysis show that this force can make the reaction activation energy of the biomass pyrolysis decrease. A new mechanism is proposed for explaining the effect of inorganic ions on cellulose pyrolysis.展开更多
In order to get a good indicator to evaluate the impacts of no tillage （NT） on soil structure and soil quality, we studied the dynamics of total soil organic carbon （SOC） and aggregate-associated SOC, and their re...In order to get a good indicator to evaluate the impacts of no tillage （NT） on soil structure and soil quality, we studied the dynamics of total soil organic carbon （SOC） and aggregate-associated SOC, and their relationships in the plow layer （30 cm） in black soil of Northeast China under NT practice. The tillage experiment was established in Dehui County, Jilin Province, China, in 2001. The total SOC and aggregate-associated SOC under 5-yr tillage treatments were measured. NT practices did not lead to the increase of average SOC content at 0-30 cm depth, but it did significantly increase SOC at the top soil （0-5 cm）. In NT plots, the change of SOC in 〉 1 000 μm aggregate was the same with that of total SOC, but the effect of NT on SOC in 〉 1 000 lain aggregate was greater than the effect on total SOC, suggesting that 〉 1 000 μm aggregate had more sensitive response to the impact of tillage practices. Also, significant positive correlation occurred between total SOC and SOC in 〉 1 000 μm aggregate in black soil. Consequently, in the short term soil macroaggregate 〉 1 000 μm could be used as an indicator to evaluate the impacts of tillage practices on soil structure in black soil of Northeast China.展开更多
基金Project supported by the Hundred Talents Program of Chinese Academy of Sciences (No. K09Z3) the National Natural Science Foundation of China (Nos. 40271108 and 40471125).
文摘Soil and water losses through erosion have been serious in the black soil region of Northeast China. Therefore, a sloping cultivated land in Songnen Plain was selected as a case study to: 1) determine the 137Cs reference inventory in the study area; 2) calculate erosion and deposition rates of black soil on different slope locations; 3) conduct a sensitivity analysis of some model parameters; and 4) compare overall outputs using four different models. Three transects were set in the field with five slope locations for each transect, including summit, shoulder-slope, back-slope, foot-slope, and toe-slope. Field measurements and model simulation were used to estimate a bomb-derived 137Cs reference inventory in the study area. Soil erosion and deposition rates were estimated using four 137Cs models and percentage of 137Cs loss/gain. The 137Cs reference value in the study area was 2 232.8 Bq m-2 with 137Cs showing a clear topographic pattern, decreasing from the summit to shoulder-slope, then increasing again at the foot-slope and reaching a maximum at the toe-slope. Predicted soil redistribution rates for different slope locations varied. Among models, the Yang Model (YANG-M) overestimated erosion loss but underestimated deposition. However, the standard mass balance model (MBM1) gave predictions similar to a mass balance model incorporating soil movement by tillage (MBM2). Sensitivity analysis of the proportion factor 7 and distribution pattern of 137Cs in the surface layer demonstrated the impact of 137Cs enrichment on calculation of the soil erosion rate. Factors influencing the redistribution of fallout 137Cs in landscape should be fully considered as calculating soil redistribution rate using 137Cs technique.
基金Supported by the National High Technology Research and Development Program of China(No. 2003AA514023) and the Na-tional Basic Research Program of China(No. 2004CB719700)
文摘In order to study the effect of minerals on biomass pyrolysis, experiments on pyrolysis of corn straw with different pretreatment methods were performed by using a thermogravimetric analyzer（TGA） coupled with a Fourier transform infrared （FTIR） spectrometer. The pretreatment methods included water washing and acid washing. The experimental results show that acid washing can remove almost all K^＋ and 78% of Ca^2＋ , while water washing only removes most of K ^＋. The existence of K^＋ and Ca^2＋ obviously favors the formation of compounds containing carbonyl groups and CO2 , but it will decrease the yields of compounds containing C-O-C groups. However, the formation of H2O, CO and CH4 are slightly affected by the removal of inorganic ions. With regard to the structure of the metal ions-adsorbed cellulose characterized by IR analysis, it can be considered that there is an ＂ion force＂ between metal ions and cellulosic biomass. The results of thermal kinetic analysis show that this force can make the reaction activation energy of the biomass pyrolysis decrease. A new mechanism is proposed for explaining the effect of inorganic ions on cellulose pyrolysis.
基金supported by the National Natural Science Foundation of China (40801071)the Key Technologies R&D Program of China during the 11th Five-Year Plan period (2006BAD15B01)+1 种基金the Program for Advanced Science Field (KZCX3-SW-NA3-31)Doctoral Research Foundation in Northeast Institute of Geography and Agroecology,Chinese Academy of Sciences (O8H2041)
文摘In order to get a good indicator to evaluate the impacts of no tillage （NT） on soil structure and soil quality, we studied the dynamics of total soil organic carbon （SOC） and aggregate-associated SOC, and their relationships in the plow layer （30 cm） in black soil of Northeast China under NT practice. The tillage experiment was established in Dehui County, Jilin Province, China, in 2001. The total SOC and aggregate-associated SOC under 5-yr tillage treatments were measured. NT practices did not lead to the increase of average SOC content at 0-30 cm depth, but it did significantly increase SOC at the top soil （0-5 cm）. In NT plots, the change of SOC in 〉 1 000 μm aggregate was the same with that of total SOC, but the effect of NT on SOC in 〉 1 000 lain aggregate was greater than the effect on total SOC, suggesting that 〉 1 000 μm aggregate had more sensitive response to the impact of tillage practices. Also, significant positive correlation occurred between total SOC and SOC in 〉 1 000 μm aggregate in black soil. Consequently, in the short term soil macroaggregate 〉 1 000 μm could be used as an indicator to evaluate the impacts of tillage practices on soil structure in black soil of Northeast China.
