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铋纳米材料的电化学制备及储锂性能研究 被引量:1
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作者 杨应昌 牛雨 《广东化工》 CAS 2019年第7期51-51,50,共2页
与传统方法相比,电化学合成纳米材料具有低成本、高效率、绿色环保的优势,当今在科学研究及工业应用中颇受重视。本文以金属铋为前驱体采用便捷、绿色、高效的电化学阴极极化法合成了铋纳米材料,并探索了其在锂离子电池负极材料中的应... 与传统方法相比,电化学合成纳米材料具有低成本、高效率、绿色环保的优势,当今在科学研究及工业应用中颇受重视。本文以金属铋为前驱体采用便捷、绿色、高效的电化学阴极极化法合成了铋纳米材料,并探索了其在锂离子电池负极材料中的应用。电化学测试说明其可逆比容量达到359.7 mAh/g,然而该电极材料循环性能较差,与之匹配的电解液或粘结剂需进一步优化。 展开更多
关键词 铋纳米材料 阴极极化 锂离子电池
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低温固相法合成锰酸锂及其储锂性能研究 被引量:1
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作者 杨应昌 黄小艳 向阳 《广东化工》 CAS 2019年第5期33-35,共3页
由于尖晶石型锰酸锂具有无污染、能量密度高、成本低且资源丰富等特点,现已发展成为最具潜力的锂离子电池正极材料之一。本文分别以电化学法获得的Mn_3O_4及商业化Mn_3O_4为前驱体,采用低温固相法(700℃)合成了不同尺寸的尖晶石LiMn_2O_... 由于尖晶石型锰酸锂具有无污染、能量密度高、成本低且资源丰富等特点,现已发展成为最具潜力的锂离子电池正极材料之一。本文分别以电化学法获得的Mn_3O_4及商业化Mn_3O_4为前驱体,采用低温固相法(700℃)合成了不同尺寸的尖晶石LiMn_2O_4材料。电化学测试表明以电化学法获得的Mn_3O_4为前驱体合成的LiMn_2O_4具有较好的循环性能和倍率性能。100次充放电循环后,该LiMn_2O_4电极的容量保持率达到91.7%。20C倍率下,比容量仍高达98.9 mAh/g。 展开更多
关键词 锰酸锂 阴极材料 锂离子电池
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固相合成Li_4Ti_5O_(12)及其储锂性能研究 被引量:1
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作者 杨应昌 廖世佳 张树容 《广东化工》 CAS 2019年第6期34-35,共2页
本文以交流电电化学法获得的超细纳米TiO_2为前驱体,采用固相法合成了纳米尖晶石Li_4Ti_5O_(12)材料。电化学测试表明该法合成的纳米钛酸锂用于锂离子电池负极材料具有优异的循环性能和倍率性能。10 C下400次充放电循环后容量保持率为90... 本文以交流电电化学法获得的超细纳米TiO_2为前驱体,采用固相法合成了纳米尖晶石Li_4Ti_5O_(12)材料。电化学测试表明该法合成的纳米钛酸锂用于锂离子电池负极材料具有优异的循环性能和倍率性能。10 C下400次充放电循环后容量保持率为90.0%,大电流密度50 C下其放电比容量达到56.7 mAh/g。 展开更多
关键词 钛酸锂 负极材料 锂离子电池
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THEORETICAL EXPLANATION OF SPIN REORIENTATION IN DyTiFe_(11) COMPOUND
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作者 PEI Xiedi yang yingchang +2 位作者 ZHA Yyanbo SUN Hong KONG Linshu 《Chinese Physics Letters》 SCIE CAS CSCD 1989年第7期325-328,共4页
At room temperature,the c-axis is the easy magnetization direction tn DyTiFen compound.However,when we decrease temperature,the thermal magnetic curves show that a spin reorientation takes place at about 175K.The anis... At room temperature,the c-axis is the easy magnetization direction tn DyTiFen compound.However,when we decrease temperature,the thermal magnetic curves show that a spin reorientation takes place at about 175K.The anisotropy constants of Ft sublattice have been determined by measuring the magnetocrystalline anisotropy of YTiFen,We have calculated the anisotropy constants of Dy by using single ion theory.The results demonstrate that the spin reorientation arises from the competition of magnetocrystalline anisotropy between Dy and Fe sublattices.The spin reorientation is explaned by the theo retical calculation. 展开更多
关键词 CALCULATION ANISOTROPY THEORY
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Magnetic Properties of Sm_(2) Fe_(17) N_(2) and Y_(2) Fe_(17) N_(2)
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作者 yang yingchang ZHANG Xiaodong +1 位作者 KONG Linshu PAN Qi 《Chinese Physics Letters》 SCIE CAS CSCD 1991年第6期318-321,共4页
The crystallographic and magnetic properties of Sm_(2) Fe_(17) N_(2) and Y_(2) Fe_(17) N_(2) have been investigated by using X-ray diffraction techniques and magnetic measurements.The effects of the interstitial nitro... The crystallographic and magnetic properties of Sm_(2) Fe_(17) N_(2) and Y_(2) Fe_(17) N_(2) have been investigated by using X-ray diffraction techniques and magnetic measurements.The effects of the interstitial nitrogen atoms on the Fe-Fe and R-Fe exchange interactions,iron 3d band structure and magnetocrystalline anisotropy induced by crystal field interactions in these nitride compounds are discussed. 展开更多
关键词 ANISOTROPY MAGNETIC
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Magnetic Properties of NdTiFe_(11)N_(0.5) and YTiF_(11)N_(0.5)
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作者 yang yingchang ZHANG Xiaodong +1 位作者 PAN Qi KONG Linshu 《Chinese Physics Letters》 SCIE CAS CSCD 1991年第7期372-375,共4页
The structural and magnetic properties of NdTiFe_(11)N_(0.5) and YTiFe_(11)N_(0.5) have been studied.The nitrides retain the tetragonal ThMn_(12) structure and their unit cell volumes slightly increase.The interstitia... The structural and magnetic properties of NdTiFe_(11)N_(0.5) and YTiFe_(11)N_(0.5) have been studied.The nitrides retain the tetragonal ThMn_(12) structure and their unit cell volumes slightly increase.The interstitial nitrogen atoms are found to increase the Curie temperature and saturation magnetization of the compounds,and especially have a strong effect on the magnetocrystalline anisotropy. 展开更多
关键词 slightly MAGNETIZATION
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CONTRIBUTION OF Sm^(3+) ION TO THE MAGNETOCRYSTALLINE ANISOTROPY IN SmTiFe_(11) COMPOUND
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作者 PEI Xiedi yang yingchang +2 位作者 ZHA Yuanbo SUN Hong KONG Linshu 《Chinese Physics Letters》 SCIE CAS CSCD 1989年第4期189-192,共4页
The magnetocrystalline anisotropy of SmTiFe_(11) Aas 6een studied.In addition to experimental investigations,the contribution of Sm^(3+) ion to the magnetocrystalline anisotropy of SmTiFe^(11) has been calculated usin... The magnetocrystalline anisotropy of SmTiFe_(11) Aas 6een studied.In addition to experimental investigations,the contribution of Sm^(3+) ion to the magnetocrystalline anisotropy of SmTiFe^(11) has been calculated using the single ion theory.The effect of the first excited state of Sm^(3+) has been taken into consideration in the calculations,and the calculated results are consistent with the experimental data. 展开更多
关键词 ANISOTROPY EXCITED
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NEUTRON DIFFRACTION STUDY OF SPIN REORIENTATION OF Nd_(15)Fe_(78)B_(7)
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作者 HE Wenwang yang yingchang +5 位作者 CHEN Haiying XING Feng yang Jilian ZHANG Baishen ZHOU Huiaing JIN Lan 《Chinese Physics Letters》 SCIE CAS 1987年第11期517-520,共4页
Using neutron diffraction and magnetic measurement,we have measured the canting angle of the iron spin in Nd_(15)Fe_(78)B_(7) compound with powder samples.The iron spins rotate away from the c-axis by 26°34'a... Using neutron diffraction and magnetic measurement,we have measured the canting angle of the iron spin in Nd_(15)Fe_(78)B_(7) compound with powder samples.The iron spins rotate away from the c-axis by 26°34'at 77K. 展开更多
关键词 rotate COMPOUND
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