Per-and polyfluoroalkyl substances(PFASs)have been restricted from production and consumption in many countries due to their persistence and biological toxicity.With the development of removal technologies,the require...Per-and polyfluoroalkyl substances(PFASs)have been restricted from production and consumption in many countries due to their persistence and biological toxicity.With the development of removal technologies,the requirement on the detection of different kinds of PFASs and their derivates is increasing.A suitable analytical method is the prerequisite and basis for the study of the degradation of PFASs.As various analytical methods have been reported,questions about which one is more suitable have arisen.It is a right time to summarize the past and suggest the future.In this paper,we summarized and discussed the analytical methods applied in the chemical degradation of PFASs.We also proposed the current problems and discussed the future directions in this field.展开更多
Mercury(Hg),arsenic(As) and selenium(Se) are ubiquitous in the environment and exist in a variety of species,which have great influence on their transport,bioaccumulation and toxicity.This review presents the recent r...Mercury(Hg),arsenic(As) and selenium(Se) are ubiquitous in the environment and exist in a variety of species,which have great influence on their transport,bioaccumulation and toxicity.This review presents the recent research progress in speciation analysis of Hg,As,and Se,with emphasis on enhanced cold vapor generation as interface for liquid chromatography and atomic spectrometry,speciation of volatile species in gas phase,and isotope dilution technique to improve the precision and accuracy of speciation.Hyphenated techniques to characterize the complexes of Hg and As with phytochelatins and chromatographic separation coupled with multi-collector-inductively coupled plasma mass spectrometry to measure species-specific isotopic ratios,are also briefly discussed.展开更多
A headspace solid phase microextrac- tion coupled with gas chromatography mass spec- trometry (HS-SPME/GC-MS) method was estab- lished for analyzing nitrobenzene, benzene and ani- line in environmental water samples s...A headspace solid phase microextrac- tion coupled with gas chromatography mass spec- trometry (HS-SPME/GC-MS) method was estab- lished for analyzing nitrobenzene, benzene and ani- line in environmental water samples simultaneously. Factors affecting extraction efficiency (SPME fiber selection, acidity, temperature, salt addition, extrac- tion time, headspace, etc) were verified. Under opti- mal extraction conditions, the detection limits are 0.50, 0.11 and 1.00 μg/L for nitrobenzene, benzene and aniline, respectively. The results indicate that this method is capable of making sensitive and accuracy analyses on nitrobenzene, benzene and aniline in environmental water samples.展开更多
基金supported by the National Natural Science Foundation of China(No.22206113)the Fund of Qilu Youth Talent Program of Shandong University,China(No.61440082163171)+1 种基金the Outstanding Youth Science Fund(Overseas)of Shandong Provincial Natural Science Foundation,China(No.2022HWYQ-015)the Taishan Scholars Project Special Fund,China(No.tsqn202211039).
文摘Per-and polyfluoroalkyl substances(PFASs)have been restricted from production and consumption in many countries due to their persistence and biological toxicity.With the development of removal technologies,the requirement on the detection of different kinds of PFASs and their derivates is increasing.A suitable analytical method is the prerequisite and basis for the study of the degradation of PFASs.As various analytical methods have been reported,questions about which one is more suitable have arisen.It is a right time to summarize the past and suggest the future.In this paper,we summarized and discussed the analytical methods applied in the chemical degradation of PFASs.We also proposed the current problems and discussed the future directions in this field.
基金supported by the National Natural Science Foundation of China (20877082,21120102040,21025729)
文摘Mercury(Hg),arsenic(As) and selenium(Se) are ubiquitous in the environment and exist in a variety of species,which have great influence on their transport,bioaccumulation and toxicity.This review presents the recent research progress in speciation analysis of Hg,As,and Se,with emphasis on enhanced cold vapor generation as interface for liquid chromatography and atomic spectrometry,speciation of volatile species in gas phase,and isotope dilution technique to improve the precision and accuracy of speciation.Hyphenated techniques to characterize the complexes of Hg and As with phytochelatins and chromatographic separation coupled with multi-collector-inductively coupled plasma mass spectrometry to measure species-specific isotopic ratios,are also briefly discussed.
文摘A headspace solid phase microextrac- tion coupled with gas chromatography mass spec- trometry (HS-SPME/GC-MS) method was estab- lished for analyzing nitrobenzene, benzene and ani- line in environmental water samples simultaneously. Factors affecting extraction efficiency (SPME fiber selection, acidity, temperature, salt addition, extrac- tion time, headspace, etc) were verified. Under opti- mal extraction conditions, the detection limits are 0.50, 0.11 and 1.00 μg/L for nitrobenzene, benzene and aniline, respectively. The results indicate that this method is capable of making sensitive and accuracy analyses on nitrobenzene, benzene and aniline in environmental water samples.
