The title complex bistri(o-fluorbenzyl)tinpiperazinylbisdithiocarbamate (C48H44- F6N2S4Sn2, Mr = 1128.47) was synthesized by the reaction of tri(o-fluorbenzyl)tin chloride with piperazinylbisdithiocarbamate in 2:1 mol...The title complex bistri(o-fluorbenzyl)tinpiperazinylbisdithiocarbamate (C48H44- F6N2S4Sn2, Mr = 1128.47) was synthesized by the reaction of tri(o-fluorbenzyl)tin chloride with piperazinylbisdithiocarbamate in 2:1 molar ratio. The structure was characterized by elemental analysis, IR and 1H NMR, and the crystal structure was determined by X-ray single-crystal diffrac- tion. The crystal belongs to triclinic, space group P with a= 10.348(5), b = 10.636(6), c = 13.279(7) , a = 68.445(9), b = 86.763(9), g = 61.278(8)o, Z = 1, V = 1179(1) 3, Dc = 1.589 g/cm3, m = 1.296 mm-1, F(000) = 564, R = 0.0534 and wR = 0.0849. In the complex, the tin atoms are five-coordinate to a distorted tirgonal bipyramidal configuration.展开更多
基金Project supported by the Natural Science Foundation of Shandong province (No. L2003B01) and the State Key Laboratory of Crystal Materials Shandong University
文摘The title complex bistri(o-fluorbenzyl)tinpiperazinylbisdithiocarbamate (C48H44- F6N2S4Sn2, Mr = 1128.47) was synthesized by the reaction of tri(o-fluorbenzyl)tin chloride with piperazinylbisdithiocarbamate in 2:1 molar ratio. The structure was characterized by elemental analysis, IR and 1H NMR, and the crystal structure was determined by X-ray single-crystal diffrac- tion. The crystal belongs to triclinic, space group P with a= 10.348(5), b = 10.636(6), c = 13.279(7) , a = 68.445(9), b = 86.763(9), g = 61.278(8)o, Z = 1, V = 1179(1) 3, Dc = 1.589 g/cm3, m = 1.296 mm-1, F(000) = 564, R = 0.0534 and wR = 0.0849. In the complex, the tin atoms are five-coordinate to a distorted tirgonal bipyramidal configuration.
