Theoretical analysis of the optical rotational Doppler effect under atmospheric turbulence by mode decomposition

The optical rotational Doppler effect associated with orbital angular momentum provides a new means for rotational velocity detection.In this paper,we investigate the influence of atmospheric turbulence on the rotational Doppler effect.First,we deduce the generalized formula of the rotational Doppler shift in atmospheric turbulence by mode decomposition.It is found that the rotational Doppler signal frequency spectrum will be broadened,and the bandwidth is related to the turbulence intensity.In addition,as the propagation distance increases,the bandwidth also increases.And when C_(n)^(2)≤5×10^(-15)m^(-2/3)and 2z≤2 km,the rotational Doppler signal frequency spectrum width d and the spiral spectrum width d_(0)satisfy the relationship d=2d_(0-1).Finally,we analyze the influence of mode crosstalk on the rotational Doppler effect,and the results show that it destroys the symmetrical distribution of the rotational Doppler spectrum about 2l·Ω/2π.This theoretical model enables us to better understand the generation of the rotational Doppler frequency and may help us better analyze the influence of the complex atmospheric environment on the rotational Doppler frequency.

Nacre-inspired interface structure design of polymer bonded explosives toward significantly enhanced mechanical performance

Realizing effective enhancement to the structure of interface region between explosive crystals and polymer binder plays a key role in improving the mechanical properties of the current polymer bonded explosives(PBXs).Herein,inspired by the structure of natural nacre which possesses outstanding mechanical performance,a kind of nacre-like structural layer is constructed in the interface region of PBXs composites,making use of two-dimensional graphene sheets and one-dimensional bio-macromolecules of cellulose as inorganic and organic building blocks,respectively.Our results reveal that the constructed nacre-like structural layer can effectively improve the interfacial strength and then endow the PBXs composites with significantly enhanced mechanical properties involving of creep resistance,Brazilian strength and fracture toughness,demonstrating the obvious advantage of such bioinspired interface structure design strategy.In addition,the thermal conduction performance of PBXs composites also exhibits noticeable enhancement due to the remarkable phonon transport capability endowed by the asdesigned nacre-like structural layer.We believe this work provides a novel design route to conquer the issue of weak interfacial strength in PBXs composites and greatly increase the comprehensive properties for better meeting the higher requirements proposed to the explosive part of weapon equipment in new era.

Plasmon-enhanced fluorescence of gold nanoparticle/graphene quantum dots for detection of Cr^(3+)ions

Graphene quantum dots(GQDs),fascinating semiconductors with stable photoluminescence(PL),have important potential applications in the fields of biology,medicine,and new semiconductor devices.However,it is still challenging to overcome the weak PL intensity.Here,we report a strategy for selective resonance enhancement of GQD fluorescence using gold nanoparticles(AuNPs)as plasmas.Interestingly,the addition of low concentration AuNP makes AuNP/GQDs exhibit significant fluorescence enhancement of 2.67 times in the visible range.The addition of high concentration AuNP leads to the formation of an excitation peak at 421 nm and selectively enhances certain radiation modes.We concluded that the main reason for the selective enhancement of PL intensity in high concentration AuNP is the transfer of generous hot electrons at high energy states from AuNP to GQD and relaxation to the ground state.The electron resonance of low concentration AuNP transfers to GQD and relaxes to lower energy levels,exhibiting an overall enhancement of PL intensity.We apply it for detection of the heavy metal ion Cr^(3+),and verify that it has a correlation coefficient of 97.36%.We believe AuNP/GQDs can be considered excellent candidates for heavy metal detection and high fluorescence bio-imaging.