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活性炭纤维负载型离子液体脱汞性能研究 被引量:2
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作者 于江怀 鲍静静 +3 位作者 许家菱 罗紫菱 唐继国 孙立成 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2021年第1期124-132,共9页
采用过量浸渍法将氯化1-丁基-3-甲基咪唑(BmimCl)负载于活性炭纤维(ACF)制得活性炭纤维负载型离子液体吸附剂(ACF-BmimCl)。将制得的吸附剂置于湿法烟气脱硫(WFGD)系统下游进行Hg0吸附实验。研究结果表明:在活性炭纤维载体上负载离子液... 采用过量浸渍法将氯化1-丁基-3-甲基咪唑(BmimCl)负载于活性炭纤维(ACF)制得活性炭纤维负载型离子液体吸附剂(ACF-BmimCl)。将制得的吸附剂置于湿法烟气脱硫(WFGD)系统下游进行Hg0吸附实验。研究结果表明:在活性炭纤维载体上负载离子液体可以显著提高其脱汞性能,离子液体负载质量分数约为1%时脱汞效果最好;O2对ACF-1%BmimCl吸附Hg0具有明显的促进作用;CO2和NO在浓度较低时可促进ACF-1%BmimCl吸附脱除Hg0,但浓度较高时则会与Hg0发生竞争吸附,导致ACF-1%BmimCl脱汞效率降低;SO2对ACF-1%BmimCl吸附Hg0具有明显的抑制作用。同时,热重分析、扫描电子显微镜(SEM)及傅里叶红外光谱(FTIR)分析结果表明离子液体负载型吸附剂具有较好的热稳定性,BmimCl可以稳定负载于ACF表面,并可通过化学反应稳定吸附汞。 展开更多
关键词 离子液体 吸附剂 烟气 活性炭纤维
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湿法烟气脱硫系统中Hg0再释放特性及离子液体脱汞研究 被引量:1
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作者 许家菱 鲍静静 +2 位作者 于江怀 罗紫菱 孙立成 《华电技术》 CAS 2020年第10期41-47,共7页
为进一步提高湿法烟气脱硫(WFGD)系统中的脱汞效率,对低浓度SO32-工况下Hg0再释放特性以及不同离子液体的脱汞性能进行了研究。基于鼓泡塔反应器,在N2气氛下研究了SO32-和金属离子(Fe2+,Fe3+和Cu2+)对WFGD系统中Hg0再释放特性的影响,同... 为进一步提高湿法烟气脱硫(WFGD)系统中的脱汞效率,对低浓度SO32-工况下Hg0再释放特性以及不同离子液体的脱汞性能进行了研究。基于鼓泡塔反应器,在N2气氛下研究了SO32-和金属离子(Fe2+,Fe3+和Cu2+)对WFGD系统中Hg0再释放特性的影响,同时考察了3种离子液体(HMIM[PF6],BMIM[PF6],BMIMCl)的脱汞性能,筛选出表现最佳的添加剂和其最优运行工况。结果表明,当脱硫液中SO32-浓度处于较低水平时,增加SO32-浓度可促进Hg2+的还原;而当SO32-过量时,Hg0再释放行为将被明显抑制。Fe2+,Fe3+和Cu2+等金属离子浓度的增加均能促进Hg0的再释放。上述3种离子液体添加剂抑制效果为BMIMCl>BMIM[PF6]>HMIM[PF6]。对脱汞性能较好的添加剂BMIMCl进行进一步试验,获得其抑制Hg0再释放的最佳工况,即添加质量浓度为10 g/L、较低脱硫液pH值以及50℃脱硫液温度。 展开更多
关键词 湿法烟气脱硫 Hg0再释放 SO32-浓度 金属离子 离子液体 脱汞
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Occurrence and Fate of Antibiotics in the Aqueous Environment and Their Removal by Constructed Wetlands in China: A review 被引量:24
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作者 GUAN Yidong WANG Bo +4 位作者 GAO Yongxia LIU Wen ZHAO Xiaoli HUANG Xiaofeng yu jianghuai 《Pedosphere》 SCIE CAS CSCD 2017年第1期42-51,共10页
Overuse of antibiotics has become a serious ecological problem worldwide. There is growing concern that antibiotics are losing their effectiveness due to an increased antibiotic resistance in bacteria. During the last... Overuse of antibiotics has become a serious ecological problem worldwide. There is growing concern that antibiotics are losing their effectiveness due to an increased antibiotic resistance in bacteria. During the last twenty years, consumption of antibiotics has increased rapidly in China, which has been cited as one of the world's worst abusers of antibiotics. This review summarizes the current state of antibiotic contamination in China's three major rivers (the Yangtze River, Yellow River, and Pearl River) and illustrates the occurrence and fate of antibiotics in conventional municipal wastewater treatment plants (VC-VVTPs). The analytical data indicate that traditional W-WTPs cannot completely remove these concerned pharmaceuticals, as seen in the large difference between the distribution coefficient (Kd) and the uneven removal efficiency of various types of antibiotics. Although constructed wetlands (CWs) offer a potential way to remove these antibiotics from water supplies, knowledge of their mechanisms is limited. There are four main factors affecting the performance of CWs used for the treatment of antibiotics in water supplies, the types and configurations of CWs, hydraulic load rates, substrates, and plants and microorganisms. Further researches focusing on these factors are needed to improve the removal efficiency of antibiotics in CWs. 展开更多
关键词 antibiotic contamination biological degration municipal treatment plant POLLUTANTS water supplies
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