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淹水-落干循环驱动下土壤砷结合形态的动态转化
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作者 侯钦宣 张英 +2 位作者 于开宁 韩冬雅 陈俊良 《科学技术与工程》 北大核心 2023年第22期9728-9736,共9页
外源砷在土壤中的毒性/迁移性主要受控于其结合形态,探明土壤砷结合形态的动态变化是准确评价其生态风险的前提。通过室内土柱淹水-落干循环模拟野外土壤氧化还原环境的交替性转变,利用连续提取技术分析了土壤砷各结合形态的变化规律及... 外源砷在土壤中的毒性/迁移性主要受控于其结合形态,探明土壤砷结合形态的动态变化是准确评价其生态风险的前提。通过室内土柱淹水-落干循环模拟野外土壤氧化还原环境的交替性转变,利用连续提取技术分析了土壤砷各结合形态的变化规律及相互转变过程,结果表明:土柱的淹水-落干循环致使不同层位土壤氧化还原电位值(oxidation reduction potential,ORP)在-114~615 mV范围内振荡变化并驱动着土壤氧化环境的交替变化。此外,ORP的振荡变化提高了与砷迁移性密切相关的氧化铁晶形化。在120 d的试验周期内,非专性吸附态和残渣态砷含量总体减少,而非晶质和晶质氧化物结合态砷含量增加。水溶性砷在水动力作用下向上层土壤迁移,导致非专性吸附态砷含量表现为上层土壤>底层土壤,其他形态则相反。微生物对土壤矿物的氧化/还原性溶解、微孔扩散、氧化物的吸附包裹等可能是土壤砷结合形态相互转化的主要驱动机制。对比特定氧化/还原条件,氧化还原条件的交替转变明显延缓了土壤砷的“老化”并使其在各形态的(重)分配变得更为复杂。 展开更多
关键词 土壤 砷结合形态 氧化还原环境交替 转化机制
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碱处理对河北围场天然沸石结构和性能的影响及其机理研究 被引量:1
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作者 王程 郭慧东 +3 位作者 于佳乐 冯锴 于开宁 李艳 《岩石矿物学杂志》 CAS CSCD 北大核心 2021年第3期565-570,共6页
采用NaOH对围场地区天然沸石进行处理,采用X射线衍射仪、红外光谱仪、N2吸附-脱附技术、扫描电子显微镜等对材料进行表征分析,采用水蒸气吸附法评价材料的亲水性,采用Cr3+和Mn2+评价材料的离子交换性能,探讨了碱处理对天然沸石的结构、... 采用NaOH对围场地区天然沸石进行处理,采用X射线衍射仪、红外光谱仪、N2吸附-脱附技术、扫描电子显微镜等对材料进行表征分析,采用水蒸气吸附法评价材料的亲水性,采用Cr3+和Mn2+评价材料的离子交换性能,探讨了碱处理对天然沸石的结构、亲水性和离子交换性能的影响及其机理。实验结果表明,围场地区天然沸石中主要含有斜发沸石、石英和伊利石;碱处理可降低天然沸石的硅铝比,且沸石的硅铝比随着碱处理浓度的提高而不断降低;碱处理对斜发沸石结构的影响较石英和伊利石更大;高浓度碱处理导致天然沸石的结构发生破坏,比表面积降低,孔体积提高;伴随着天然沸石硅铝比的降低,其亲水性和离子交换性能不断提高。 展开更多
关键词 天然沸石 碱处理 硅铝比 亲水性 离子交换性能
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随夯诊断技术研究与应用
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作者 赵民 贺可强 +2 位作者 陈小钰 于开宁 付浩 《建筑技术》 2021年第11期1307-1310,共4页
针对强夯设计的半经验性和夯实效果的不可控性,研究强夯过程监控指标与夯实质量的响应关系,自主研发了随夯诊断技术。该技术借助动静态载荷试验原理、能量耗散和碰撞理论研制了SMS装置,可实时诊断夯实效果。通过工程对比试验,验证了该... 针对强夯设计的半经验性和夯实效果的不可控性,研究强夯过程监控指标与夯实质量的响应关系,自主研发了随夯诊断技术。该技术借助动静态载荷试验原理、能量耗散和碰撞理论研制了SMS装置,可实时诊断夯实效果。通过工程对比试验,验证了该技术的准确性和可靠性,表明SMS装置性能稳定可靠,可为强夯动态设计和质量控制提供新思路。 展开更多
关键词 强夯 诊断 SMS装置 测试
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Primary study on evaluation index system for groundwater exploitation potentiality based on the niche theories 被引量:1
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作者 yu kai-ning LIAO An-ran 《Journal of Groundwater Science and Engineering》 2016年第1期18-25,共8页
Based on the groundwater resources evaluation, the groundwater exploitation potentiality evaluation is aiming at providing references for management, planning and development of groundwater. Traditional evaluation met... Based on the groundwater resources evaluation, the groundwater exploitation potentiality evaluation is aiming at providing references for management, planning and development of groundwater. Traditional evaluation methods mainly adopted individual indicator as a method which cannot fully reflect the affecting factors of the groundwater exploitation potential in a scientific way. The idea that the spatial distribution and dynamic change of groundwater is not only affected by socio-economic development and exploitation technology but also influenced by its regulation is coincided with the niche theory. This paper has preliminarily applied the niche theory to groundwater exploitation potential analysis, and proposed the concept of groundwater niche as well as its related definition, connotation and calculation formula. Meanwhile, by taking the Hebei Plain as an example, the article has made an evaluation of groundwater exploitation potentiality and a contrast with the results of the traditional evaluation methods on the construction of groundwater niche index system, and then verified the feasibility and rationality of this index system. It turns out that, it is truly comprehensive, scientific and rational to make groundwater niche calculation and exploitation potential analysis by using the evaluation index system. Niche theory has provided a new and fundamental attempt for the analysis and competition strategy for the groundwater exploitation potentiality evaluation. 展开更多
关键词 NICHE theory GROUNDWATER NICHE GROUNDWATER EXPLOITATION potential Evaluationindicators Hebei PLAIN
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Statistical characteristics of heavy metals content in groundwater and their interrelationships in a certain antimony mine area
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作者 yu kai-ning LI Jian +3 位作者 LI Hui CHEN Kang LV Bing-xu ZHAO Long-hui 《Journal of Groundwater Science and Engineering》 2016年第4期284-292,共9页
In recent years, most of domestic and foreign researches about heavy metal pollutions of metal mine mainly focus on water, soil and plants on the surface. There is lack of researches about heavy metal pollution in gro... In recent years, most of domestic and foreign researches about heavy metal pollutions of metal mine mainly focus on water, soil and plants on the surface. There is lack of researches about heavy metal pollution in groundwater of metal mine. In this research, a certain antimony mine area is selected as a typical study area. Also, the study about statistical characteristics of heavy metals in groundwater has been carried out. Furthermore, the interrelationships have been preliminarily discussed through related analysis, such as relevant analysis, cluster analysis and principle component analysis. The results show that: the excessive elements in groundwater of study area are Sb, As, Pb, Se, and Ni. The average mass concentration of Sb, As, and Pb is higher than that of drinking water standards(GB5749-2006). The concentration of most heavy metals in dry season is lower than or equal to that in wet season for groundwater. Zn is the only metal in groundwater showing a different pattern, the concentration of which in dry season is higher than that in wet season. Under the impacts of stratum leaching and absorption effect, the concentration of heavy metals(except Pb and Ba) in groundwater are lower than or equal to that in surface water. As and Se, the two heavy metals have a significant positive correlation, which shows the two elements might have gone through similar environmental geochemical effect. Also, the connection among Zn, Hg, Pb, and Mn is not obvious; therefore, the sources of those elements are quite different. In addition, the elements of Se and As have obvious positive interrelationship with elements of CO_3^(2-) and F^-. Also, the Pb has significant positive correlation with PO_4^(3-), H_2SiO_3 and oxygen consumption. The results of cluster analysis show that 9 different heavy metals in the study area can be divided into 3 categories: Zn, Cd, Mn, Hg, Cu, and Cr belong to the first category, Se and As belong to the second one, and the last category is Pb. Also, the principle component analysis divides 6 heavy metals(Zn, As, Hg, Pb, Mn, and Se) into 4 different principle components, which can be utilized to assess heavy metals pollution situations in groundwater. The reliability of this method is higher than 91%. Moreover, the research provides theory basis and models for establishing evaluation index system and exploring the evaluation method of heavy mental pollution in groundwater. 展开更多
关键词 GROUNDWATER Heavy metals CONTENT Statistical characteristics INTERRELATIONSHIPS Antimony mine
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西宁市浅层地下水化学特征及形成机制 被引量:15
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作者 刘春燕 于开宁 +2 位作者 张英 荆继红 刘景涛 《环境科学》 EI CAS CSCD 北大核心 2023年第6期3228-3236,共9页
地下水是西部干旱地区重要的供水水源,随着西部大开发战略的深入,工业化和城市化发展加大了西宁市对地下水资源量的需求,不合理的开发利用已引起地下水环境发生变化,探明地下水化学演化特征及形成机制,对防止其恶化,确保可持续利用至关... 地下水是西部干旱地区重要的供水水源,随着西部大开发战略的深入,工业化和城市化发展加大了西宁市对地下水资源量的需求,不合理的开发利用已引起地下水环境发生变化,探明地下水化学演化特征及形成机制,对防止其恶化,确保可持续利用至关重要.运用水化学和多元统计技术相结合的方法,分析了西宁市地下水化学特征,探讨了地下水的形成机制和不同因子的影响程度.结果表明,西宁市浅层地下水化学类型多达36种,以HCO_(3)-Ca(Mg)(占比60.00%)和HCO_(3)·SO_(4)-Ca(Mg)(占比11.81%)为主,草地、林地和裸地中地下水化学类型5~6种,建设用地和耕地中地下水化学类型复杂,多达21种,表明受到人类活动影响较强.研究区地下水化学演化过程主要受岩石风化溶滤、蒸发结晶和阳离子交换作用综合影响,主要控制因素分别是水-岩相互作用(贡献率为27.56%)、工业废水排放(贡献率为16.16%)、酸碱环境(贡献率为16.00%)、化肥、农药的过量施用(贡献率为13.11%)和生活污水(贡献率为8.82%).针对西宁市地下水化学特征及其人类活动影响,提出了地下水资源开发利用方面的管控建议. 展开更多
关键词 西宁市 地下水 水化学特征 形成机制 多元统计 控制因素
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