Bis（diphenylphosphinyl）butadiyne reacted with methylcyclopentadiene at room temperature and four isomeric products were obtained. Crystal structures of isomers 1 and 3 have been determined. Crystal data for compound...Bis（diphenylphosphinyl）butadiyne reacted with methylcyclopentadiene at room temperature and four isomeric products were obtained. Crystal structures of isomers 1 and 3 have been determined. Crystal data for compound 1 C40H36O2P2·2CHCl3： monoclinic, space group C12/c1 with a = 17.983（2）, b = 11.8723（12）, c = 20.081（2） A, β = 111.218（3）°, V= 3996.5（8） A^3, Z = 4, Mr= 849.36, Dc = 1.412 g/cm^3, F（000） = 1752,μ = 0.546 mm^-1, the final R = 0.0351 and wR = 0.0951 for 3965 observed reflections （I 〉 2σ（I））; and those for compound 3 C40H36O2P2·H2O： triclinic, space group PI with a = 10.4144（15）, b = 13.0558（18）, c = 13.742（2） A, a = 70.453（8）, β = 75.382（8）, γ = 72.312（8）°, V = 1653.7（4） A^3, Z = 2, Mr= 628.64, Dc = 1.262 g/cm^3, F（000） = 664,μ = 0.169 mm^-1, the final R = 0.0593 and wR = 0.1296 for 4891 observed reflections （I 〉 2σ（I））. The structures of the other two isomers are identified via IR, ^1H NMR and MS spectra.展开更多
In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant househ...In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant households' input of chemical fertilizer in apple orchard, and collect soil samples for measuring and analysis. The results show that the average input of nitrogen, phosphorus and potassium nutrient is 839.6 kg/hm2, 520.4 kg/hm2, and 899.7 kg/hm2, respectively; the input proportion of nitrogen to phosphorus to potassium nutrient is 1∶0.62∶1.07; in 0-60cm soil, the average content of alkali-hydrolyzable nitrogen is 53.49 mg/kg, the average content of available phosphorus in soil is 70.73 kg/mg, and the average content of available potassium in soil is 180.1 mg/kg (the proportion of alkali-hydrolyzable nitrogen to available phosphorus to available potassium in soil is 1:1.32:3.37). It indicates that the overall level of input of chemical fertilizer in apple orchard is relatively high; the content of alkali-hydrolyzable nitrogen in soil is very low on the whole, the content of available phosphorus in soil is very high, and the content of available potassium in soil is high.展开更多
A scheme for probabilistic teleportation of an unknown three-atom entangled state via a five-atom non- maximally entangled cluster state as quantum channel is proposed. In this scheme, the sender performs two Bell sta...A scheme for probabilistic teleportation of an unknown three-atom entangled state via a five-atom non- maximally entangled cluster state as quantum channel is proposed. In this scheme, the sender performs two Bell state and a single-atom measurements on the atoms, the receiver can reconstruct the original state with a certain probability by introducing an auxiliary atom and operating appropriate unitary transformations and controlled-not （C-not） operations according to the sender Alice＇s measurement results. As a result, the probability of successful teleportation is determined by the smallest two of the coefficients＇ absolute values of the cluster state. The considerable advantage of our scheme is that we employ a non-maximally entangled cluster state as quantum channel in the scheme, which can greatly reduce the amount of entanglement resources and need less classical bits. If we employ a maximally entangled cluster state as quantum channel, the probabilistic teleportation scheme becomes usual teleportation, the successful probability being 100%.展开更多
基金Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars and the State Education Ministry
文摘Bis（diphenylphosphinyl）butadiyne reacted with methylcyclopentadiene at room temperature and four isomeric products were obtained. Crystal structures of isomers 1 and 3 have been determined. Crystal data for compound 1 C40H36O2P2·2CHCl3： monoclinic, space group C12/c1 with a = 17.983（2）, b = 11.8723（12）, c = 20.081（2） A, β = 111.218（3）°, V= 3996.5（8） A^3, Z = 4, Mr= 849.36, Dc = 1.412 g/cm^3, F（000） = 1752,μ = 0.546 mm^-1, the final R = 0.0351 and wR = 0.0951 for 3965 observed reflections （I 〉 2σ（I））; and those for compound 3 C40H36O2P2·H2O： triclinic, space group PI with a = 10.4144（15）, b = 13.0558（18）, c = 13.742（2） A, a = 70.453（8）, β = 75.382（8）, γ = 72.312（8）°, V = 1653.7（4） A^3, Z = 2, Mr= 628.64, Dc = 1.262 g/cm^3, F（000） = 664,μ = 0.169 mm^-1, the final R = 0.0593 and wR = 0.1296 for 4891 observed reflections （I 〉 2σ（I））. The structures of the other two isomers are identified via IR, ^1H NMR and MS spectra.
基金Supported by Science and Technology Development Plan of Yantai (2010322)
文摘In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant households' input of chemical fertilizer in apple orchard, and collect soil samples for measuring and analysis. The results show that the average input of nitrogen, phosphorus and potassium nutrient is 839.6 kg/hm2, 520.4 kg/hm2, and 899.7 kg/hm2, respectively; the input proportion of nitrogen to phosphorus to potassium nutrient is 1∶0.62∶1.07; in 0-60cm soil, the average content of alkali-hydrolyzable nitrogen is 53.49 mg/kg, the average content of available phosphorus in soil is 70.73 kg/mg, and the average content of available potassium in soil is 180.1 mg/kg (the proportion of alkali-hydrolyzable nitrogen to available phosphorus to available potassium in soil is 1:1.32:3.37). It indicates that the overall level of input of chemical fertilizer in apple orchard is relatively high; the content of alkali-hydrolyzable nitrogen in soil is very low on the whole, the content of available phosphorus in soil is very high, and the content of available potassium in soil is high.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 11147134, 11273008, and 51271059 and the Natural Science Foundation of Anhui Province University under Grant Nos. 2013A205 and 2012Z309
文摘A scheme for probabilistic teleportation of an unknown three-atom entangled state via a five-atom non- maximally entangled cluster state as quantum channel is proposed. In this scheme, the sender performs two Bell state and a single-atom measurements on the atoms, the receiver can reconstruct the original state with a certain probability by introducing an auxiliary atom and operating appropriate unitary transformations and controlled-not （C-not） operations according to the sender Alice＇s measurement results. As a result, the probability of successful teleportation is determined by the smallest two of the coefficients＇ absolute values of the cluster state. The considerable advantage of our scheme is that we employ a non-maximally entangled cluster state as quantum channel in the scheme, which can greatly reduce the amount of entanglement resources and need less classical bits. If we employ a maximally entangled cluster state as quantum channel, the probabilistic teleportation scheme becomes usual teleportation, the successful probability being 100%.
