漂浮式海上风机的应用带动了动态海缆的发展。由于应用环境较为复杂,动态缆需要具有很好的抗拉伸能力和易弯曲性。在动态缆截面设计过程中,填充形式是否会影响到其力学性能有待进一步研究。本文基于UFLEX2D软件,采用有限元方法计算了3...漂浮式海上风机的应用带动了动态海缆的发展。由于应用环境较为复杂,动态缆需要具有很好的抗拉伸能力和易弯曲性。在动态缆截面设计过程中,填充形式是否会影响到其力学性能有待进一步研究。本文基于UFLEX2D软件,采用有限元方法计算了3种常见填充形式下的26/35k V 3×70mm^(2)动态海缆的拉伸性能和弯曲性能,并将仿真分析结果与理论值、实测值进行对比。研究结果表明,填充形式会影响动态缆的拉伸性能但不明显,对于弯曲性能无影响。总体而言,截面设计过程中填充形式的选择仅需考虑是否能够维持电缆的圆整度。展开更多
In this paper, a novel compound 3-（2-qninolyl）-5-ferrocenyl-isoxazole（5） with high selectivity toward Cu2＋ over other heavy and transition-metal（HTM） ions was designed and synthesized in good yields. The compou...In this paper, a novel compound 3-（2-qninolyl）-5-ferrocenyl-isoxazole（5） with high selectivity toward Cu2＋ over other heavy and transition-metal（HTM） ions was designed and synthesized in good yields. The compound not only could be used as an electrochemical probe for Cu2＋ with an anodic peak shift of Fe（II）/Fe（III） redox couple, but also could be a colorimetric and fluorescent probe due to the detectable change in color by naked eyes and a significant fluorescence quenching of monomeric anthracene moiety. This highly selective sensing of Cu2＋ may be attributed to the unprecedented intermolecular electron-transfer reorganization after the oxidation of the first single electron of compound 5, as indicated by electrospray ionization mass spectrometry（ESI-MS） and density functional theory（DFT） calculation results. To the best of our knowledge, this class of compounds have rarely been reported in the field of molecular sensing. It may have a potential significance for the application of the ferrocenyl-isoxazole derivative in molecular recognition.展开更多
文摘漂浮式海上风机的应用带动了动态海缆的发展。由于应用环境较为复杂,动态缆需要具有很好的抗拉伸能力和易弯曲性。在动态缆截面设计过程中,填充形式是否会影响到其力学性能有待进一步研究。本文基于UFLEX2D软件,采用有限元方法计算了3种常见填充形式下的26/35k V 3×70mm^(2)动态海缆的拉伸性能和弯曲性能,并将仿真分析结果与理论值、实测值进行对比。研究结果表明,填充形式会影响动态缆的拉伸性能但不明显,对于弯曲性能无影响。总体而言,截面设计过程中填充形式的选择仅需考虑是否能够维持电缆的圆整度。
基金Supported by the National Natural Science Foundation of China（Nos.21172001, 21372008）, the Natural Science Foundation of the Education Administration of Anhni Province, China（No.K J2016A267）, the Special and Excellent Research Fund of Anhui Normal University, China and the Doctoral Scientific Research Foundation of Anhui Normal University, China（No.2016XJJ110）.
文摘In this paper, a novel compound 3-（2-qninolyl）-5-ferrocenyl-isoxazole（5） with high selectivity toward Cu2＋ over other heavy and transition-metal（HTM） ions was designed and synthesized in good yields. The compound not only could be used as an electrochemical probe for Cu2＋ with an anodic peak shift of Fe（II）/Fe（III） redox couple, but also could be a colorimetric and fluorescent probe due to the detectable change in color by naked eyes and a significant fluorescence quenching of monomeric anthracene moiety. This highly selective sensing of Cu2＋ may be attributed to the unprecedented intermolecular electron-transfer reorganization after the oxidation of the first single electron of compound 5, as indicated by electrospray ionization mass spectrometry（ESI-MS） and density functional theory（DFT） calculation results. To the best of our knowledge, this class of compounds have rarely been reported in the field of molecular sensing. It may have a potential significance for the application of the ferrocenyl-isoxazole derivative in molecular recognition.
