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基于苯基功能化纤维状Fe3O4@SiO2@KCC-1的磁性固相萃取-高效液相色谱测定环境水样中的邻苯二甲酸酯 被引量:2
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作者 周学政 闫向阳 +6 位作者 朱玲 马明 戴亚 汪长国 朱立军 虞柯洁 刘少民 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第6期749-756,I0003,共9页
本文采用共聚法制备了一种新型苯基功能化纤维状Fe3O4@SiO2@KCC-1(Fe3O4@SiO2@KCC-1-phenyl)材料,用于环境水样中邻苯二甲酸酯的磁性萃取.制备的Fe3O4@SiO2@KCC-1-phenyl展现了单分散的球形纤维状、较强的磁性(29 emu/g)和一个丰富的π... 本文采用共聚法制备了一种新型苯基功能化纤维状Fe3O4@SiO2@KCC-1(Fe3O4@SiO2@KCC-1-phenyl)材料,用于环境水样中邻苯二甲酸酯的磁性萃取.制备的Fe3O4@SiO2@KCC-1-phenyl展现了单分散的球形纤维状、较强的磁性(29 emu/g)和一个丰富的π电子体系.研究和优化了洗脱溶剂的种类、吸附剂的用量、萃取时间和可重复使用性等因素对分析物萃取效率的影响.在最佳条件下,用高效液相色谱方法,采用Fe3O4@SiO2@KCC-1-phenyl萃取分离及测定环境水样中的邻苯二甲酸酯类化合物.结果表明,本方法具有良好的线性(0.1~20 ng/mL)、低的检测限(7.5~29μg/L,S/N=3).将该方法应用于不同环境水样中邻苯二甲酸酯类化合物的测定,回收率为93%~103.4%,相对标准偏差为0.8%~8.3%. 展开更多
关键词 纤维状介孔二氧化硅 苯基功能化 磁性固相萃取 高效液相色谱 邻苯二甲酸酯类 环境水
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Global expression profile of silkworm genes from larval to pupal stages: Toward a comprehensive understanding of sexual differences
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作者 Min Zhao Xing-Fu Zha +6 位作者 Jin Liu Wen-Ji Zhang Ning-Jia He Dao-Jun Cheng ya dai Zhong-Huai Xiang Qing-You Xia 《Insect Science》 SCIE CAS CSCD 2011年第6期607-618,共12页
Sexual dimorphism is a widespread phenomenon in many higher animals. The genes and gene networks that underlie sex differences are poorly understood. Using microarray data we analyzed sex-related differences in the gl... Sexual dimorphism is a widespread phenomenon in many higher animals. The genes and gene networks that underlie sex differences are poorly understood. Using microarray data we analyzed sex-related differences in the global expression profiles of silkworm genes from larval to pupal stages. Sex-biased genes could be divided into three clusters. Cluster 1 contained 932 genes that showed a female-biased expression trend at first and a male-biased trend afterward. Cluster 2 included 283 male-biased genes. Cluster 3 was comprised of 497 female-biased genes that were expressed during the late pupal stage. Cluster 1 genes were found to be related closely to cuticle proteins, hormones, binding proteins, enzyme regulators, structural proteins, transcription regulators and so on. Several genes in clusters 2 and 3 were associated with spermatogenesis and oogenesis, respectively. The chromosomal distribution of sex-biased genes showed evidence of chromosomal enrichment. In particular a large number of the silkworms' male-biased genes are located on the Z chromosome. These results provide new insights into the molecular differences that dictate sexual dimorphism in the silkworm. 展开更多
关键词 Bombyx mori microarray sex-biased gene sexual dimorphism
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Structural design and performance analysis of China’s Local Government Financing Vehicles
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作者 Liang Guo Erzhuo Liu ya dai 《Economic and Political Studies》 2020年第2期203-223,共21页
In this paper,we investigate the reasons for the establishment and operation models of China’s Local Government Financing Vehicles(LGFVs).We also outline the current literature on the structural arrangement and the d... In this paper,we investigate the reasons for the establishment and operation models of China’s Local Government Financing Vehicles(LGFVs).We also outline the current literature on the structural arrangement and the developments of LGFVs.Moreover,we employ the empirical analysis to examine the driv-ing factors of the financial performance of LGFVs.Using 1,042 LGFVs that issued debt securities during the period 2011–2016,we find that the financial performance of LGFVs is positively asso-ciated with local tax revenues,local education levels,local saving deposits,and firm size but negatively associated with local gov-ernment spending and firm leverage ratios.Based on our empir-ical findings,we finally propose policy recommendations for the establishment of relevant investment and financing platforms. 展开更多
关键词 Local Government Financing Vehicles financial performance struc-tural design
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