The solubility,metastable zone width(MSZW),and induction time of thiourea for cooling crystallization were experimentally determined in the temperature range of 283-323 K.The solubility data could be well described by...The solubility,metastable zone width(MSZW),and induction time of thiourea for cooling crystallization were experimentally determined in the temperature range of 283-323 K.The solubility data could be well described by the Apelblat equation model as lnx=-99.55+1071.66/T+16.27 lnT.The determinations of the effects of various stirring and cooling rates indicated that the MSZW increased with increasing and decreasing cooling and stirring rates,respectively.Furthermore,the induction times at various temperatures and supersaturation ratios were also measured.The results indicated that homogeneous nucleation could occur at high supersaturation,whereas heterogeneous nucleation was more likely to occur at low supersaturation.Based on the classical nucleation theory and induction period data,the calculated solid-liquid interfacial tensions of thiourea in deionized water at 302.46 and 312.58 K were 2.86 and 2.94 mJ·m^(-2),respectively.展开更多
Crustal deformation and deep metallogenic mechanisms in southeastern(SE)China are still debated.In this study,we applied the receiver function method to measure crustal thickness and Poisson’s ratio for crustal rock ...Crustal deformation and deep metallogenic mechanisms in southeastern(SE)China are still debated.In this study,we applied the receiver function method to measure crustal thickness and Poisson’s ratio for crustal rock using teleseismic data recorded at 207 seismic stations from China Earthquake Administration Network.The results showed that crustal thickness varied from~27 km in the eastern part to~43 km in the western part of the study area,with an average crustal thickness of 31 km.The crust is thick in the west and thin in the east.The observed Poisson’s ratio for crustal rock was relatively high in the southern Cathaysia Block(CB),with an average of 0.295,while in the Qinling—Dabie terrane,it was relatively low,with an average of 0.257.In the middle of the Yangtze craton and central east of the CB,Poisson’s ratio for crustal rock varied from 0.257 to 0.286.By comparing Poisson’s ratio of the intrusive deposits with that of igneous rocks in volcanic complexes,we deduced that the metallic mineral system might be associated with orogenic and hydrothermal deposits.These results indicated that multistage magma and mineralization in the study area might be attributed to the tectonic-magma-thermal event.The high Poisson’s ratio for crustal rock in the southeastern margin of the CB and northeastern Upper Yangtze Craton might be related to Mesozoic lower crustal mafic partial melt,which provides an important environment for various magmatic intrusions and metallogenies.展开更多
To the Editor:Pulmonary nodules are defined as localized opacities of up to 30 mm in diameter,surrounded by pulmonary parenchyma or located adjacent to the pleura.^([1])The ideal management for pulmonary nodules is to...To the Editor:Pulmonary nodules are defined as localized opacities of up to 30 mm in diameter,surrounded by pulmonary parenchyma or located adjacent to the pleura.^([1])The ideal management for pulmonary nodules is to diagnose and treat malignant nodules as early as possible and minimize radiation exposures,based on the general guidance.Clinical practice guidelines(CPGs)always provide efficient recommendations based on systematic reviews of high-quality evidence and reporting to optimize patient care.^([2])Accumulating evidence shows that adherence to the guidelines improves patient outcomes.^([3])However,the reporting quality of CPGs seems poor.^([4])Several instruments have been generated to evaluate the quality of CPGs.展开更多
To the Editor:Transthoracic needle aspiration(TTNA)and bronchoscopy have been the preferred methods for the sampling of pulmonary nodules suspected of lung cancer.However,despite having a higher diagnostic accuracy,TT...To the Editor:Transthoracic needle aspiration(TTNA)and bronchoscopy have been the preferred methods for the sampling of pulmonary nodules suspected of lung cancer.However,despite having a higher diagnostic accuracy,TTNA has been associated with a high rate of pneumothorax.Moreover,conventional bronchoscopy with a low rate of pneumothorax has exhibited a low diagnostic yield for peripheral pulmonary nodules,particularly for nodules<2 cm in size or those without a bronchus leading directly to them.Thus,Herth et al[1]developed a novel bronchoscopy technique called bronchoscopic transparenchymal nodule access(BTPNA)under the guidance of Archimedes Virtual Bronchoscopic Navigation(VBN)System for the purpose of accessing pulmonary nodules using a transparenchymal approach without relying on the airway to approach the lesion.Here,we systematically reviewed evidence regarding BTPNA to provide general guidance on the safe implementation and development of this novel approach.展开更多
Ni-rich cathode materials will be primarily used as next-generation high-specific energy cathode materials in lithium-ion batteries.However,residual Li formation and cracking considerably restrict the wide application...Ni-rich cathode materials will be primarily used as next-generation high-specific energy cathode materials in lithium-ion batteries.However,residual Li formation and cracking considerably restrict the wide application of these materials.To address the issues related to cracking,micro-sized single-crystal cathode materials without internal grain boundaries are proposed.In this study,we constructed a thin LiBO_(2)layer on the single-crystal LiNi_(0.83)Co_(0.07)Mn_(0.10)O_(2)particles by solvent-free H_(3)BO_(3)modification.The residual Li on the material surface decreased by 14%through the reaction of LiOH/Li_(2)CO_(3)and H_(3)BO_(3).The coated materials exhibited higher initial Coulombic efficiency(88.44%),higher reversible capacity(213.4 mAh·g^(-1)at 0.1 C),and better cycling performance(91.31%retention over 50 cycles within 3.0-4.3 V at 1.0C)than the unmodified materials.Using the galvanostatic intermittent titration technique,electrochemical impedance spectroscopy(EIS),and inductively coupled plasma-optical emission spectroscopy(ICP-OES),we reveal the mechanism by which the electrochemical properties are improved upon H_(3)BO_(3)modification.The superior electrochemical performances are associated with increased Li+conductivity,lower charge transfer impedance,and suppressed transition metal dissolution.Therefore,this study demonstrates the importance of surface modification in obtaining Ni-rich single-crystal materials with enhanced performance.展开更多
To the Editor:The vaccine-related adaptive immune systems,including humoral immunity induced by B cell reaction and cellular immunity induced by T cells,are crucial for controlling severe acute respiratory syndrome co...To the Editor:The vaccine-related adaptive immune systems,including humoral immunity induced by B cell reaction and cellular immunity induced by T cells,are crucial for controlling severe acute respiratory syndrome coronavirus-2(SARS-CoV-2)infection.[1]Therefore,it is vital to clarify the immune changes caused by inactivated vaccines,which are most commonly used in China,for evaluating the protective effect of vaccines and formulating vaccination plans.展开更多
With the increase in applied voltage and the decrease in volume,integrated electronic modules have become electrostatic sensitive.ZnO microvaristors doped silicone rubber(SiR)composite,with electric field‐dependent c...With the increase in applied voltage and the decrease in volume,integrated electronic modules have become electrostatic sensitive.ZnO microvaristors doped silicone rubber(SiR)composite,with electric field‐dependent conductivity,shows promising prospects for solving the electrostatic problem.In this study,20 vol%to 50 vol%ZnO/SiR composite films,filled with 10–30μm ZnO microvaristors,were prepared and put into the test of electrostatic discharge.Compared with the insulating and conducting materials,ZnO/SiR composites achieve the lowest initial voltage and a short time constant of electrostatic discharge.With the increase of ZnO microvaristors volume fraction,from 20%to 50%,the initial voltage and the time constant of electrostatic discharge drop from 1.78 to 0.72 kV and 3.1 ms to 0.4μs.When the ZnO volume fraction is higher than 30%,there is no residual voltage after 0.1 s.To explore the reason behind different electrostatic discharge performances of the ZnO/SiR composites,the conductivities of the com-posites were measured.It is found that the break‐over voltage of the composite drops with the increase in the ZnO microvaristors volume fraction.When a high voltage im-pulse is applied on the ZnO/SiR film,the composite will turn to the conducting state and release the electrostatic charge adaptively so that the initial voltage can be controlled.This work supplies a novel electrostatic discharge idea for electric and electronic devices.展开更多
Spinel phase LiMn2O4 was successfully embedded into monoclinic phase layered- structured Li2MnO3 nanorods, and these spineMayered integrate structured nanorods showed both high capacities and superior high-rate capabi...Spinel phase LiMn2O4 was successfully embedded into monoclinic phase layered- structured Li2MnO3 nanorods, and these spineMayered integrate structured nanorods showed both high capacities and superior high-rate capabilities as cathode material for lithium-ion batteries (LIBs). Pristine Li2MnO3 nanorods were synthesized by a simple rheological phase method using α-MnO2 nanowires as precursors. The spinel-layered integrate structured nanorods were fabricated by a facile partial reduction reaction using stearic acid as the reductant. Both structural characterizations and electrochemical properties of the integrate structured nanorods verified that LiMn2O4 nanodomains were embedded inside the pristine Li2MnO3 nanorods. When used as cathode materials for LIBs, the spineMayered integrate structured Li2MnO3 nanorods (SL-Li2MnO3) showed much better performances than the pristine layered-structured Li2MnO3 nanorods (L-Li2MnO3). When charge-discharged at 20 mA.g-1 in a voltage window of 2.0-4.8 V, the SL-Li2MnO3 showed discharge capacities of 272.3 and 228.4 mAh.g-1 in the first and the 60th cycles, respectively, with capacity retention of 83.8%. The SL-Li2MnO3 also showed superior high-rate performances. When cycled at rates of 1 C, 2 C, 5 C, and 10 C (1 C = 200 mA-g-1) for hundreds of cycles, the discharge capacities of the SL-Li2MnO3 reached 218.9, 200.5, 147.1, and 123.9 mAh-g-1, respectively. The superior performances of the SL-Li2MnO3 are ascribed to the spineMayered integrated structures. With large capacities and superior high-rate performances, these spinel-layered integrate structured materials are good candidates for cathodes of next-generation high-power LIBs.展开更多
ZnO microvaristors/epoxy resin composite has drawn great attention from academia and industry for its adjustable non‐linear conductivity,high mechanical strength,and good ageing resistance.However,the sedimentation o...ZnO microvaristors/epoxy resin composite has drawn great attention from academia and industry for its adjustable non‐linear conductivity,high mechanical strength,and good ageing resistance.However,the sedimentation of ZnO microvaristors in epoxy resin during preparation is the key problem,which limits its application in engineering.In this study,a novel method of wet winding with polyester fibre cloth is proposed to prepare the ZnO microvaristors/epoxy resin composite.The anti‐settling effect of ZnO micro-varistors in the composite is verified by scanning electron microscopy(SEM)and thermal gravimetric analysis(TGA).The microstructure shows that ZnO microvaristors distribute uniformly in the composite,and the content difference of ZnO microvaristors at the top and bottom part is only 0.4%.The composite shows typical non‐linear conductivity,and the threshold electric field and the non‐linear coefficient decrease with the content of ZnO microvaristors,while the conductivity in the insulating state shows an increasing trend.To verify the field grading effect of the composite with non‐linear conductivity(CNC),a finite element model of a needle‐plate electrode,simulating the condition of a conductive tip in a solid insulated system,is set up.CNC can adaptively grade the electric field,which reduces the surface electric field of the needle tip by 86.6%and the highest electric field in the system by 82.1%.This wet winding method solidifies the industrial application of CNC in high‐voltage power equipment.展开更多
基金supported by Top-notch Academic Programs Project of Jiangsu Higher Education Institution(TAPP)Priority Academic Program Development of Jiangsu Higher Education Institutions(PPZY2015A044)support from Jingbo Nanjing Tech University Research Institute(JBNT-2020-003)。
文摘The solubility,metastable zone width(MSZW),and induction time of thiourea for cooling crystallization were experimentally determined in the temperature range of 283-323 K.The solubility data could be well described by the Apelblat equation model as lnx=-99.55+1071.66/T+16.27 lnT.The determinations of the effects of various stirring and cooling rates indicated that the MSZW increased with increasing and decreasing cooling and stirring rates,respectively.Furthermore,the induction times at various temperatures and supersaturation ratios were also measured.The results indicated that homogeneous nucleation could occur at high supersaturation,whereas heterogeneous nucleation was more likely to occur at low supersaturation.Based on the classical nucleation theory and induction period data,the calculated solid-liquid interfacial tensions of thiourea in deionized water at 302.46 and 312.58 K were 2.86 and 2.94 mJ·m^(-2),respectively.
基金financially supported by the National Natural Science Foundation of China(Nos.41974049,42074165)the Science and Technology on Parallel and Distributed Processing Laboratory,China(No.6142110180202)。
文摘Crustal deformation and deep metallogenic mechanisms in southeastern(SE)China are still debated.In this study,we applied the receiver function method to measure crustal thickness and Poisson’s ratio for crustal rock using teleseismic data recorded at 207 seismic stations from China Earthquake Administration Network.The results showed that crustal thickness varied from~27 km in the eastern part to~43 km in the western part of the study area,with an average crustal thickness of 31 km.The crust is thick in the west and thin in the east.The observed Poisson’s ratio for crustal rock was relatively high in the southern Cathaysia Block(CB),with an average of 0.295,while in the Qinling—Dabie terrane,it was relatively low,with an average of 0.257.In the middle of the Yangtze craton and central east of the CB,Poisson’s ratio for crustal rock varied from 0.257 to 0.286.By comparing Poisson’s ratio of the intrusive deposits with that of igneous rocks in volcanic complexes,we deduced that the metallic mineral system might be associated with orogenic and hydrothermal deposits.These results indicated that multistage magma and mineralization in the study area might be attributed to the tectonic-magma-thermal event.The high Poisson’s ratio for crustal rock in the southeastern margin of the CB and northeastern Upper Yangtze Craton might be related to Mesozoic lower crustal mafic partial melt,which provides an important environment for various magmatic intrusions and metallogenies.
文摘To the Editor:Pulmonary nodules are defined as localized opacities of up to 30 mm in diameter,surrounded by pulmonary parenchyma or located adjacent to the pleura.^([1])The ideal management for pulmonary nodules is to diagnose and treat malignant nodules as early as possible and minimize radiation exposures,based on the general guidance.Clinical practice guidelines(CPGs)always provide efficient recommendations based on systematic reviews of high-quality evidence and reporting to optimize patient care.^([2])Accumulating evidence shows that adherence to the guidelines improves patient outcomes.^([3])However,the reporting quality of CPGs seems poor.^([4])Several instruments have been generated to evaluate the quality of CPGs.
文摘To the Editor:Transthoracic needle aspiration(TTNA)and bronchoscopy have been the preferred methods for the sampling of pulmonary nodules suspected of lung cancer.However,despite having a higher diagnostic accuracy,TTNA has been associated with a high rate of pneumothorax.Moreover,conventional bronchoscopy with a low rate of pneumothorax has exhibited a low diagnostic yield for peripheral pulmonary nodules,particularly for nodules<2 cm in size or those without a bronchus leading directly to them.Thus,Herth et al[1]developed a novel bronchoscopy technique called bronchoscopic transparenchymal nodule access(BTPNA)under the guidance of Archimedes Virtual Bronchoscopic Navigation(VBN)System for the purpose of accessing pulmonary nodules using a transparenchymal approach without relying on the airway to approach the lesion.Here,we systematically reviewed evidence regarding BTPNA to provide general guidance on the safe implementation and development of this novel approach.
基金financially supported by China Postdoctoral Science Foundation(Nos.2021M690478 and 2021M700523)。
文摘Ni-rich cathode materials will be primarily used as next-generation high-specific energy cathode materials in lithium-ion batteries.However,residual Li formation and cracking considerably restrict the wide application of these materials.To address the issues related to cracking,micro-sized single-crystal cathode materials without internal grain boundaries are proposed.In this study,we constructed a thin LiBO_(2)layer on the single-crystal LiNi_(0.83)Co_(0.07)Mn_(0.10)O_(2)particles by solvent-free H_(3)BO_(3)modification.The residual Li on the material surface decreased by 14%through the reaction of LiOH/Li_(2)CO_(3)and H_(3)BO_(3).The coated materials exhibited higher initial Coulombic efficiency(88.44%),higher reversible capacity(213.4 mAh·g^(-1)at 0.1 C),and better cycling performance(91.31%retention over 50 cycles within 3.0-4.3 V at 1.0C)than the unmodified materials.Using the galvanostatic intermittent titration technique,electrochemical impedance spectroscopy(EIS),and inductively coupled plasma-optical emission spectroscopy(ICP-OES),we reveal the mechanism by which the electrochemical properties are improved upon H_(3)BO_(3)modification.The superior electrochemical performances are associated with increased Li+conductivity,lower charge transfer impedance,and suppressed transition metal dissolution.Therefore,this study demonstrates the importance of surface modification in obtaining Ni-rich single-crystal materials with enhanced performance.
基金Emergency Scientific Research on Novel Coronavirus Prevention and Control of Henan Province(No.221111311500)
文摘To the Editor:The vaccine-related adaptive immune systems,including humoral immunity induced by B cell reaction and cellular immunity induced by T cells,are crucial for controlling severe acute respiratory syndrome coronavirus-2(SARS-CoV-2)infection.[1]Therefore,it is vital to clarify the immune changes caused by inactivated vaccines,which are most commonly used in China,for evaluating the protective effect of vaccines and formulating vaccination plans.
基金supported in part by National Key R&D Program of China under Grant 2018YFE0200100Natural Science Foundation of China under Grant 52125703.
文摘With the increase in applied voltage and the decrease in volume,integrated electronic modules have become electrostatic sensitive.ZnO microvaristors doped silicone rubber(SiR)composite,with electric field‐dependent conductivity,shows promising prospects for solving the electrostatic problem.In this study,20 vol%to 50 vol%ZnO/SiR composite films,filled with 10–30μm ZnO microvaristors,were prepared and put into the test of electrostatic discharge.Compared with the insulating and conducting materials,ZnO/SiR composites achieve the lowest initial voltage and a short time constant of electrostatic discharge.With the increase of ZnO microvaristors volume fraction,from 20%to 50%,the initial voltage and the time constant of electrostatic discharge drop from 1.78 to 0.72 kV and 3.1 ms to 0.4μs.When the ZnO volume fraction is higher than 30%,there is no residual voltage after 0.1 s.To explore the reason behind different electrostatic discharge performances of the ZnO/SiR composites,the conductivities of the com-posites were measured.It is found that the break‐over voltage of the composite drops with the increase in the ZnO microvaristors volume fraction.When a high voltage im-pulse is applied on the ZnO/SiR film,the composite will turn to the conducting state and release the electrostatic charge adaptively so that the initial voltage can be controlled.This work supplies a novel electrostatic discharge idea for electric and electronic devices.
文摘Spinel phase LiMn2O4 was successfully embedded into monoclinic phase layered- structured Li2MnO3 nanorods, and these spineMayered integrate structured nanorods showed both high capacities and superior high-rate capabilities as cathode material for lithium-ion batteries (LIBs). Pristine Li2MnO3 nanorods were synthesized by a simple rheological phase method using α-MnO2 nanowires as precursors. The spinel-layered integrate structured nanorods were fabricated by a facile partial reduction reaction using stearic acid as the reductant. Both structural characterizations and electrochemical properties of the integrate structured nanorods verified that LiMn2O4 nanodomains were embedded inside the pristine Li2MnO3 nanorods. When used as cathode materials for LIBs, the spineMayered integrate structured Li2MnO3 nanorods (SL-Li2MnO3) showed much better performances than the pristine layered-structured Li2MnO3 nanorods (L-Li2MnO3). When charge-discharged at 20 mA.g-1 in a voltage window of 2.0-4.8 V, the SL-Li2MnO3 showed discharge capacities of 272.3 and 228.4 mAh.g-1 in the first and the 60th cycles, respectively, with capacity retention of 83.8%. The SL-Li2MnO3 also showed superior high-rate performances. When cycled at rates of 1 C, 2 C, 5 C, and 10 C (1 C = 200 mA-g-1) for hundreds of cycles, the discharge capacities of the SL-Li2MnO3 reached 218.9, 200.5, 147.1, and 123.9 mAh-g-1, respectively. The superior performances of the SL-Li2MnO3 are ascribed to the spineMayered integrated structures. With large capacities and superior high-rate performances, these spinel-layered integrate structured materials are good candidates for cathodes of next-generation high-power LIBs.
基金supported in part the National Key R&D Program of China under Grant No 2018YFE0200101the Natural Science Foundation of China under Grant No U1766221the Shuimu Tsinghua Scholar Program。
文摘ZnO microvaristors/epoxy resin composite has drawn great attention from academia and industry for its adjustable non‐linear conductivity,high mechanical strength,and good ageing resistance.However,the sedimentation of ZnO microvaristors in epoxy resin during preparation is the key problem,which limits its application in engineering.In this study,a novel method of wet winding with polyester fibre cloth is proposed to prepare the ZnO microvaristors/epoxy resin composite.The anti‐settling effect of ZnO micro-varistors in the composite is verified by scanning electron microscopy(SEM)and thermal gravimetric analysis(TGA).The microstructure shows that ZnO microvaristors distribute uniformly in the composite,and the content difference of ZnO microvaristors at the top and bottom part is only 0.4%.The composite shows typical non‐linear conductivity,and the threshold electric field and the non‐linear coefficient decrease with the content of ZnO microvaristors,while the conductivity in the insulating state shows an increasing trend.To verify the field grading effect of the composite with non‐linear conductivity(CNC),a finite element model of a needle‐plate electrode,simulating the condition of a conductive tip in a solid insulated system,is set up.CNC can adaptively grade the electric field,which reduces the surface electric field of the needle tip by 86.6%and the highest electric field in the system by 82.1%.This wet winding method solidifies the industrial application of CNC in high‐voltage power equipment.