Polyoxometalates(POMs),large oxoanions of the group 5 and 6 elements,attract attention due to their use as oxidation-stable catalysts and ligands.Different from the well-known V,Mo,and W POMs,the group V POMs of Ta as...Polyoxometalates(POMs),large oxoanions of the group 5 and 6 elements,attract attention due to their use as oxidation-stable catalysts and ligands.Different from the well-known V,Mo,and W POMs,the group V POMs of Ta assemble and are stable only in highly alkaline solution rather than acidic solution.In this paper,we successfully synthesized and structurally characterized two unprecedented peroxotantalum-containing clusters,KNa_(2)[HSe_(2)(TaO_(2))_(6)(OH)_(4)(H_(2)O)_(2)O_(13)]·15H_(2)O(1)and Cs_(2)K_(1.5)Na_(1.5)[Se_(4)(TaO_(2))_(6)(OH)_(3)O_(18)]·17H_(2)O(2),which comprises a 6-peroxo-6-tantalum core stabilized by two and four selenite centers,respectively.The simple,one-pot synthesis of 1 and 2 involving addition of sodium selenite into the acidified hexatantalate aqueous solution in the presence of hydrogen peroxide could represent a general procedure for incorporating heteroatoms into peroxo-polyoxotantalate species,thus opening new possibilities for this emergent branch of polyoxotantalate chemistry.Moreover,the catalytic properties of these two compounds were investigated using succinic anhydride and phenylamine as the model substrate,and compound 2 presents excellent catalytic activity in the amidation reactions of anhydrides and amines.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 21671056 and 22071045)the Program for Science & Technology Innovation Talents in Universities of Henan Province (Grant No. 19HASTIT044)Excellent Youth Science Fund Project of Henan Province (Grant No. 202300410042)
文摘Polyoxometalates(POMs),large oxoanions of the group 5 and 6 elements,attract attention due to their use as oxidation-stable catalysts and ligands.Different from the well-known V,Mo,and W POMs,the group V POMs of Ta assemble and are stable only in highly alkaline solution rather than acidic solution.In this paper,we successfully synthesized and structurally characterized two unprecedented peroxotantalum-containing clusters,KNa_(2)[HSe_(2)(TaO_(2))_(6)(OH)_(4)(H_(2)O)_(2)O_(13)]·15H_(2)O(1)and Cs_(2)K_(1.5)Na_(1.5)[Se_(4)(TaO_(2))_(6)(OH)_(3)O_(18)]·17H_(2)O(2),which comprises a 6-peroxo-6-tantalum core stabilized by two and four selenite centers,respectively.The simple,one-pot synthesis of 1 and 2 involving addition of sodium selenite into the acidified hexatantalate aqueous solution in the presence of hydrogen peroxide could represent a general procedure for incorporating heteroatoms into peroxo-polyoxotantalate species,thus opening new possibilities for this emergent branch of polyoxotantalate chemistry.Moreover,the catalytic properties of these two compounds were investigated using succinic anhydride and phenylamine as the model substrate,and compound 2 presents excellent catalytic activity in the amidation reactions of anhydrides and amines.
