Based on the technology of gas-injection blast furnace(BF),the characteristics of primary slag formation with H2 addition were researched.The results indicate that,compared with traditional BF,the primary melt is form...Based on the technology of gas-injection blast furnace(BF),the characteristics of primary slag formation with H2 addition were researched.The results indicate that,compared with traditional BF,the primary melt is formed at a lower temperature,which promotes the deformation of the solid burden particles.With the increase in temperature and H2 content,the quantity of formed melt containing FeO decreases sharply,corresponding to the crystallization of solid 2CaO Si02 during reduction.A wider softening range and narrower melting zone could be found in the gas-injection BF with a higher reduction potential.The permeability of burden layer is ameliorated as a result of decreased melt quantity.The influence of H2 on the high-temperature properties of burden is not so conspicuous when the H2 addition is from 10 to 15 vol.%against 5 to 10 vol.%.What is more,the slag shows a better liquidity with the decrease in basicity,owing to the transformation of melt composition from a primary phase field with high melting point to that with low melting point.The process of slag forming in gas-injection BF is characterized by earlier melt formation,less primary slag,higher melting temperature,better permeability and better liquidity,and the phase compositions of primary slag are close to those of final slag.展开更多
BN-MgA1ON composites were prepared by hot-pressing sintering under nitrogen atmosphere with BN-Mg- A1ON composite powders as raw material and Y2 O3 as sintering additive. Based on thermodynamic analysis, the oxi- dati...BN-MgA1ON composites were prepared by hot-pressing sintering under nitrogen atmosphere with BN-Mg- A1ON composite powders as raw material and Y2 O3 as sintering additive. Based on thermodynamic analysis, the oxi- dation resistance of BN-MgAION composites was investigated and the dynamics of oxidation process was also ana- lyzed. The oxidation process and the micro-morphology of the samples before and after oxidation were characterized by X-ray diffraction and scanning electron microscopy. The dynamics of oxidation resistance of the BN-MgA1ON composites was investigated via the analysis of the constant temperature oxidation mass gain curves. The results show that the main components of the material are MgA1ON, Sialon, BN and CaYAI3 07 at 1 650--1750 ＊C, and the content of CaYA1307 decreases as the sintering temperature increases. The BN-MgA1ON composites prepared at 1750 ℃ is uniform and compact with the balanced distributions of A1, Mg, O, and N. The oxidation process of BN- MgA1ON composites in air mainly consists of MgAION, Sialon and BN oxidation. The section after being oxidized at 1000--1300 ℃ involves three layers, namely, the outer layer, the middle layer and the inner layer. The oxidation process follows the parabola model. The apparent activation energy of the oxidation process is 2.13 × 10 5 J/mol and the frequency factor is 4.66 × 10 6.展开更多
基金National Natural Science Foundation of China(U1360205,51674122)Iron and Steel Research Foundation of Hebei(E2016209367).
文摘Based on the technology of gas-injection blast furnace(BF),the characteristics of primary slag formation with H2 addition were researched.The results indicate that,compared with traditional BF,the primary melt is formed at a lower temperature,which promotes the deformation of the solid burden particles.With the increase in temperature and H2 content,the quantity of formed melt containing FeO decreases sharply,corresponding to the crystallization of solid 2CaO Si02 during reduction.A wider softening range and narrower melting zone could be found in the gas-injection BF with a higher reduction potential.The permeability of burden layer is ameliorated as a result of decreased melt quantity.The influence of H2 on the high-temperature properties of burden is not so conspicuous when the H2 addition is from 10 to 15 vol.%against 5 to 10 vol.%.What is more,the slag shows a better liquidity with the decrease in basicity,owing to the transformation of melt composition from a primary phase field with high melting point to that with low melting point.The process of slag forming in gas-injection BF is characterized by earlier melt formation,less primary slag,higher melting temperature,better permeability and better liquidity,and the phase compositions of primary slag are close to those of final slag.
基金Item Sponsored by National Natural Science Foundation of China(50904022)Education Department of Hebei Province Outstanding Youth Fund Project of China(Y2011116)
文摘BN-MgA1ON composites were prepared by hot-pressing sintering under nitrogen atmosphere with BN-Mg- A1ON composite powders as raw material and Y2 O3 as sintering additive. Based on thermodynamic analysis, the oxi- dation resistance of BN-MgAION composites was investigated and the dynamics of oxidation process was also ana- lyzed. The oxidation process and the micro-morphology of the samples before and after oxidation were characterized by X-ray diffraction and scanning electron microscopy. The dynamics of oxidation resistance of the BN-MgA1ON composites was investigated via the analysis of the constant temperature oxidation mass gain curves. The results show that the main components of the material are MgA1ON, Sialon, BN and CaYAI3 07 at 1 650--1750 ＊C, and the content of CaYA1307 decreases as the sintering temperature increases. The BN-MgA1ON composites prepared at 1750 ℃ is uniform and compact with the balanced distributions of A1, Mg, O, and N. The oxidation process of BN- MgA1ON composites in air mainly consists of MgAION, Sialon and BN oxidation. The section after being oxidized at 1000--1300 ℃ involves three layers, namely, the outer layer, the middle layer and the inner layer. The oxidation process follows the parabola model. The apparent activation energy of the oxidation process is 2.13 × 10 5 J/mol and the frequency factor is 4.66 × 10 6.
