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Comparison of Four Deoxygenation Techniques for Cyclodextrin Induced Room Temperature Phosphorescence
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作者 Hai Rong ZHANG yan sheng wei +1 位作者 wei Jun JIN Chang Song LIU(Department of Chemistry, Shanxi University, Taiyuan 030006) 《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第4期339-342,共4页
The traditional deoxygenation techniques for cyclodextrin induced room temperature phosphorescence (CD-RTP) include N-2(g)purging([1]) and Na2SO3 chemical deoxygenation. In this paper, with 1-bromocyclohexane (1-BrCH)... The traditional deoxygenation techniques for cyclodextrin induced room temperature phosphorescence (CD-RTP) include N-2(g)purging([1]) and Na2SO3 chemical deoxygenation. In this paper, with 1-bromocyclohexane (1-BrCH) as an external heavy atom perturber, 7,8-benzoquinoline (7,8-BQ) was used as a model compound, hydrogen and carbon dioxide are used for deoxygenation in CD-RTP and compared with two traditional deoxygenation techniques. The results show that the new deoxygenation techniques have obvious advantages such as simpler facilities, faster speed of deoxygenation and wider acidity range etc. 展开更多
关键词 FOUR Comparison of Four Deoxygenation Techniques for Cyclodextrin Induced Room Temperature Phosphorescence RTP
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