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铟在氯化物熔盐中的氧化还原行为
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作者 徐亮 熊延杭 +5 位作者 孟金伟 王家保 华中胜 田勇攀 尤静林 赵卓 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第5期1496-1505,共10页
采用循环伏安、计时电位等电化学分析测试手段对450℃下LiCl-KCl共融盐中In(Ⅲ)在惰性钼电极上的电化学行为进行系统研究。结果表明:In(Ⅲ)在熔盐中的还原是一个两步过程,电极反应In(Ⅲ)/In(Ⅰ)和In(Ⅰ)/In分别发生在-0.4V和-0.8V (vs A... 采用循环伏安、计时电位等电化学分析测试手段对450℃下LiCl-KCl共融盐中In(Ⅲ)在惰性钼电极上的电化学行为进行系统研究。结果表明:In(Ⅲ)在熔盐中的还原是一个两步过程,电极反应In(Ⅲ)/In(Ⅰ)和In(Ⅰ)/In分别发生在-0.4V和-0.8V (vs Ag/AgCl)。结合还原过程电子转移数的理论计算以及恒电位沉积产物的表征进一步证明In(Ⅲ)在熔盐中的两步还原机制。此外,根据循环伏安和计时电位测试结果计算铟离子在450℃下LiCl-KCl共融盐中的扩散系数。采用两种方法得到的数据吻合良好,结果为DIn(Ⅲ)=1.8×10^(-5)cm^(2)/s和DIn(I)=1.4×10^(-4)cm^(2)/s。 展开更多
关键词 铟离子 氧化还原行为 LiCl−KCl共融盐 废弃液晶显示屏 资源回收
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Recovery of platinum from spent automotive catalyst based on hydrometallurgy
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作者 Tao Ge Jin-Dong He +5 位作者 Liang Xu yan-hang xiong Ling Wang Xiao-Wei Zhou Yong-Pan Tian Zhuo Zhao 《Rare Metals》 SCIE EI CAS CSCD 2023年第4期1118-1137,共20页
Platinum(Pt)is a critical raw material for automotive catalytic converters due to its high-temperature stability,corrosion resistance and catalytic activity,whereas its limited primary resources and uneven distributio... Platinum(Pt)is a critical raw material for automotive catalytic converters due to its high-temperature stability,corrosion resistance and catalytic activity,whereas its limited primary resources and uneven distribution make it hard to meet the growing demand of platinum.Spent automotive catalyst(SAC)is currently the most important secondary resource of platinum,of which the platinum content is much higher than that of the primary platinum resources.The recovery process of platinum from spent automobile catalyst mainly consists of pretreatment followed by enrichment and refining,involving pyro-and hydrometallurgical techniques,among which enrichment and refining processes are extremely important for platinum recovery from spent automobile catalyst.This paper provides an overview of the technologies for platinum recovery from spent automotive catalyst.The emphasis is placed on the processes of enrichment and refining based on hydrometallurgical techniques.Future directions of research and development of platinum recovery from spent automobile catalyst are also proposed. 展开更多
关键词 Platinum(Pt) Platinum group metals Spent automotive catalyst(SAC) HYDROMETALLURGY Solvent extraction Separation and purification
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