Polymer light-emitting devices using poly(ethylene oxide) as an electron injecting layer

The performance of polymer light emitting devices(PLEDs)based on polyvinyl carbazole(PVK)is improved by introducing a nanoscale interfacial thin layer,made of poly(ethylene oxide)(PEO),between the calcium cathode and the PVK emissive layer.It is believed that the PEO layer plays a key role in enhancing the device performance.In comparison to the device with Ca/Al as the cathode,the performance of the PLED with PEO/Ca/Al cathode,including the driving voltage,luminance efficiency is significantly improved.These improvements are attributed to the introduction of a thin layer of PEO that can lower the interfacial barrier and facilitate electron injection.

Ultra-small amorphous MoS2 decorated reduced graphene oxide for supercapacitor application

Amorphous materials have recently gained much attention as electrode materials in supercapacitor application due to the presence of larger amount active sites which can efficiently increase the storage capacity of the materials.Nano engineering is an elegant approach to fully utilize the advantages of the amorphous structure.Moreover,large surface area and high conductivity of reduced graphene oxide(RGO)can efficiently increase the storage capacity of the system.Exploiting this idea,in the present work,we have successfully synthesized amorphous MoS2 of two different sizes on reduced graphene oxide and thoroughly investigated the supercapacitor behavior of the system.The specific capacitance of the composite structures has been found to be largely increased with decreasing size of the amorphous nano particle.The specific capacitance of amorphous MoS2-RGO composite containing nearly 50 nm of MoS2 found to be 270 F/g whereas when the particle size is reduced to 5–7 nm,value of specific capacitance increases to 460 F/g.The large increase in specific capacitance with the tuning of the size of amorphous nano particle has been explained by the presence of a large number of active sulfur edges of ultra-small MoS2 nano structure along with the better charge transport which can effectively increase the storage capacity of the overall system.The retention in the capacitance of the material has been found to be 90%after 5000 cycles.