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钴改性Fe3O4-MnO2催化转化生物质合成气制备液体燃料(英文) 被引量:2
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作者 王捷 向颖 +5 位作者 丁毅远 徐艳飞 孔祥辉 马光远 Chanatip Samart 定明月 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2019年第6期721-726,I0003,I0016-I0024,共16页
本文制备了用于费托合成反应的钴改性Fe3O4-MnO2双功能催化剂,并探究了钴负载量对Fe-Co协同效应的影响以及Fe1CoxMn1催化剂的费托合成反应性能.实验发现,在Fe3O4-Mn催化剂中加入Co可促进铁氧化物的还原、增加反应过程中铁位点的活性.此... 本文制备了用于费托合成反应的钴改性Fe3O4-MnO2双功能催化剂,并探究了钴负载量对Fe-Co协同效应的影响以及Fe1CoxMn1催化剂的费托合成反应性能.实验发现,在Fe3O4-Mn催化剂中加入Co可促进铁氧化物的还原、增加反应过程中铁位点的活性.此外,Co的加入可增强Fe-Co金属间的电子转移,加强两者的协同作用,提高催化性能.Co负载较高的Fe1CoxMn1催化剂可进一步促进加氢反应能力,使产品分布向短链烃方向转移.在280℃、2.0 MPa和3000 h-1的最佳工况条件下,Fe1Co1Mn1催化剂的液体燃料收率最高. 展开更多
关键词 费托合成 Fe3O4-Mn 钴负载 协同效应
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Strata-pressure behavior of double-unit mining method combining fully-mechanized and mechanized coal face
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作者 Fu-Jun ZHAO yan-fei xu Guo-Ju WANG 《Journal of Coal Science & Engineering(China)》 2013年第4期454-461,共8页
关键词 采煤工作面 工作面开采 地层压力 全机械化 行为 应力集中系数 单位 复杂地质条件
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Effect of stabilizing treatment on microstructure and stress rupture properties of phosphorus microalloyed Inconel 706 alloy
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作者 Sha Zhang Yu-chao Wu +6 位作者 Yu Lil Zhong-pei Dail Dan Jia yan-fei xu Guang-sheng Zeng Zhi-ming Guo Jian Liul 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2023年第8期1613-1621,共9页
The microstructure and stress rupture properties of Inconel 706 alloy microalloyed with phosphorus are examined under stabilizing and unstabilizing heat treatment conditions.It was found that applying the stabilizing ... The microstructure and stress rupture properties of Inconel 706 alloy microalloyed with phosphorus are examined under stabilizing and unstabilizing heat treatment conditions.It was found that applying the stabilizing treatment resulted in a 98% increment in the stress rupture life and a 215% increment in the elongation tested at 650℃/690 MPa for the alloy compared to that under the unstabilizing heat treatment condition.The stabilizing treatment led to the precipitation of rod-shaped and needle-shaped n phases at the grain boundaries.Morphologies of γ'-γ" co-precipitates in the grain interior were noncompact form and compact form for the alloy under unstabilizing and stabilizing heat treatment conditions,respectively.Based on the microstructure characterizations,the improvement of stress rupture properties by the stabilizing treatment was attributed to the precipitation of n phases at the grain boundaries,which can hinder cracks initiation and propagation and relieve the stress concentration. 展开更多
关键词 SUPERALLOY STABILIZATION ηphase γ'-γ"co-precipitate Stress rupture property
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