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铜包铝复合材料界面金属间化合物及形成机理(英文) 被引量:4
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作者 初娣 张建宇 +2 位作者 姚金金 韩艳秋 吴春京 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第11期2521-2528,共8页
采用垂直充芯连铸工艺制备了直径为12 mm、铜层厚度为2 mm的铜包铝复合材料。通过SEM、XRD和TEM对界面金属间化合物的种类和形态进行了研究。研究结果表明,Cu_/Al界面主要由层状γ_1(Cu_9Al_4)相、胞状θ(Cu_Al_2)相和α(Al)+θ(Cu_Al_2... 采用垂直充芯连铸工艺制备了直径为12 mm、铜层厚度为2 mm的铜包铝复合材料。通过SEM、XRD和TEM对界面金属间化合物的种类和形态进行了研究。研究结果表明,Cu_/Al界面主要由层状γ_1(Cu_9Al_4)相、胞状θ(Cu_Al_2)相和α(Al)+θ(Cu_Al_2)共晶组成,特别是在界面组织中观察到残留的针状Cu_3Al_(2+x)相。通过比较γ_1(Cu_9Al_4)和ε_2(Cu_3Al_(2+x))的形核驱动力,证明了ε_2(Cu_3Al_(2+x))相优先在界面处形成。此外,完整揭示了铜包铝复合材料界面形成机理。 展开更多
关键词 铜包铝复合材料 垂直充芯连铸 界面形成机理
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Investigation on the interface of Cu/Al couples during isothermal heating 被引量:3
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作者 yan-qiu han Li-hua Ben +2 位作者 Jin-jin Yao Shu-wei Feng Chun-jing Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第3期309-318,共10页
The evolutionary process and intermetallic compounds of Cu/A1 couples during isothermal heating at a constant bonding tem- perature of 550℃ were investigated in this paper. The interracial morphologies and microstruc... The evolutionary process and intermetallic compounds of Cu/A1 couples during isothermal heating at a constant bonding tem- perature of 550℃ were investigated in this paper. The interracial morphologies and microstructures were examined by optical microscopy, scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, and X-ray diffraction. The results suggest that bonding is not achieved between Cu and A1 at 550℃ in 10 min due to undamaged oxide films. Upon increasing the bonding time from 15 to 25 min, however, metallurgical bonding is obtained in these samples, and the thickness of the reactive zone varies with holding time. In the interfacial region, the final microstructure consists of Cu9A14, CuAl, CuA12, and ct-A1 + CuAl2. Furthermore, these results provide new insights into the mechanism of the imerfacial reaction between Cu and A1. Microhardness measurements show that the chemical composition exerts a signifi- cant influence on the mechanical properties of Cu/A1 couples. 展开更多
关键词 COPPER ALUMINUM intermetallic compounds oxide films isothermal heating
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Microstructural characterization of Cu/Al composites and effect of cooling rate at the Cu/Al interfacial region 被引量:2
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作者 yan-qiu han Li-hua Ben +1 位作者 Jin-jin Yao Chun-jing Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第1期94-101,共8页
Cu/Al composites are of vital importance in industrial applications because of their numerous advantages. The influence of bond-ing temperature and cooling rate on the microstructure and morphology of Cu/Al composites... Cu/Al composites are of vital importance in industrial applications because of their numerous advantages. The influence of bond-ing temperature and cooling rate on the microstructure and morphology of Cu/Al composites was investigated in this paper. The interfacial morphology and constituent phases at the Cu/Al interface were analyzed by optical microscopy and field-emission scanning electron mi-croscopy equipped with energy-dispersive X-ray spectroscopy. The results indicate that effective Cu-Al bonding requires a higher bonding temperature to facilitate interdiffusion between the two metals. The microstructural characteristics are associated with various bonding tem-peratures, which impact the driving force of interdiffusion. It is observed that cooling rate exerts a significant influence on the morphology and amount of the intermetallic compounds at the interfacial region. Meanwhile, microhardness measurements show that hardness varies with the bonding temperature and rate of cooling. 展开更多
关键词 composite materials copper aluminum temperature cooling rate INTERFACES diffusion bonding
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