Comprehensive Summary Endohedral metallofullerenes(EMFs)are a family of molecules with metal clusters or ions encapsulated inside a fullerene cage.Their unique structures provide a powerful interface for organic chemi...Comprehensive Summary Endohedral metallofullerenes(EMFs)are a family of molecules with metal clusters or ions encapsulated inside a fullerene cage.Their unique structures provide a powerful interface for organic chemists to manipulate metal elements.Over a decade ago,many reactions on empty fullerenes were adopted for EMFs,resulting in a series of reactions that are well-established and reviewed in the literature.In recent years,new topics have emerged in EMF chemistry.First,new addition reactions were developed,notably some that are not based on known empty-fullerene reactions.Second,considerable progress has been made on regioselective multi-additions on EMFs.展开更多
基金the support of the US Department of Energy(Grant No.DE-SC0020260).
文摘Comprehensive Summary Endohedral metallofullerenes(EMFs)are a family of molecules with metal clusters or ions encapsulated inside a fullerene cage.Their unique structures provide a powerful interface for organic chemists to manipulate metal elements.Over a decade ago,many reactions on empty fullerenes were adopted for EMFs,resulting in a series of reactions that are well-established and reviewed in the literature.In recent years,new topics have emerged in EMF chemistry.First,new addition reactions were developed,notably some that are not based on known empty-fullerene reactions.Second,considerable progress has been made on regioselective multi-additions on EMFs.
