Hollow B–SiO2@TiO2 composites were prepared by the wet chemical deposition method starting from TiCl4 and hollow B–SiO2 microspheres.TiO2 layers composed of anatase TiO2 nanoparticles were coated on the surfaces of ...Hollow B–SiO2@TiO2 composites were prepared by the wet chemical deposition method starting from TiCl4 and hollow B–SiO2 microspheres.TiO2 layers composed of anatase TiO2 nanoparticles were coated on the surfaces of the hollow B–SiO2 microspheres probably through the formation of Ti—O—Si and Ti—O—B bonds.A great number of—OH groups were also present at the TiO2 coating layers.The presence of Ti—O—Si bonds and Ti—O—B bonds resulted in the formation of defects in the TiO2 coating layers,which decreased the band gap of the TiO2 coating layers to ca.3.0 eV and endowed the TiO2 coating layers with visible light absorption performance.The buoyancy hollow B–SiO2@TiO2 composites exhibited high photocatalytic activities for the degradation of ammonia-nitrogen and green algae.The conversion of ammonia-nitrogen reached 65%when the degradation of ammonia-nitrogen(43 mg·L-1 at pH value of 8)was catalyzed by the B–SiO2@TiO2(100:10)composite under the simulated solar light irradiation at 35°C for 660 min.The green algae(5 mg·L-1)were almost completely degraded over the B–SiO@TiO2(100:20)photocatalyst under the visible light irradiation at 35°C for 510 min.展开更多
厌氧共消化是市政有机固废减量化资源化的主流工艺之一,然而湖北省武汉市仍缺乏具有本地代表性的厨余垃圾与剩余污泥厌氧共消化效能及潜在影响的相关研究。通过生化产甲烷潜力批式实验、动力学分析和共消化性能评估考察了武汉本地典型...厌氧共消化是市政有机固废减量化资源化的主流工艺之一,然而湖北省武汉市仍缺乏具有本地代表性的厨余垃圾与剩余污泥厌氧共消化效能及潜在影响的相关研究。通过生化产甲烷潜力批式实验、动力学分析和共消化性能评估考察了武汉本地典型厨余垃圾和剩余污泥的比例对厌氧共消化效能和潜在应用的影响。研究结果表明:厨余垃圾与剩余污泥共消化的产甲烷速率比厨余垃圾单独消化提高了40%~96%;厨余垃圾与剩余污泥的最佳比例为2∶1(基于VS),此时实际产甲烷潜力为408 mLCH_(4)·g^(-1) VS added,比理论叠加值提高了11.2%;厌氧消化的渗透率达到60%时,武汉本地的厨余垃圾和剩余污泥通过厌氧消化回收的能量高达6100万m^(3)CH_(4)·a^(-1)或2亿kWh·a^(-1),可以供应约7.6%的居民生活天然气需求量或1.7%的电力需求量,可为武汉本地乃至全国的厨余垃圾和剩余污泥共消化提供参考和指导意义。展开更多
People could potentially mitigate heat discomfort when outdoors by combining passive radiative cooling(PRC)strategies with personal thermal management techniques.However,most current PRC materials lack wearing comfort...People could potentially mitigate heat discomfort when outdoors by combining passive radiative cooling(PRC)strategies with personal thermal management techniques.However,most current PRC materials lack wearing comfort and durability.In this study,a microarray technique is applied to fabricate the tailoring photonic-engineered textiles with intriguing PRC capability and appealing wearability.The developed radiative cooling textiles(RCTs)demonstrate appropriate air-moisture permeability,structural stability,and extended spectroscopic response with high sunlight reflectivity(91.7%)and robust heat emissivity(95.8%)through the atmospheric transparent spectral window(ATSW).In a hot outdoor cooling test,a skin simulator covered by the RCTs displays a temperature drop of approximately 4.4℃at noon compared with cotton textiles.The evolution of our mimetic structures may provide new insights into the generation of wearable,thermal-wet comfortable,and robust textiles for exploring PRC techniques in personal thermal management applications.展开更多
Bimetallic compounds such as hydrotalcite-type layered double hydroxides(LDHs)are promising electrocatalysts owing to their unique electronic structures.However,their abilities toward nitrogen adsorption and reduction...Bimetallic compounds such as hydrotalcite-type layered double hydroxides(LDHs)are promising electrocatalysts owing to their unique electronic structures.However,their abilities toward nitrogen adsorption and reduction are undermined since the surface-mantled,electronegative-OH groups hinder the charge transfer between transition metal atoms and nitrogen molecules.Herein,a smart interfacing strategy is proposed to construct a coupled heterointerface between LDH and 2D g-C_(3)N_(4),which is proven by density functional theory(DFT)investigations to be favorable for nitrogen adsorption and ammonia desorption compared with neat LDH surface.The interfaced LDH and g-C_(3)N_(4) is further hybridized with a self-standing TiO_(2) nanofibrous membrane(NM)to maximize the interfacial effect owing to its high porosity and large surface area.Profited from the synergistic superiorities of the three components,the LDH@C_(3)N_(4)@TiO_(2) NM delivers superior ammonia yield(2.07×10^(−9) mol s^(−1) cm^(−2))and Faradaic efficiency(25.3%),making it a high-efficiency,noble-metal-free catalyst system toward electrocatalytic nitrogen reduction.展开更多
基金Supported by the National Natural Science Foundation of China(21506078).
文摘Hollow B–SiO2@TiO2 composites were prepared by the wet chemical deposition method starting from TiCl4 and hollow B–SiO2 microspheres.TiO2 layers composed of anatase TiO2 nanoparticles were coated on the surfaces of the hollow B–SiO2 microspheres probably through the formation of Ti—O—Si and Ti—O—B bonds.A great number of—OH groups were also present at the TiO2 coating layers.The presence of Ti—O—Si bonds and Ti—O—B bonds resulted in the formation of defects in the TiO2 coating layers,which decreased the band gap of the TiO2 coating layers to ca.3.0 eV and endowed the TiO2 coating layers with visible light absorption performance.The buoyancy hollow B–SiO2@TiO2 composites exhibited high photocatalytic activities for the degradation of ammonia-nitrogen and green algae.The conversion of ammonia-nitrogen reached 65%when the degradation of ammonia-nitrogen(43 mg·L-1 at pH value of 8)was catalyzed by the B–SiO2@TiO2(100:10)composite under the simulated solar light irradiation at 35°C for 660 min.The green algae(5 mg·L-1)were almost completely degraded over the B–SiO@TiO2(100:20)photocatalyst under the visible light irradiation at 35°C for 510 min.
文摘厌氧共消化是市政有机固废减量化资源化的主流工艺之一,然而湖北省武汉市仍缺乏具有本地代表性的厨余垃圾与剩余污泥厌氧共消化效能及潜在影响的相关研究。通过生化产甲烷潜力批式实验、动力学分析和共消化性能评估考察了武汉本地典型厨余垃圾和剩余污泥的比例对厌氧共消化效能和潜在应用的影响。研究结果表明:厨余垃圾与剩余污泥共消化的产甲烷速率比厨余垃圾单独消化提高了40%~96%;厨余垃圾与剩余污泥的最佳比例为2∶1(基于VS),此时实际产甲烷潜力为408 mLCH_(4)·g^(-1) VS added,比理论叠加值提高了11.2%;厌氧消化的渗透率达到60%时,武汉本地的厨余垃圾和剩余污泥通过厌氧消化回收的能量高达6100万m^(3)CH_(4)·a^(-1)或2亿kWh·a^(-1),可以供应约7.6%的居民生活天然气需求量或1.7%的电力需求量,可为武汉本地乃至全国的厨余垃圾和剩余污泥共消化提供参考和指导意义。
基金supported by the Ministry of Industry and Information Technologythe National Development and Reform Commission of the People’s Republic of China+2 种基金the Fundamental Research Funds for the Central Universities(2232020A-06)the Science and Technology Commission of Shanghai Municipality(20QA1400500,21130750100,and 22dz1200102)Huo Yingdong Education Foundation(171065)。
文摘People could potentially mitigate heat discomfort when outdoors by combining passive radiative cooling(PRC)strategies with personal thermal management techniques.However,most current PRC materials lack wearing comfort and durability.In this study,a microarray technique is applied to fabricate the tailoring photonic-engineered textiles with intriguing PRC capability and appealing wearability.The developed radiative cooling textiles(RCTs)demonstrate appropriate air-moisture permeability,structural stability,and extended spectroscopic response with high sunlight reflectivity(91.7%)and robust heat emissivity(95.8%)through the atmospheric transparent spectral window(ATSW).In a hot outdoor cooling test,a skin simulator covered by the RCTs displays a temperature drop of approximately 4.4℃at noon compared with cotton textiles.The evolution of our mimetic structures may provide new insights into the generation of wearable,thermal-wet comfortable,and robust textiles for exploring PRC techniques in personal thermal management applications.
基金financially supported by the National Natural Science Foundation of China(No.52173055 and 21961132024)the Natural Science Foundation of Shanghai(No.19ZR1401100)+3 种基金the International Cooperation Fund of Science and Technology Commission of Shanghai Municipality(No.21130750100)the Innovation Program of Shanghai Municipal Education Commission(No.2017-01-07-00-03-E00024)the Fundamental Research Funds for the Central Universities(No.18D310109)the DHU Distinguished Young Professor Program(No.LZA2020001).
文摘Bimetallic compounds such as hydrotalcite-type layered double hydroxides(LDHs)are promising electrocatalysts owing to their unique electronic structures.However,their abilities toward nitrogen adsorption and reduction are undermined since the surface-mantled,electronegative-OH groups hinder the charge transfer between transition metal atoms and nitrogen molecules.Herein,a smart interfacing strategy is proposed to construct a coupled heterointerface between LDH and 2D g-C_(3)N_(4),which is proven by density functional theory(DFT)investigations to be favorable for nitrogen adsorption and ammonia desorption compared with neat LDH surface.The interfaced LDH and g-C_(3)N_(4) is further hybridized with a self-standing TiO_(2) nanofibrous membrane(NM)to maximize the interfacial effect owing to its high porosity and large surface area.Profited from the synergistic superiorities of the three components,the LDH@C_(3)N_(4)@TiO_(2) NM delivers superior ammonia yield(2.07×10^(−9) mol s^(−1) cm^(−2))and Faradaic efficiency(25.3%),making it a high-efficiency,noble-metal-free catalyst system toward electrocatalytic nitrogen reduction.
