A novel squaraine dye（SQ） modified by ferrocene has been synthesized through（E）-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid.The molecular structure of SQ was characterized by ~1H NMR,^（13）C NMR,MS and...A novel squaraine dye（SQ） modified by ferrocene has been synthesized through（E）-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid.The molecular structure of SQ was characterized by ~1H NMR,^（13）C NMR,MS and elemental analysis.SQ is high soluble in common solvents.The maximum absorptions of SQ in different solvents are in the range of 708-734 nm,exhibiting positive solvatochromism with increasing solvent polarity.The optical and electrical properties of SQ indicate that it is a promising electron donor material for bulk-heterojunction organic solar cell.展开更多
基金the National Natural Science Foundation of China(No20702005)the Fujian Provincial Natural Science Foundation of China(No2008J0148)
文摘A novel squaraine dye（SQ） modified by ferrocene has been synthesized through（E）-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid.The molecular structure of SQ was characterized by ~1H NMR,^（13）C NMR,MS and elemental analysis.SQ is high soluble in common solvents.The maximum absorptions of SQ in different solvents are in the range of 708-734 nm,exhibiting positive solvatochromism with increasing solvent polarity.The optical and electrical properties of SQ indicate that it is a promising electron donor material for bulk-heterojunction organic solar cell.
