The synthesis and properties of a class of soluble fluorine-containing aromatic polyimides are described. The polyimides show desirable features of materials for microelectronics applications.
Under microwave irradiation, boron trifluoride has been found to mediate a novel condensation reaction of alkyl aryl ketone with ethyl ortho-formate to give a series of new condensation products (5,6,7,8). Their struc...Under microwave irradiation, boron trifluoride has been found to mediate a novel condensation reaction of alkyl aryl ketone with ethyl ortho-formate to give a series of new condensation products (5,6,7,8). Their structures were determined by IR, H-1/C-13-NMR, MS spectra, and the crystal structure of 8 was further defined by X-ray diffraction.展开更多
Poly[ethyl trifluorobuty-2-noate] (PETFB) was prepared from ethyltrifluorobuty-2-noate by anionic polymerization. The polymer was examined by UV-Vis, IR and NMR spectrometries. It possessed pi-conjugated backbone in t...Poly[ethyl trifluorobuty-2-noate] (PETFB) was prepared from ethyltrifluorobuty-2-noate by anionic polymerization. The polymer was examined by UV-Vis, IR and NMR spectrometries. It possessed pi-conjugated backbone in the main chain. No significant variation in the electrical conductivity of BF3-doped PETFB was observed after more than three months' storage, indicating improved conductive stability in air as compared with polyacetylene.展开更多
基金the National Natural Science Foundation of China (NSAC) for Distinguished Young Scholars !(Project No. 59925310 )
文摘The synthesis and properties of a class of soluble fluorine-containing aromatic polyimides are described. The polyimides show desirable features of materials for microelectronics applications.
文摘Under microwave irradiation, boron trifluoride has been found to mediate a novel condensation reaction of alkyl aryl ketone with ethyl ortho-formate to give a series of new condensation products (5,6,7,8). Their structures were determined by IR, H-1/C-13-NMR, MS spectra, and the crystal structure of 8 was further defined by X-ray diffraction.
基金Project supported by the National Natural Science Foundation of China.
文摘Poly[ethyl trifluorobuty-2-noate] (PETFB) was prepared from ethyltrifluorobuty-2-noate by anionic polymerization. The polymer was examined by UV-Vis, IR and NMR spectrometries. It possessed pi-conjugated backbone in the main chain. No significant variation in the electrical conductivity of BF3-doped PETFB was observed after more than three months' storage, indicating improved conductive stability in air as compared with polyacetylene.
