A novel micro-rolling&incremental sheet forming hybrid process:Deformation behavior and microstructure evolution

Thin-walled metal parts with functional micro-featured surface have broad application prospects in the fields of resistance reduction,noise reduction,etc.In this study,a novel micro-rolling&incremental sheet forming hybrid process(μR-ISF)is proposed to fabricate thin-walled metal parts with microgroove arrays.An analytical model which relates the rolling force and microgroove depth in the micro-rolling stage was first established.Then,the formation mechanism of microgroove morphology during both micro-rolling stage and macro-shape forming stage are investigated.After the micro-grooved sheet being incrementally formed,a significant reduction(between 21%to nearly 60%)is occurred in the depth of both transverse and longitudinal grooves compared to the flat sheet.Meanwhile,the width of transverse grooves decreases slightly by about 10%on average,while the width of longitudinal microgrooves increases significantly by more than 30%on average.After micro-rolling,85°{102}tensile twins appear on the micro-grooved sheet and the percentage of 65°{112}compressive twins increases.After incremental forming,the percentage of low-angle grain boundaries and the density of geometrically necessary dislocations in the formed part increase significantly,and the grain size distribution becomes more uniform.The present work provides a new strategy for the fabrication of 3D metal thin-walled components with surface micro-features.

原发性胆汁性胆管炎患者发生肝癌的危险因素研究

目的:探讨原发性胆汁性胆管炎(primary biliary cholangitis,PBC)患者发生肝癌的危险因素。方法:回顾性分析2011年1月至2016年12月郑州大学第一附属医院670例PBC患者的病例资料,随访确定发生肝癌的患者,应用病例对照研究的方法探索PBC患者发生肝癌的潜在危险因素,使用Logistic回归模型进行单因素和多因素分析,计算相关因素的危险比及95%置信区间(confidence interval,CI)。结果:通过随访,确定发生肝癌的PBC患者35例(5.2%),其中4例(女性4例)因相关影响因素不全不可纳入病例对照研究,另有6例(男性2例,女性4例)因与PBC同时或先于诊断而不能纳入研究,因此本研究纳入病例对照研究的患者共25例。男性PBC相关性肝癌患者较女性易伴有饮酒史、吸烟史、输血史和家族性恶性肿瘤史(P<0.05),且肝功能损害更为严重,表现为ALT、AST和GGT的水平均高于女性患者(P<0.05)。Logistic回归模型分析显示体质量指数(body mass index,BMI)≥25和饮酒史与PBC患者发生肝癌风险增加呈独立相关(均P<0.05)。结论:研究显示BMI≥25和饮酒史为PBC相关性肝癌发生的独立危险因素。因此,PBC患者除常规筛查外,可从戒酒和控制体质量中受益。

Confinement of sulfur-doped NiO nanoparticles into N-doped carbon nanotube/nanofiber-coupled hierarchical branched superstructures:Electronic modulation by anion doping boosts oxygen evolution electrocatalysis

The search for non-precious and efficient electrocatalysts towards the oxygen evolution reaction(OER)is of vital importance for the future advancement of multifarious renewable energy conversion/storage technologies.Electronic modulation via heteroatom doping is recognized as one of the most forceful leverages to enhance the electrocatalytic activity.Herein,we demonstrate a delicate strategy for the in-situ confinement of S-doped Ni O nanoparticles into N-doped carbon nanotube/nanofiber-coupled hierarchical branched superstructures(labeled as S-Ni O@N-C NT/NFs).The developed strategy simultaneously combines enhanced thermodynamics via electronic regulation with accelerated kinetics via nanoarchitectonics.The S-doping into Ni O lattice and the 1 D/1 D-integrated hierarchical branched carbon substrate confer the resultant S-Ni O@N-C NT/NFs with regulated electronic configuration,enriched oxygen vacancies,convenient mass diffusion pathways and superior architectural robustness.Thereby,the SNi O@N-C NT/NFs display outstanding OER properties with an overpotential of 277 m V at 10 m A cm^(-2)and impressive long-term durability in KOH medium.Density functional theory(DFT)calculations further corroborate that introducing S-dopant significantly enhances the interaction with key oxygenate intermediates and narrow the band gap.More encouragingly,a rechargeable Zn-air battery using an air-cathode of Pt/C+S-Ni O@N-C NT/NFs exhibits a lower charge voltage and preferable cycling stability in comparison with the commercial Pt/C+Ru O_(2)counterpart.This study highlighting the concurrent consideration of electronic regulation,architectural design and nanocarbon hybridization may shed light on the future exploration of economical and efficient electrocatalysts.

Porous rod-like Ni_(2)P/Ni assemblies for enhanced urea electrooxidation

The urea oxidation reaction has attracted increasing attention.Here,porous rod-like Ni2P/Ni assemblies,which consist of numerous nanoparticle subunits with matching interfaces at the nanoscale have been synthesized via a simple phosphating approach.Density functional theory calculations and density of states indicate that porous rod-like Ni2P/Ni assemblies can significantly enhance the activity of chemical bonds and the conductivity compared with NiO/Ni toward the urea oxidation reaction.The optimal catalyst of Ni2P/Ni can deliver a low overpotential of 50 mV at 10 mA·cm−2 and Tafel slope of 87.6 mV·dec−1 in urea oxidation reaction.Moreover,the constructed electrolytic cell exhibits a current density of 10 mA·cm−2 at a cell voltage of 1.47 V and an outstanding durability in the two-electrode system.This work has provided a new possibility to fabricate metal phosphides-metal assemblies with advanced performance.

Experimental and numerical investigation on surface quality for two-point incremental sheet forming with interpolator

The unsatisfied surface quality seriously impedes the wide application of incremental sheet forming(ISF)in industrial field.As a novel approach,the interpolator method is a promising strategy to enhance the surface quality in ISF.However,the mechanism for the improvement of surface quality and the influence of interpolator properties on surface roughness are not well understood.In this paper,the influences of process variables(i.e.tool diameter,step size and thickness of interpolators)on the forming process(e.g.surface roughness,forming force and geometric error)are investigated through a systematic experimental approach of central composite design(CCD)in two-point incremental sheet forming(TPIF).It is obtained that the increase in thickness of interpolators decreases the surface roughness in direction vertical to the tool path while increases the surface roughness in direction horizontal to the tool path.Nevertheless,the combined influence between thickness of interpolators and process parameters(tool diameter and step size)is limited.Meanwhile,the placement of interpolator has little influence on the effective forming force of blank.In addition,the geometric error enlarges with the increase of step size and thickness of interpolator while decreases firstly and then increase with an increase in tool diameter.Finally,the influencing mechanism of the interpolator method on surface quality can be attributed to the decrease of thecontact pressure due to the increase of contact area with the unchanged contact force.Meanwhile,the interpolator method eliminates the sliding friction on the surface of blank due to the stable relative position between the blank and the interpolator.

Formation mechanism and modeling of surface waviness in incremental sheet forming

mproving and controlling surface quality has always been a challenge for incremental sheet forming (ISF), whereas the generation mechanism of waviness surface is still unknown, which impedes the widely application of ISF in the industrial field. In this paper, the formation mechanism and the prediction of waviness are both investigated through experiments, numerical simulation, and theoretical analysis. Based on a verified finite element model, the waviness topography is predicted numerically for the first time, and its generation is attributed to the residual bending deformation through deformation history analysis. For more efficient engineering application, a theoretical model for waviness height is proposed based on the generation mechanism, using a modified strain function considering deformation modes. This work is favorable for the perfection of formation mechanism and control of surface quality in ISF.

Enhanced ORR performance of Pt catalysts in acidic media by coupling with topological C defects

Defect engineering is a promising strategy for supported catalysts to improve the catalytic activity and durability.Here,we selected the Cmatrix enriched with topological defects to serve as the substrate material,in which the topological defects can act as anchoring centers to trapPt nanoparticles for driving the O_(2) reduction reactions(ORRs).Both experimental characterizations and theoretical simulations revealed the strong Ptdefect interaction with enhanced charge transfer on the interface.Despite a low Pt loading,the supported catalyst can still achieve a remarkable 55 mV positive shift of half-wave potential toward ORR in O_(2)-saturated 0.1 M HClO_(4) electrolyte compared with the commercial Pt catalyst on graphitized C.Moreover,the degeneration after 5,000 voltage cycles was negligible.This finding indicates that the presence of strong interaction between Pt and topological C defects can not only stabilize Pt nanoparticles but also optimize the electronic structures of Pt/C catalysts toward ORR.

A toolpath strategy for improving geometric accuracy in double-sided incremental sheet forming

The double-sided incremental forming(DSIF)improved the process flexibility compared to other incremental sheet forming(ISF)processes.Despite the flexible nature,it faces the challenge of low geometric precision like ISF variants.In this work,two strategies are used to overcome this.First,a novel method is employed to determine the optimal support tool location for improving geometric precision.In this method,the toolpath oriented the tools to each other systematically in the circumferential direction.Besides,it squeezed the sheet by the same amount at the point of interest.The impacts of various support tool positions in the circumferential direction are evaluated for geometric precision.The results demonstrate that the support tool should support the master tool within 10°to its local normal in the circumferential direction to improve the geometric accuracy.Second,a two-stage process reduced the geometric error of the part by incrementally accommodating the springback error by artificially increasing the step size for the second stage.With the optimal support tool position and two-stage DSIF,the geometric precision of the part has improved significantly.The proposed method is compared to the best DSIF toolpath strategies for geometric accuracy,surface roughness,forming time,and sheet thickness fluctuations using grey relational analysis(GRA).It outperforms the other toolpath strategies including single-stage DSIF,accumulative double-sided incremental forming(ADSIF),and two-stage mixed double sided incre-mental forming(MDSIF).Our approach can improve geometric precision in complex parts by successfully employing the support tool and managing the springback incrementally.

Damage mechanism and evaluation model of compressor impeller remanufacturing blanks:A review

The theoretical and technological achievements in the damage mechanism and evaluation model obtained through the national basic research program“Key Fundamental Scientific Problems on Mechanical Equipment Remanufacturing”are reviewed in this work.Large centrifugal compressor impeller blanks were used as the study object.The materials of the blanks were FV520B and KMN.The mechanism and evaluation model of ultra-high cycle fatigue,erosion wear,and corrosion damage were studied via theoretical calculation,finite element simulation,and experimentation.For ultra-high cycle fatigue damage,the characteristics of ultra-high cycle fatigue of the impeller material were clarified,and prediction models of ultra-high cycle fatigue strength were established.A residual life evaluation technique based on the“b-HV-N”(where b was the nonlinear parameter,HV was the Vickers hardness,and N was the fatigue life)double criterion method was proposed.For erosion wear,the flow field of gas-solid two-phase flow inside the impeller was simulated,and the erosion wear law was clarified.Two models for erosion rate and erosion depth calculation were established.For corrosion damage,the electrochemical and stress corrosion behaviors of the impeller material and welded joints in H2S/CO2 environment were investigated.KISCC(critical stress intensity factor)and da/dt(crack growth rate,where a is the total crack length and t is time)varied with H2S concentration and temperature,and their variation laws were revealed.Through this research,the key scientific problems of the damage behavior and mechanism of remanufacturing objects in the multi-strength field and cross-scale were solved.The findings provide theoretical and evaluation model support for the analysis and evaluation of large centrifugal compressor impellers before remanufacturing.