Recent Progress in Atmospheric Chemistry Research in China: Establishing a Theoretical Framework for the “Air Pollution Complex”

Atmospheric chemistry research has been growing rapidly in China in the last 25 years since the concept of the“air pollution complex”was first proposed by Professor Xiaoyan TANG in 1997.For papers published in 2021 on air pollution(only papers included in the Web of Science Core Collection database were considered),more than 24000 papers were authored or co-authored by scientists working in China.In this paper,we review a limited number of representative and significant studies on atmospheric chemistry in China in the last few years,including studies on(1)sources and emission inventories,(2)atmospheric chemical processes,(3)interactions of air pollution with meteorology,weather and climate,(4)interactions between the biosphere and atmosphere,and(5)data assimilation.The intention was not to provide a complete review of all progress made in the last few years,but rather to serve as a starting point for learning more about atmospheric chemistry research in China.The advances reviewed in this paper have enabled a theoretical framework for the air pollution complex to be established,provided robust scientific support to highly successful air pollution control policies in China,and created great opportunities in education,training,and career development for many graduate students and young scientists.This paper further highlights that developing and low-income countries that are heavily affected by air pollution can benefit from these research advances,whilst at the same time acknowledging that many challenges and opportunities still remain in atmospheric chemistry research in China,to hopefully be addressed over the next few decades.

Impacts of canopy structure on the sub-canopy solar radiation under a deciduous forest based on fisheye photographs

Forest canopy in a deciduous forest has significant sheltering effects on the sub-canopy solar radiation,significantly influencing the energy balance of snow and permafrost beneath the forest and their spatial distribution.This study employs a digital camera mounted with a fisheye lens to acquire photographs at various times in a growth cycle of the forest canopy at three selected sites in a deciduous forest near the Greater Khingan Mountains Forest Ecological Station,Northeast China.The vegetation types and conditions at the selected sites include P1 in Ledum-Claopodium-L.dahurica,P2 in Carex tato-L.dahurica,and P3 in Betula fruticosa-L.dahurica.After necessary image processing,these photographs were used to identify the canopy structure and its impacts on the sub-canopy solar radiation.Results show that fisheye photographs can successfully capture the forest canopy structure and are useful in estimating the sub-canopy solar radiation.The order of sheltering effects from the largest to the smallest on sub-canopy solar radiation at three selected sites is P3,P1,and P2,highly depending on the canopy density.Then sub-canopy solar radiation was calculated using fisheye photographs and an algorithm validated by in-situ observed solar radiation beneath the canopy at P1 and P3.The results are reasonable,although the accuracy seems compromised due to the mismatch of conditions for calculation and observation.Results also show that the mean annual solar radiation above the canopy was about 148.3 W/m2 in 2018,and the mean annual solar radiation values beneath the canopy were about 90.0,123.8,and 61.0 W/m2 at P1,P2,and P3,with only 60%,84%,and 42%of the total solar radiation penetrating through the canopy,respectively.Even in winter,when the trees are leafless,the canopy sheltering effects cannot be ignored in dense forests.Despite the limitations,fisheye photographs and related algorithms are useful in investigating the forest canopy structure and its impacts on sub-canopy solar radiation.

Study of seasonal snow cover influencing the ground thermal regime on western flank of Da Xing'anling Mountains,northeastern China

Although many studies relevant to snow cover and permafrost have focused on alpine, arctic, and subarctic areas, there is still a lack of understanding of the influences of seasonal snow cover on the thermal regime of the soils in permafrost regions in the mid-latitudes and boreal regions, such as that on the western flank of the Da Xing'anling(Hinggan) Mountains, northeastern China. This paper gives a detailed analysis on meteorological data series from 2001 to 2010 provided by the Gen'he Weather Station, which is located in a talik of discontinuous permafrost zone and with sparse meadow on the observation field. It is inferred that snow cover is important for the ground thermal regime in the middle Da Xing'anling Mountains. Snow cover of 10-cm in thickness and five to six months in duration(generally November to next March) can reduce the heat loss from the ground to the atmosphere by 28%, and by 71% if the snow depth increases to 36 cm. Moreover, the occurrence of snow cover resulted in mean annual ground surface temperatures 4.7–8.2 °C higher than the mean annual air temperatures recorded at the Gen'he Weather Station. The beginning date for stable snow cover establishment(SE date) and the initial snow depth(SDi) also had a great influences on the ground freezing process. Heavy snowfall before ground surface freeze-up could postpone and retard the freezing process in Gen'he. As a result, the duration of ground freezing was shortened by at least 20 days and the maximum depth of frost penetration was as much as 90 cm shallower.

The efficacy of Kriging spatial interpolation for filling temporal gaps in daily air temperature data: A case study in northeast China

daily air temperature;;gap filling;;Kriging spatial interpolation;;northeast

Vegetation impact on the thermal regimes of the active layer and near-surface permafrost in the Greater Hinggan Mountains, Northeastern China

The ground temperature and active layer are greatly influenced by vegetation in the Greater Hinggan Mountains in Northeastern China.However,vegetation,as a complex system,is difficult to separate the influence of its different components on the ground thermal regime.In this paper,four vegetation types,including a Larix dahurica–Ledum palustre var.dilatatum–Bryum forest(P1),a L.dahurica–Betula fruticosa forest(P2),a L.dahurica–Carex tato forest(P3) in the China Forest Ecological Research Network Station in Genhe,and a Carex tato swamp(P4) at the permafrost observation site in Yitulihe,have been selected to study and compare their seasonal and annual influence on the ground thermal regime.Results show that the vegetation insulates the ground resulting in a relatively high ground temperature variability in the Carex tato swamp where there are no tree stands and shrubs when compared with three forested vegetation types present in the area.Vegetation thickness,structure,and coverage are the most important factors that determine the insulating properties of the vegetation.In particular,the growth of ground cover,its water-holding capacity and ability to intercept snow exert a significant effect on the degree of insulation of the soil under the same vegetation.

Study the relationship between the expression of MRP and the radiosensitivity of primary lesions of nasopharyngeal carcinoma

Objective: To study the relationship between the expression of multidrug resistance-associated protein (MRP) gene in nasopharyngeal carcinoma (NPC) and the radiosensitivity of primary lesions of NPC. Methods: Total 51 cases of NPC were analyzed retrospectively, who were treated by radiotherapy between January 1, 1999 and December 31, 2000 in our department, including the cases of pure radiotherapy and chemotherapy after radiotherapy. Using immunohistochemiscal S-P method, the expression of MRP in NPC was detected, and the relationship with the radiosensitivity of primary lesions of NPC was analyzed. Results: The rate of positive expression was 68.63% (35/51) in NPC, and there were significant difference between T stages (P<0.05), but no significant difference with radiosensitivity of primary lesions of NPC (P>0.05). Conclusion: There is a higher expression of MRP in NPC, but it has no relationship with radiosensitivity of primary lesions of NPC. So MRP can not be regarded as the predictive marker of radiosensitivity of primary lesions of NPC.

E-Healthcare Supported by Big Data

The era of open information in healthcare has arrived. E-healthcare supported by big data supports the move toward greater transparency in healthcare by making decades of stored health data searchable and usable. This paper gives an overview the e-healthcare architecture. We discuss the four layers of the architecture—data collection, data transport, data storage, and data analysis—as well as the challenges of data security, data privacy, real-time delivery, and open standard interface. We discuss the necessity of establishing an impeccably secure access mechanism and of enacting strong laws to protect patient privacy.

燃烧源氨排放对灰霾期间北京大气铵的重要贡献

Aerosol ammonium(NH_(4)^(+)),mainly produced from the reactions of ammonia(NH_(3))with acids in the atmosphere,has significant impacts on air pollution,radiative forcing,and human health.Understanding the source and formation mechanism of NH_(4)^(+)can provide scientific insights into air quality improvements.However,the sources of NH_(3)in urban areas are not well understood,and few studies focus on NH_(3)/NH_(4)^(+)at different heights within the atmospheric boundary layer,which hinders a comprehensive understanding of aerosol NH_(4)^(+).In this study,we perform both field observation and modeling studies(the Community Multiscale Air Quality,CMAQ)to investigate regional NH_(3)emission sources and vertically resolved NH_(4)^(+)formation mechanisms during the winter in Beijing.Both stable nitrogen isotope analyses and CMAQ model suggest that combustion-related NH_(3)emissions,including fossil fuel sources,NH_(3)slip,and biomass burning,are important sources of aerosol NH_(4)^(+)with more than 60%contribution occurring on heavily polluted days.In contrast,volatilization-related NH_(3)sources(livestock breeding,N-fertilizer application,and human waste)are dominant on clean days.Combustion-related NH_(3)is mostly local from Beijing,and biomass burning is likely an important NH_(3)source(~15%–20%)that was previously overlooked.More effective control strategies such as the two-product(e.g.,reducing both SO_(2)and NH_(3))control policy should be considered to improve air quality.

δ^(15)N-stable isotope analysis of NH_(x): An overview on analytical measurements, source sampling and its source apportionment

Agricultural sources and non-agricultural emissions contribute to gaseous ammonia(NH_(3))that plays a vital role in severe haze formation.Qualitative and quantitative contributions of these sources to ambient PM_(2.5)(particulate matter with an aerodynamic equivalent diameter below 2.5µm)concentrations remains uncertain.Stable nitrogen isotopic composition(δ^(15)N)of NH_(3)and NH_(4)+(δ^(15)N(NH_(3))andδ^(15)N(NH_(4)+),respectively)can yield valuable information about its sources and associated processes.This review provides an overview of the recent progress in analytical techniques forδ^(15)N(NH_(3))andδ^(15)N(NH_(4)+)measurement,sampling of atmospheric NH_(3)and NH_(4)+in the ambient air and their sources signature(e.g.,agricultural vs.fossil fuel),and isotope-based source apportionment of NH_(3)in urban atmosphere.This study highlights that collecting sample that are fully representative of emission sources remains a challenge in fingerprintingδ^(15)N(NH_(3))values of NH_(3)emission sources.Furthermore,isotopic fractionation during NH_(3)gas-to-particle conversion under varying ambient field conditions(e.g.,relative humidity,particle pH,temperature)remains unclear,which indicates more field and laboratory studies to validate theoretically predicted isotopic fractionation are required.Thus,this study concludes that lack of refinedδ^(15)N(NH_(3))fingerprints and full understanding of isotopic fractionation during aerosol formation in a laboratory and field conditions is a limitation for isotope-based source apportionment of NH_(3).More experimental work(in chamber studies)and theoretical estimations in combinations of field verification are necessary in characterizing isotopic fractionation under various environmental and atmospheric neutralization conditions,which would help to better interpret isotopic data and our understanding on NH_(x)(NH_(3)+NH_(4)+)dynamics in the atmosphere.

Geological controls of shale gas accumulation and enrichment mechanism in Lower Cambrian Niutitang Formation of western Hubei, Middle Yangtze, China

The lower Cambrian Niutitang Formation is of crucial importance for shale gas target reservoirs in western Hubei,China;however,little work has been done in this field,and its shale gas accumulation and enrichment mechanism are still unclear.Based on survey wells,outcrop data,and large numbers of tests,the geological conditions of shale gas accumulation were studied;moreover,the factors that influence the gas content were thoroughly discussed.The results show that the Niutitang Formation(Є1n)can be divided into three sections:the first section(Є_(1)n^(1)),the second section(Є_(1)n^(2)),and the third section(Є1n3).TheЄ_(1)n^(2) is the main shale gas reservoir.The deep shelf facies is the main sedimentary facies and can be divided into three main lithofacies:argillaceous siltstone,carbonaceous shale and carbonaceous siliceous rock.The total organic carbon(TOC)content shows gentle growth trends until bottom of theЄ_(1)n^(2) and then decreases rapidly within theЄ_(1)n^(1),and the TOC content mainly ranges from 2%to 4%horizontally.The calcite and dolomite dissolution pores,clay intergranular pores and organic pores are the main pore types and the micropore types are clearly related to the mineral compositions and the TOC content.Vertically,the gas content is mainly affected by the TOC content.Horizontally,wells with high gas contents are distributed only southeast of the Huangling anticline,and the combination of structural styles,fault and fracture development,and the distribution of the regional unconformity boundary between the upper Sinian Dengying Formation(Z2d)and theЄ_(1)n^(2) are the three most important factors affecting the gas content.The favorable areas must meet the following conditions:a deep shelf environment,the presence of theЄ_(1)n^(1),wide and gentle folds,far from large normal faults that are more than 5 km,moderate thermal evolution,and greater than 500 m burial depth;this includes the block with the YD2–ZD2 wells,and the block with the Y1 and YD4 wells,which are distributed in the southern portion of the Huangling anticline and northern portion of the Xiannvshan fault.

Optimized design of the power consumption test of mountain orchard transporters

In order to study the influence rule of various factors on the operating power consumption of the traction orchard transporter and realize the optimal design of the operation power consumption of the transporter,according to the traditional experience and the existing research foundation,the monorail transporter test bench was designed and built on the basis of the whole structure and operation characteristics of the transporter.Taking the motor frequency,track gradient and load as the investigation factors,and the driving shaft power,shaft power transmission and mechanical efficiency as the evaluation indices,the orthogonal test was conducted,and the range analysis of the influence effect was carried out according to the test results.The primary and secondary orders of the influence of various factors were obtained that motor frequency was greater than track gradient and track gradient was greater than load.According to the orthogonal test results,the second-order response surface method was used to establish the optimization model of the power consumption of the transporter,and the model was verified on the test bench.The results showed that the relative error between the model optimization value and the test value based on the response surface power optimization model was less than 10%,which indicated that the power optimization model had satisfactory performance.The research can provide a reference for the orchard conveyor to choose the parameter combination which can save power consumption and the motor that matches power consumption.

Development and test of hydraulic driven remote transporter

To solve the problems of the traditional orchard conveyor,such as inflexible steering,a complex structure,poor stability and no power grid coverage,a remote-controlled rail conveyor powered by hydraulic pressure for mountainous orchards was designed and manufactured.Climbing stress analysis was carried out on a full-load trailer to obtain the maximum traction force,which met the requirement of the climbing slope of the transport mechanism.The key components of the conveyor were developed,such as the hydraulic transmission,the control system,safety protection devices,limiting devices,the throttle and decompression actuator,the counterweight tension and the battery.Through the theoretical calculations of key components,an orchard conveyor powered by diesel and hydraulic pressure was designed.Finally,the working performance of the transporter was tested through functionality,driving speed,system pressure and remote-controlled tests.The test results showed that the climbing angle of the transporter can reach 50°,the uphill load can reach 840 kg,the downhill load can reach 1100 kg,and the average running speed is 0.77 m/s;the driving speed ranges from 0.29 m/s to 1.08 m/s,and the system pressure ranges from 3.2 MPa to 10 MPa.The driving speed and system pressure are significantly affected by the load,and the remote control distance can reach 455 m.The technical specifications of the transporter meet all the design requirements,and the problem of stable operation of the transporter without power grid coverage has been addressed.The research results can well meet the practical application requirements of mountain orchard transportation without power grid coverage and provide theoretical reference for the design of key components of mountain orchard transportation machinery.

A coupled catalyst composed of CoFe_(2)O_(4) magnetic nanoparticle and[HMIM]Br-FeCl_(3) to intensify the oxidative desulfurization of FCC diesel

Ionic liquids have been extensively studied as solvents or catalysts for oxidative desulfurization(ODS)of diesel fuel,but it is still a challenge to reduce the desulfurization time and steps.In this work,a new highly efficient desulfurization system composed of CoFe_(2)O_(4) magnetic nanoparticle,[HMIM]Br-FeCl_(3) and H_(2)O_(2) was developed for the ODS of FCC diesel fuel.The desulfurization performances were investigated including desulfurization time,temperature,volume ratio of IL/oil,O/S molar ratio,dosage of CoFe_(2)O_(4),FeCl_(3) content in ILs,regeneration,and reuse of catalyst and solvent.Owing to the coupled catalytic roles of CoFe_(2)O_(4) magnetic nanoparticle and[HMIM]Br-FeCl_(3),where Co2t and Fe3t interact with H_(2)O_(2) to produce ·OH radical that converts S-compounds into sulfone and sulfoxide compounds,such a desulfurization system is highly effective in removing S-compound in diesel fuel.The S-content in FCC diesel fuel was reduced from the original 272.8 ppm to 0.5 ppm with 99.82%S-removal efficiency after one step within 8 minunder the optimal conditions of 25℃,8 min,V(IL/oil)=1:10,O/S=20,5 wt%CoFe_(2)O_(4) dosage and n([HMIM]Br)/n(FeCl_(3))=1:1;the desulfurization performance is much better in desulfurization time and steps than other desulfurization systems reported previously.The desulfurization system can be regenerated and reused without remarkable loss of desulfurization activity.A desulfurization mechanism was proposed.