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聚合诱导自组装制备形貌多样的ABA型三嵌段共聚物微/纳米粒子 被引量:1
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作者 刘佳丽 燕春福 +4 位作者 惠嘉 杨海宾 苏志鹏 曹艳玲 石艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第4期7-12,共6页
以聚N,N-二甲基丙烯酰胺(PDMA)为大分子链转移剂、苯乙烯(St)为单体,采用可逆加成-断裂链转移(RAFT)分散聚合制备了PDMA-b-PS-b-PDMA两亲性三嵌段共聚物胶束。考察了固含量和疏、亲溶剂链段比对胶束尺寸、形貌的影响。固含量为25%和30%... 以聚N,N-二甲基丙烯酰胺(PDMA)为大分子链转移剂、苯乙烯(St)为单体,采用可逆加成-断裂链转移(RAFT)分散聚合制备了PDMA-b-PS-b-PDMA两亲性三嵌段共聚物胶束。考察了固含量和疏、亲溶剂链段比对胶束尺寸、形貌的影响。固含量为25%和30%时,胶束形貌转化过程是从球状、蠕虫状向囊泡状胶束发展,最终得到大小2种尺寸的嵌段共聚物形貌囊泡。固含量为30%,疏、亲溶剂链段比为300∶32和400∶32时,分别获得平均粒径约为900/310 nm和400/210 nm的大小囊泡;固含量为25%,疏、亲溶剂链段比为400∶32时,大小囊泡的尺寸分别约为520 nm和200 nm。固含量为35%和40%时,胶束形貌则由球状逐渐向海绵状、复合囊泡,大复合胶束转变,最终得到微米级大复合胶束。 展开更多
关键词 聚合诱导自组装 嵌段共聚物 分散聚合
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Ultrasound on Seedling Growth of Wheat under Drought Stress Effects 被引量:2
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作者 Haiyan Ran Liyan Yang yanling cao 《Agricultural Sciences》 2015年第7期670-675,共6页
This study used different intensity ultrasound treatments, wheat seedlings in the germination energy, germination rate, growth potential, root length, and number of lateral roots optimal radiation dose selection. Stud... This study used different intensity ultrasound treatments, wheat seedlings in the germination energy, germination rate, growth potential, root length, and number of lateral roots optimal radiation dose selection. Studied under drought stress were the optimal dose of radiation treatment of wheat seedling leaf relative water content (RWC), protein content, Methane Dicarboxylic Aldehyde (MDA) content, relative conductivity, Superoxide dismutase (SOD) activity, and the impact of amylase activity. Studies have shown that after ultrasonic treatment enhanced drought resistance of wheat seedlings, alleviate drought stress on wheat seedling injury to 65 W 15 min ultrasonic treatment works best. 展开更多
关键词 DROUGHT STRESS ULTRASOUND DROUGHT RESISTANCE
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Preparation of ABA triblock copolymer assemblies through “one-pot” RAFT PISA 被引量:1
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作者 yanling cao Yan Shi +1 位作者 Xiaohui Wu Liqun Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第6期1660-1664,共5页
Poly(N,N-dimethyl acrylamide)-block-poly(styrene)-block-poly(N,N-dimethyl acrylamide)(PDMAc-bPSt-b-PDMAc)amphiphilic triblock copolymer micro/nano-objects were synthesized through reversible addition-fragmentation cha... Poly(N,N-dimethyl acrylamide)-block-poly(styrene)-block-poly(N,N-dimethyl acrylamide)(PDMAc-bPSt-b-PDMAc)amphiphilic triblock copolymer micro/nano-objects were synthesized through reversible addition-fragmentation chain transfer(RAFT)dispersion polymerization of St mediated with poly(N,Ndimethyl acrylamide)trithiocarbonate(PDMAc-TTC-PDMAc)bi-functional macromolecular RAFT agent.It is found that the morphology of the PDMAc-b-PSt-b-PDMAc copolymer micro/nano-objects like spheres,vesicles and vesicle with hexagonally packed hollow hoops(HHHs)wall can be tuned by changing the solvent composition.In addition,vesicles with two sizes(600 nm,264 nm)and vesicles with HHHs features were also synthesized in high solid content systems(30 wt%and 40 wt%,respectively).Besides,as compared with typical AB diblock copolymers(A is the solvophilic,stabilizer block,and B is the solvophobic block),ABA triblock copolymers tend to form higher order morphologies,such as vesicles,under similar conditions.The finding of this study provides a new and robust approach to prepare block copolymer vesicles and other higher order micelles with special structure via PISA. 展开更多
关键词 Reversible addition-fragmentation chain transfer POLYMERIZATION Polymerization induced self-assembly Triblock copolymer Dispersion polymerization Block copolymer micelles
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