The synthesis of degradable polymers with easy-to-break in-chain carbon-oxygen bonds has attracted much attention.This minireview introduces the synthesis of a variety of degradable polymers from the(co)polymerization...The synthesis of degradable polymers with easy-to-break in-chain carbon-oxygen bonds has attracted much attention.This minireview introduces the synthesis of a variety of degradable polymers from the(co)polymerizations of several typical oxygenated monomers such as epoxides,cyclic carbonates,cyclic esters,carbon dioxide(CO_(2)),carbonyl sulfide(COS),and cyclic anhydrides.We highlight the catalysts and mechanisms for these(co)polymerizations.The ring-opening copolymerization of five-membered carbonate with cyclic anhydride or COS has been introduced.We also highlight the synthesis of block copolymers and cyclic copolymers with well-defined sequences by the method of growing center switching.We hope that these new polymerization systems can provide new ideas for the development of degradable low-carbon polymers in the future.展开更多
基金the National Science Foundation of China(Nos.52203129,51973190)Zhejiang Provincial Department of Science and Technology(No.2020R52006).
文摘The synthesis of degradable polymers with easy-to-break in-chain carbon-oxygen bonds has attracted much attention.This minireview introduces the synthesis of a variety of degradable polymers from the(co)polymerizations of several typical oxygenated monomers such as epoxides,cyclic carbonates,cyclic esters,carbon dioxide(CO_(2)),carbonyl sulfide(COS),and cyclic anhydrides.We highlight the catalysts and mechanisms for these(co)polymerizations.The ring-opening copolymerization of five-membered carbonate with cyclic anhydride or COS has been introduced.We also highlight the synthesis of block copolymers and cyclic copolymers with well-defined sequences by the method of growing center switching.We hope that these new polymerization systems can provide new ideas for the development of degradable low-carbon polymers in the future.
