Lithium-ion batteries(LIBs) have been developed for over 30 years;however, existing electrode materials cannot satisfy the increasing requirements of high-energy density, stable cycling, and low cost. Here, we present...Lithium-ion batteries(LIBs) have been developed for over 30 years;however, existing electrode materials cannot satisfy the increasing requirements of high-energy density, stable cycling, and low cost. Here, we present a perovskite-type LaNiO3 oxide(LNO) as a new negative electrode material. LNO was successfully synthesized by a sol-gel method. The microstructure and electrochemical performance of LNO calcined at various temperatures have been systematically investigated. The LNO electrode shows a high rate capability and long cycling stability. In a C-rate test, a specific capacity of 77 mAh/g was exhibited at 6 C. LNO can also deliver a specific capacity of 92 mAh/g after 200 cycles at 1 C. This paper presents a type of binary metal oxide as a new anode material for high-performance LIBs.展开更多
基金supported by the National Natural Science Foundations of China (No. 21805185)ShanghaiTech University Start-Up Funding.
文摘Lithium-ion batteries(LIBs) have been developed for over 30 years;however, existing electrode materials cannot satisfy the increasing requirements of high-energy density, stable cycling, and low cost. Here, we present a perovskite-type LaNiO3 oxide(LNO) as a new negative electrode material. LNO was successfully synthesized by a sol-gel method. The microstructure and electrochemical performance of LNO calcined at various temperatures have been systematically investigated. The LNO electrode shows a high rate capability and long cycling stability. In a C-rate test, a specific capacity of 77 mAh/g was exhibited at 6 C. LNO can also deliver a specific capacity of 92 mAh/g after 200 cycles at 1 C. This paper presents a type of binary metal oxide as a new anode material for high-performance LIBs.