Lithium-sulfur batteries are considered important devices for the power of movable equipment,but there are still some challenges that limit their applications,such as how to obtain a cathode for high sulfide adsorptio...Lithium-sulfur batteries are considered important devices for the power of movable equipment,but there are still some challenges that limit their applications,such as how to obtain a cathode for high sulfide adsorption and rapid conversion.Here,a new strategy is proposed to enhance the performance of lithium-sulfur batteries by growing 3-dimensional hydrogen-substituted graphdiyne(HsGDY)layers on Ni foam via Glaser cross-coupling reaction to anchor MoS_(2)/Ni_(3)S_(2),enhancing the conductivity of host material of S.The results show that the 3-dimensional HsGDY framework enables the fast adsorption of lithium polysulfides and the Ni_(3)S_(2)/MoS_(2) performs as the reaction center with a low charge transfer resistance.The charge capacity of Ni@HsGDY/MoS_(2)/Ni_(3)S_(2) cell is up to 1,234.7 mAh·g^(−1) at the first circle,and the specific capacity keeps 486 mAh·g^(−1) after 500 cycles at a current density of 2 C.The incorporation of HsGDY into the cathode promotes the adsorption and the conversion of polysulfides,paving a path to obtain lithium-sulfur batteries with high energy density.展开更多
In the Research Article“HsGDY on Ni Foam for Loading MoS_(2)/Ni_(3)S_(2) to Enhance the Performance on Lithium-Sulfur Batteries”[1],the publisher made an error.“235.0 and 232.0 eV from 235.7 and 232.0 eV”should be...In the Research Article“HsGDY on Ni Foam for Loading MoS_(2)/Ni_(3)S_(2) to Enhance the Performance on Lithium-Sulfur Batteries”[1],the publisher made an error.“235.0 and 232.0 eV from 235.7 and 232.0 eV”should be replaced with“235.4 and 232.3 eV from 235.7 and 232.4 eV”in the sentence,“As shown in Fig.4B,after adsorbing the Li2S6,the Mo 3d_(3/2) and Mo 3d_(5/2) XPS peaks of Mo^(4+)in MoS_(2) shift toward lower binding energies of 235.0 and 232.0 eV from 235.7 and 232.0 eV,respectively,indicating increased electron density at the metal center.”This has now been corrected in the PDF and HTML(full text).展开更多
基金Guangdong Basic and Applied Basic Research Foundation(2021A1515110152,2022A1515240007,and 2023A1515010562)Special Fund for the Sci-tech Innovation Strategy of Guangdong Province(STKJ202209083,STKJ202209066,2020ST006,and 210719165864287)+3 种基金Characteristic Innovation Project of Colleges and Universities in Guangdong(2021KTSCX030)Scientific Research Foundation of Shantou University(NTF20005 and NTF22018)Scientific Research Foundation of Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center(QD2221007)2020 Li Ka Shing Foundation Cross-Disciplinary Research Grant(2020LKSFG01A).
文摘Lithium-sulfur batteries are considered important devices for the power of movable equipment,but there are still some challenges that limit their applications,such as how to obtain a cathode for high sulfide adsorption and rapid conversion.Here,a new strategy is proposed to enhance the performance of lithium-sulfur batteries by growing 3-dimensional hydrogen-substituted graphdiyne(HsGDY)layers on Ni foam via Glaser cross-coupling reaction to anchor MoS_(2)/Ni_(3)S_(2),enhancing the conductivity of host material of S.The results show that the 3-dimensional HsGDY framework enables the fast adsorption of lithium polysulfides and the Ni_(3)S_(2)/MoS_(2) performs as the reaction center with a low charge transfer resistance.The charge capacity of Ni@HsGDY/MoS_(2)/Ni_(3)S_(2) cell is up to 1,234.7 mAh·g^(−1) at the first circle,and the specific capacity keeps 486 mAh·g^(−1) after 500 cycles at a current density of 2 C.The incorporation of HsGDY into the cathode promotes the adsorption and the conversion of polysulfides,paving a path to obtain lithium-sulfur batteries with high energy density.
文摘In the Research Article“HsGDY on Ni Foam for Loading MoS_(2)/Ni_(3)S_(2) to Enhance the Performance on Lithium-Sulfur Batteries”[1],the publisher made an error.“235.0 and 232.0 eV from 235.7 and 232.0 eV”should be replaced with“235.4 and 232.3 eV from 235.7 and 232.4 eV”in the sentence,“As shown in Fig.4B,after adsorbing the Li2S6,the Mo 3d_(3/2) and Mo 3d_(5/2) XPS peaks of Mo^(4+)in MoS_(2) shift toward lower binding energies of 235.0 and 232.0 eV from 235.7 and 232.0 eV,respectively,indicating increased electron density at the metal center.”This has now been corrected in the PDF and HTML(full text).