Diet is one of the main pathways for heavy metals to enter the human body,so studying the content of heavy metals in agricultural products and evaluating them is of great significance.When farmland soil is contaminate...Diet is one of the main pathways for heavy metals to enter the human body,so studying the content of heavy metals in agricultural products and evaluating them is of great significance.When farmland soil is contaminated with heavy metals,the heavy metals accumulated in the soil will be absorbed by the roots of rice plants growing on it,and will migrate and transform between different tissues and organs of rice plants.There is a significant correlation between heavy metal pollution in soil and the content of heavy metals in rice.The migration and enrichment of heavy metals in the agricultural soil rice system is a complex process that is influenced by many factors,such as the physical and chemical properties of the soil,the content and occurrence forms of heavy metals in the soil,and the physiological characteristics of rice plants.In actual field environments,these influencing factors have significant spatial differences and are relatively complex.Therefore,it is necessary to conduct practical analysis of the various influencing factors in actual field environments.Based on actual data analysis,studying the heavy metal content in rice and the characteristics of heavy metal accumulation and migration in rice plants is of great significance for improving the food safety of rice.展开更多
The Chinese compound Kaixin fieyu Fang can be used to treat vascular depression; however, the underlying mechanism remains unclear. This study established a rat model of chronic cerebral ischemia-caused white matter d...The Chinese compound Kaixin fieyu Fang can be used to treat vascular depression; however, the underlying mechanism remains unclear. This study established a rat model of chronic cerebral ischemia-caused white matter damage by ligation of the bilateral common carotid arteries. Rats received daily intragastric administration of a suspension of Kaixin ]ieyu Fang powder. After 3, 7 and 21 days of treatment, the degree of white matter damage in the cerebral ischemia rat model was alleviated, Bcl-2 protein and mRNA expression in brain tissue increased, and Bax protein and mRNA expression decreased. These results indicate that Kaixin Jieyu Fang can alleviate cere- bral white matter damage, and the underlying mechanism is associated with regulation of Bcl-2/ Bax protein and mRNA expression, which is one of possible mechanism behind the protective effect of Kaixin Jieyu Fang against vascular depression.展开更多
The iron oxide nanoparticles(IONPs)that combine the nanozyme activity and magnetothermal properties have attracted significant interest for various biomedical applications.However,the effect of magnetic stimulation in...The iron oxide nanoparticles(IONPs)that combine the nanozyme activity and magnetothermal properties have attracted significant interest for various biomedical applications.However,the effect of magnetic stimulation in fine-tuning the nanozyme activities remains unclear.Here,we have constructed a series of IONPs with different magneto-thermal conversion abilities,and systematically study the effect of magnetic field stimulation on the peroxidase(POD)activity of IONPs.The results show that POD activity is effectively amplified via an in situ alternating magnetic field(AMF)stimulation with no solution temperature rise,and the degree of activity enhancement is closely related to the magnetic heating ability of the IONPs,confirming the origin of activity enhancement arises from the local magnetothermal effect.As the first report to prove magnetothermal regulation on nanozyme activity and to shed lights on the underlying correlation between activity enhancement and the intrinsic specific absorption rate(SAR),this work is expected to provide important support for future design of new magnetoresponsive nanozymes in various practical applications.展开更多
A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high ...A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high resolution inductively coupled plasma mass spectrometry(HR-ICP-MS)measurement.^(75)Se(Ⅳ) and ^(75)Se(Ⅵ)were prepared and used as tracers during the experiments.The volatility of selenium during solution evaporation was investigated to establish a reliable water samples pretreatment procedure.The parameters which affect the uptake of Se(Ⅳ)and Se(Ⅵ)on Dowex1×8 resin was optimized and the procedure for Se(Ⅳ)and Se(Ⅵ)separation was proposed.Both Se(Ⅳ)and Se(Ⅵ)are retained on the column in natural or alkaline solution with high distribution coefficient.The successive gradient elution of pre-concentrated species of selenium with HNO_(3)solution allows to differentiate between them.Se(Ⅳ)and Se(Ⅵ)finally were eluted with 0.05 mol/L HNO_(3) and 5.0 mol/L HNO_(3),respectively.The proposed method has been successfully verified using the certified reference materials(CRMs)of real water samples,and spiked recoveries for real samples were 98%-104%with 5%relative standard deviations(RSDs).The developed procedure is proved to be reliable and can be used for the rapid determination of selenium species in environmental water samples.展开更多
Xinjiang Uygur Autonomous Region,the largest agricultural high-efficiency water-saving arid area in China,was adopted to explore the coupling relationship between agricultural water consumption and economic benefits,w...Xinjiang Uygur Autonomous Region,the largest agricultural high-efficiency water-saving arid area in China,was adopted to explore the coupling relationship between agricultural water consumption and economic benefits,which is of great significance to guiding the efficient utilization and sustainable development of agricultural water resources.This study utilizes an indicator,termed the Agricultural Water Footprint Intensity(short as AWFI,which means the amount of water resource consumed per unit of agricultural GDP),to study the economic benefits of agricultural water in Xinjiang from 1991-2018.In addition,the Theil index,a measure of the imbalance between individuals or regions,was used to study the evolution in the spatial differences in water efficiency,and the Logarithmic Mean Divisia Index(LMDI)method was applied to quantify the factors driving the AWFI.The results showed that AWFI in Xinjiang has experienced three stages:obvious decline,stable and slow decline,which decreased from 16114 m^(3)/10^(4) CNY to 2100 m^(3)/10^(4) CNY,decreasing by 86.97%.The Theil index indicated that the spatial evolution of 14 prefectures(cities)resembled an inverted N-shaped Kuznets curve over time.Among the influencing factors,the contributions of water-saving technology and planting structure to the change in the AWFI in Xinjiang,China from 1991 to 2018 were 154.03%and−37.98%,respectively.The total contribution to AWFI of the total population,urbanization rate,and production scale was−16.06%.This study concluded that further improvements in the economic benefits of agricultural water consumption can be obtained by continuing to promote more efficient or“water-conservation”irrigation technologies(engineering aspects),adjusting the planting structure(policy guidance aspects),and intensive management of cultivated land(management aspects).展开更多
基金Supported by Natural Science Foundation of Fujian Province(2023J01130334)Natural Science Foundation of Xiamen City(3502Z20227315).
文摘Diet is one of the main pathways for heavy metals to enter the human body,so studying the content of heavy metals in agricultural products and evaluating them is of great significance.When farmland soil is contaminated with heavy metals,the heavy metals accumulated in the soil will be absorbed by the roots of rice plants growing on it,and will migrate and transform between different tissues and organs of rice plants.There is a significant correlation between heavy metal pollution in soil and the content of heavy metals in rice.The migration and enrichment of heavy metals in the agricultural soil rice system is a complex process that is influenced by many factors,such as the physical and chemical properties of the soil,the content and occurrence forms of heavy metals in the soil,and the physiological characteristics of rice plants.In actual field environments,these influencing factors have significant spatial differences and are relatively complex.Therefore,it is necessary to conduct practical analysis of the various influencing factors in actual field environments.Based on actual data analysis,studying the heavy metal content in rice and the characteristics of heavy metal accumulation and migration in rice plants is of great significance for improving the food safety of rice.
基金supported by the National Natural Science Foundation of China,No.30672696,81072801the Natural Science Foundation of Beijing in China,No.7093129
文摘The Chinese compound Kaixin fieyu Fang can be used to treat vascular depression; however, the underlying mechanism remains unclear. This study established a rat model of chronic cerebral ischemia-caused white matter damage by ligation of the bilateral common carotid arteries. Rats received daily intragastric administration of a suspension of Kaixin ]ieyu Fang powder. After 3, 7 and 21 days of treatment, the degree of white matter damage in the cerebral ischemia rat model was alleviated, Bcl-2 protein and mRNA expression in brain tissue increased, and Bax protein and mRNA expression decreased. These results indicate that Kaixin Jieyu Fang can alleviate cere- bral white matter damage, and the underlying mechanism is associated with regulation of Bcl-2/ Bax protein and mRNA expression, which is one of possible mechanism behind the protective effect of Kaixin Jieyu Fang against vascular depression.
基金supported by the National Natural Science Foundation of China(81771981,82072063,and 31400663)the National Natural Science Foundation for Young Scholars of China(31901003)+2 种基金Shaanxi Province Funds for Distinguished Young Scholars(202031900097)Shaanxi Science and Technology Department(2019KW-078)the Postdoctoral Science Foundation of China(2020M673631XB)。
文摘The iron oxide nanoparticles(IONPs)that combine the nanozyme activity and magnetothermal properties have attracted significant interest for various biomedical applications.However,the effect of magnetic stimulation in fine-tuning the nanozyme activities remains unclear.Here,we have constructed a series of IONPs with different magneto-thermal conversion abilities,and systematically study the effect of magnetic field stimulation on the peroxidase(POD)activity of IONPs.The results show that POD activity is effectively amplified via an in situ alternating magnetic field(AMF)stimulation with no solution temperature rise,and the degree of activity enhancement is closely related to the magnetic heating ability of the IONPs,confirming the origin of activity enhancement arises from the local magnetothermal effect.As the first report to prove magnetothermal regulation on nanozyme activity and to shed lights on the underlying correlation between activity enhancement and the intrinsic specific absorption rate(SAR),this work is expected to provide important support for future design of new magnetoresponsive nanozymes in various practical applications.
基金The financial support from National Natural Science Foundation of China(Nos.22061132004,U21A20442,22106059,22106057,21771093)Fundamental Research Funds for the Central Universities of China(No.lzujbky-2021-kb11,lzujbky-2021-sp41)Gansu guiding program of Science and Technology Innovation(No.20JR10RA610)are gratefully appreciated。
文摘A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high resolution inductively coupled plasma mass spectrometry(HR-ICP-MS)measurement.^(75)Se(Ⅳ) and ^(75)Se(Ⅵ)were prepared and used as tracers during the experiments.The volatility of selenium during solution evaporation was investigated to establish a reliable water samples pretreatment procedure.The parameters which affect the uptake of Se(Ⅳ)and Se(Ⅵ)on Dowex1×8 resin was optimized and the procedure for Se(Ⅳ)and Se(Ⅵ)separation was proposed.Both Se(Ⅳ)and Se(Ⅵ)are retained on the column in natural or alkaline solution with high distribution coefficient.The successive gradient elution of pre-concentrated species of selenium with HNO_(3)solution allows to differentiate between them.Se(Ⅳ)and Se(Ⅵ)finally were eluted with 0.05 mol/L HNO_(3) and 5.0 mol/L HNO_(3),respectively.The proposed method has been successfully verified using the certified reference materials(CRMs)of real water samples,and spiked recoveries for real samples were 98%-104%with 5%relative standard deviations(RSDs).The developed procedure is proved to be reliable and can be used for the rapid determination of selenium species in environmental water samples.
基金This work was financially supported by the Third Xinjiang Scientific Expedition(Grant No.2022xjkk0103,2021xjkk0406)the National Natural Science Foundation of China(Grant No.52179028)+1 种基金the Water Conservancy Science and Technology Project of Hunan Province(Grant No.XSKJ2019081-02)the Xinjiang Water Conservancy Science and technology project(Grant No.XSKJ-2021-01).
文摘Xinjiang Uygur Autonomous Region,the largest agricultural high-efficiency water-saving arid area in China,was adopted to explore the coupling relationship between agricultural water consumption and economic benefits,which is of great significance to guiding the efficient utilization and sustainable development of agricultural water resources.This study utilizes an indicator,termed the Agricultural Water Footprint Intensity(short as AWFI,which means the amount of water resource consumed per unit of agricultural GDP),to study the economic benefits of agricultural water in Xinjiang from 1991-2018.In addition,the Theil index,a measure of the imbalance between individuals or regions,was used to study the evolution in the spatial differences in water efficiency,and the Logarithmic Mean Divisia Index(LMDI)method was applied to quantify the factors driving the AWFI.The results showed that AWFI in Xinjiang has experienced three stages:obvious decline,stable and slow decline,which decreased from 16114 m^(3)/10^(4) CNY to 2100 m^(3)/10^(4) CNY,decreasing by 86.97%.The Theil index indicated that the spatial evolution of 14 prefectures(cities)resembled an inverted N-shaped Kuznets curve over time.Among the influencing factors,the contributions of water-saving technology and planting structure to the change in the AWFI in Xinjiang,China from 1991 to 2018 were 154.03%and−37.98%,respectively.The total contribution to AWFI of the total population,urbanization rate,and production scale was−16.06%.This study concluded that further improvements in the economic benefits of agricultural water consumption can be obtained by continuing to promote more efficient or“water-conservation”irrigation technologies(engineering aspects),adjusting the planting structure(policy guidance aspects),and intensive management of cultivated land(management aspects).