乡村治理视野下党规与村规民约的协同互动

乡村治理现代化是国家治理现代化的必然要求,乡村善治需要正式制度与非正式制度的融合发展。党规与村规民约都是国家治理体系的有机组成,也是国家治理能力在乡村社会施展的有效资源,两者在新时代乡村社会“三治融合”实践中具有功能同构的契合性。党规不仅强化村规民约的合法性,促进村规民约在性质地位、内容及程序方面的现代转型,而且推动村规民约的有效实施,由此保障村规民约制度建设。同时,村规民约也促进着党规制度建设,一方面通过促成和强化党规的“进场”和“在场”推动党规嵌入乡村社会,另一方面为完善党规制度提供群众智识、夯实群众基础。未来的乡村治理实践仍需重视两者的协同互动,以达成“最适宜的善治”。

Spectroscopic Characterization and Stereodynamics of Ferrocenylselenoethers Pt(Ⅱ),Pd(Ⅱ),Rh(Ⅲ) Complexes

Ferrocenlyselenides(C_(5)H_(5)FeC_(5)H_(4)SeR,Fe(C_(5)H_(4)SeR)_(2))and their complexes of metal Pt,Pd,Rh(R=undecenyl,benzyl,phenyl)have been prepared.The spectroscopic characterization has been examined by mass spectrum,XPS,IR and NMR.IR,NMR spectra of C_(5)H_(5)Fe C_(5)H_(4)Se(CH_(2))_(9)CH=CH_(2)PtCl_(2)reveal C=C double bond in Fe(C_(5)H_(4)Se(CH_(2))_(9)CH=CH_(2))_(2)Pt Cl_(2)is free because of binding with Pt(Ⅱ).The results obtained from^(1)H,^(13)C and^(77)Se NMR indicate that invertomers of meso and dl species existence.The ratio of meso/dl for BUnSeF Pt is ca 70/30,whereas four and three invertomers for BUnSeF Pt and BBSeFPd have been clearly observed from 1H NMR spectra.