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基于低共熔溶剂前端聚合制备大孔水凝胶及其溶胀和吸附性能 被引量:2
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作者 陈亚鹏 晏石林 +1 位作者 李胜方 邹涛 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第9期141-148,共8页
以丙烯酸(AAc)、丙烯酰胺(AM)为氢键供体(HBD),氯化胆碱(ChCl)为氢键受体(HBA),按一定比例加热合成可聚合低共熔溶剂(DES),进而以DES为反应性绿色溶剂,将DES通过前端聚合(FP)制备大孔聚(丙烯酸-co-丙烯酰胺)(P(AAc-co-AM))水凝胶。采用... 以丙烯酸(AAc)、丙烯酰胺(AM)为氢键供体(HBD),氯化胆碱(ChCl)为氢键受体(HBA),按一定比例加热合成可聚合低共熔溶剂(DES),进而以DES为反应性绿色溶剂,将DES通过前端聚合(FP)制备大孔聚(丙烯酸-co-丙烯酰胺)(P(AAc-co-AM))水凝胶。采用红外光谱和扫描电镜对水凝胶的结构进行表征,并研究了大孔水凝胶的溶胀动力学、pH敏感性以及对亚甲基蓝(MB)的吸附性能。结果表明,DES聚合后经水洗、冷冻干燥可制得大孔水凝胶。制备的水凝胶具有pH敏感性,其水溶胀遵循non-Fickian扩散机制。大孔水凝胶对MB有良好的吸附去除能力,其平衡吸附量随pH值增大而增大,当pH=12时,大孔水凝胶对MB的平衡吸附量为64mg/g,去除率达85.07%。 展开更多
关键词 低共熔溶剂 大孔水凝胶 溶胀 吸附
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Response of the accumulation of proline in the bodies of Populus euphratica to the change of groundwater level at the lower reaches of Tarim River 被引量:31
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作者 Yaning chen yapeng chen +1 位作者 Weihong Li Hongfeng Zhang 《Chinese Science Bulletin》 SCIE EI CAS 2003年第18期1995-1999,共4页
The content of proline in the plant bodies is closely related to the converse-succession-resistant capability of the plants. In this paper, the relationship between the proline accumulation in the bodies of Populus eu... The content of proline in the plant bodies is closely related to the converse-succession-resistant capability of the plants. In this paper, the relationship between the proline accumulation in the bodies of Populus euphratica and the change of groundwater level is analyzed by taking Popu-lus euphratica, the main community-building species of the desert riparian forests along the Tarim River, as the research object. The research results show that the accumulation of proline in the bodies of Populus euphratica is closely related to the change of groundwater level gradient under drought stress, it increases with the drawdown of groundwater level and the increase of moisture stress degree; the accumulation of proline in the bodies of Populus euphratica has two ex-tremely high points at the groundwater depth ranges of 3.64—5.14 m and 9.46—10.16 m. Combining the field investiga-tion and the analysis of the plots, it is considered that the groundwater level of 3.5—4.5 m is rational for the growth of Populus euphratica. The stress groundwater depth for the normal growth and the critical one for the survival of Popu-lus euphratica are below 4.5 m and 9—10 m respectively at the lower reaches of the Tarim River. 展开更多
关键词 POPULUS EUPHRATICA PROLINE groundwater level DROUGHT stress TARIM River.
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Enhanced tribological properties of aligned graphene-epoxy composites 被引量:2
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作者 Yuefeng DU Zhenyu ZHANG +8 位作者 Dong WANG Lezhen ZHANG Junfeng CUI yapeng chen Mingliang WU Ruiyang KANG Yunxiang LU Jinhong YU Nan JIANG 《Friction》 SCIE EI CAS CSCD 2022年第6期854-865,共12页
The random distribution of graphene in epoxy matrix hinders the further applications of grapheneepoxy composites in the field of tribology.Hence,in order to fully utilize the anisotropic properties of graphene,highly ... The random distribution of graphene in epoxy matrix hinders the further applications of grapheneepoxy composites in the field of tribology.Hence,in order to fully utilize the anisotropic properties of graphene,highly aligned graphene-epoxy composites(AGEC)with horizontally oriented structure have been fabricated via an improved vacuum filtration freeze-drying method.The frictional tests results indicated that the wear rate of AGEC slowly increased from 5.19x10^(-6)mm^(3)/(N-m)to 2.87x10^(-5)mm^(3)/(N-m)with the increasing of the normal load from 2 to 10 N,whereas the friction coefficient(COF)remained a constant of 0.109.Compared to the neat epoxy and random graphene-epoxy composites(RGEC),the COF of AGEC was reduced by 87.5%and 71.2%,and the reduction of wear rate was 86.6%and 85.4%at most,respectively.Scanning electron microscope(SEM)observations illustrated that a compact graphene self-lubricant film was formed on the worn surface of AGEC,which enables AGEC to possess excellent tribological performance.Finally,in light of the excellent tribological properties of AGEC,this study highlights a pathway to expand the tribological applications of graphene-epoxy composites. 展开更多
关键词 GRAPHENE ALIGNED epoxy composite tribological performance
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