The excited-state intramolecular proton transfer molecules based on chalcone （E）-3-（4＇-dimethylami- nophenyl）-l-（4＇-fluoro-2＇-hydroxyphenyl）-2-propen-l-one （DMF-HPPO） have been synthesized under microwave i...The excited-state intramolecular proton transfer molecules based on chalcone （E）-3-（4＇-dimethylami- nophenyl）-l-（4＇-fluoro-2＇-hydroxyphenyl）-2-propen-l-one （DMF-HPPO） have been synthesized under microwave irradiation. One-dimensional （1D） microwires and 2D microdisks of DMF-HPPO have been selectively prepared by controlling the solution polarity. XRD results revealed the two microcrystals exhibit distinct diffraction patterns, which indicates that they have belonged to different crystalline nature. The microcrystals demonstrate shape-dependent amplified spontaneous emissions （ASE） that the emission of ID microwire is central around 618 nm and the 2D microdisk emits fluorescence at 650 nm. This result reveals the controlled synthesis of two microcrystals and their consequent multicolor amplified spontaneous emission, providing considerable promise for the development and application of new opto-electronic devices.展开更多
基金supported by National Natural Science Foundation of China(No. 21603008)Beijing Municipal Education Committee(No. SQKM201610012006)Research Project of Talent Introduction Foundation of Beijing Institute of Fashion Technology(No. 2015A-16)
文摘The excited-state intramolecular proton transfer molecules based on chalcone （E）-3-（4＇-dimethylami- nophenyl）-l-（4＇-fluoro-2＇-hydroxyphenyl）-2-propen-l-one （DMF-HPPO） have been synthesized under microwave irradiation. One-dimensional （1D） microwires and 2D microdisks of DMF-HPPO have been selectively prepared by controlling the solution polarity. XRD results revealed the two microcrystals exhibit distinct diffraction patterns, which indicates that they have belonged to different crystalline nature. The microcrystals demonstrate shape-dependent amplified spontaneous emissions （ASE） that the emission of ID microwire is central around 618 nm and the 2D microdisk emits fluorescence at 650 nm. This result reveals the controlled synthesis of two microcrystals and their consequent multicolor amplified spontaneous emission, providing considerable promise for the development and application of new opto-electronic devices.
