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Influences of pore fluid on gas production from hydrate-bearing reservoir by depressurization
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作者 yi-fei sun Bo-Jian Cao +6 位作者 Hong-Nan Chen Yin-Long Liu Jin-Rong Zhong Liang-Liang Ren Guang-Jin Chen Chang-Yu sun Dao-Yi Chen 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1238-1246,共9页
In addition to the temperature and pressure conditions,the pore fluid composition and migration behavior are also crucial to control hydrate decomposition in the exploitation process.In this work,to investigate the ef... In addition to the temperature and pressure conditions,the pore fluid composition and migration behavior are also crucial to control hydrate decomposition in the exploitation process.In this work,to investigate the effects of these factors,a series of depressurization experiments were carried out in a visible one-dimensional reactor,using hydrate reservoir samples with water saturations ranging from 20%to 65%.The results showed a linear relationship between gas production rates and gas saturations of the reservoir,suggesting that a larger gas-phase space was conducive to hydrate decomposition and gas outflow.Therefore,the rapid water production in the early stage of hydrate exploitation could release more gas-phase space in the water-rich reservoir,which in turn improved the gas production efficiency.Meanwhile,the spatiotemporal evolution of pore fluids could lead to partial accelerated decomposition or secondary formation of hydrates.In the unsealed reservoir,the peripheral water infiltration kept reservoir at a high water saturation,which hindered the overall production process and caused higher water production.Importantly,depressurization assisted with the N2 sweep could displace the pore water rapidly.According to the results,it is recommended that using the short-term N2 sweep as an auxiliary means in the early stage of depressurization to expand the gas-phase space in order to achieve the highest production efficiency. 展开更多
关键词 CH4 hydrate Water saturation DEPRESSURIZATION Gas-phase space N2 sweep
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多孔陶瓷支撑型管式固体氧化物电解池性能研究
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作者 汪恒吉 陈文国 +4 位作者 全周益 赵凯 孙毅飞 陈旻 奥坚科·弗拉基米尔 《电化学(中英文)》 CAS 北大核心 2023年第12期24-30,共7页
固体氧化物电解池是一种新型能源转换技术,能实现间歇式能源到氢能的高效转化,为能源的有效利用提供了新途径。本文针对固体氧化物电解池金属镍基阴极支撑体在电解过程中的局部氧化以及由此引发的电池结构稳定性问题,提出了一种多孔氧... 固体氧化物电解池是一种新型能源转换技术,能实现间歇式能源到氢能的高效转化,为能源的有效利用提供了新途径。本文针对固体氧化物电解池金属镍基阴极支撑体在电解过程中的局部氧化以及由此引发的电池结构稳定性问题,提出了一种多孔氧化钇稳定的二氧化锆(YSZ)支撑型管式固体氧化物电解池,其构型为多孔YSZ支撑体/Ni-YSZ燃料极电流收集层/Ni-YSZ燃料极电化学催化层/YSZ/Ce_(0.8)Sm_(0.2)O_(1.9)双层电解质层以及La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)空气电极,研究了造孔剂(聚甲基丙烯酸甲酯,PMMA)的含量对多孔YSZ支撑体的孔隙率、孔径分布和支撑体机械强度的影响,考察了电解池在H_(2)O-H_(2)气氛中的电化学电解性能。研究结果表明,当PMMA含量为25wt.%时,电解池具有最优的综合力学性能和电解催化活性,在750°C的工作温度下,电解池的产氢气速率为3 mL•min^(–1)•cm^(–2),电解池在10次升降温热循环过程中电解性能衰减为~5%,表现出优良的电解稳定性。本研究结果验证了多孔YSZ支撑型管式电解池的应用可行性。 展开更多
关键词 固体氧化物电解池 多孔陶瓷支撑体 管式电解池 电化学电解
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Formulation of cross-anisotropic failure criterion for soils
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作者 yi-fei sun Han-long LIU +1 位作者 Gui YANG Yang XIAO 《Water Science and Engineering》 EI CAS CSCD 2013年第4期456-468,共13页
Inherently anisotropic soil fabric has a considerable influence on soil strength. To model this kind of inherent anisotropy, a three-dimensional anisotropic failure criterion was proposed, employing a scalar-valued an... Inherently anisotropic soil fabric has a considerable influence on soil strength. To model this kind of inherent anisotropy, a three-dimensional anisotropic failure criterion was proposed, employing a scalar-valued anisotropic variable and a modified general three- dimensional isotropic failure criterion. The scalar-valued anisotropic variable in all sectors of the deviatoric plane was defined by correlating a normalized stress tensor with a normalized fabric tensor. Detailed comparison between the available experimental data and the corresponding model predictions in the deviatoric plane was conducted. The proposed failure criterion was shown to well predict the failure behavior in all sectors, especially in sector II with the Lode angle ranging between 60° and 120°, where the prediction was almost in accordance with test data. However, it was also observed that the proposed criterion overestimated the strength of dense Santa Monica Beach sand in sector III where the intermediate principal stress ratio b varied from approximately 0.2 to 0.8, and slightly underestimated the strength when b was between approximately 0.8 and 1. The difference between the model predictions and experimental data was due to the occurrence of shear bending, which might reduce the measured strength. Therefore, the proposed anisotropic failure criterion has a strong ability to characterize the failure behavior of various soils and potentially allows a better description of the influence of the loading direction with respect to the soil fabric. 展开更多
关键词 eross-anisotropy soil fabric failure criterion triaxial test torsional shear test
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Detection performance improvement of photon counting chirped amplitude modulation lidar with response probability correction
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作者 孙怿飞 张子静 +2 位作者 赵丽媛 孙伟民 赵远 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第9期322-326,共5页
Geiger mode avalanche photodiode detector (Gm-APD) possesses the ultra-high sensitivity. Photon counting chirped amplitude modulation (PCCAM) light detection and ranging (lidar) uses the counting results of the ... Geiger mode avalanche photodiode detector (Gm-APD) possesses the ultra-high sensitivity. Photon counting chirped amplitude modulation (PCCAM) light detection and ranging (lidar) uses the counting results of the returned signal detected by Gm-APD to mix with the reference signal, which makes PCCAM lidar capable of realizing the ultra-high sensitivity, and this is very important for detecting the remote and weak signal. However, Gm-APD is a nonlinear device, different from traditional linear detectors. Due to the nonlinear response of Gm-APD, the counting results of the returned signal detected by Gm-APD are different from those of both the original modulation signal and the reference signal. This will affect the mixing effect and thus degrade the detection performance of PCCAM lidar. In this paper, we propose a response probability correction method. First, the response probability correction model is established on the basis of Gm-APD Poisson prob- ability response model. Then, the response probability correction model is used to adjust the original modulation signal that is used to drive laser, in order to make the counting results of the returned signal detected by Gm-APD better mix with the local reference signal in the same form. Through this method, the detection performance of PCCAM lidar is enhanced efficiently. 展开更多
关键词 photon counting CHIRPING LIDAR
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