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Delocalizedπ_(3)^(6) Bond in OX_(2) (X=Halogen) Molecules
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作者 yi-han tang Pu Yang +3 位作者 Meng-yuan Chen Yu-ru Wang Jia-xin Wang Jia-wei Xu 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2022年第3期542-550,I0003,共10页
OX_(2)(X=halogen)molecules was studied theoretically.Calculation results show that delocalizedπ_(3)^(6) bonds exist in their electronic structures and O atoms adopt the sp^(2) type of hybridization,which violates the... OX_(2)(X=halogen)molecules was studied theoretically.Calculation results show that delocalizedπ_(3)^(6) bonds exist in their electronic structures and O atoms adopt the sp^(2) type of hybridization,which violates the prediction of the valence shell electron pair repulsion theory of sp^(3) type.Delocalization stabilization energy is proposed to measure the contribution of delocalizedπ_(3)^(6) bond to energy decrease and proves to bring extra-stability to the molecule.These phenomena can be summarized as a kind of coordinating effect. 展开更多
关键词 Theoretical and computational chemistry Valence shell electron pair repulsion theory Delocalizedπbond Delocalization stabilization energy Dihalogen monoxide
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Rules of acupoint and meridian selection in acupuncture-moxibustion for stable angina pectoris 被引量:4
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作者 yi-han tang Lan-bo FEI +2 位作者 Jie DENG Song WU Wei HUANG 《World Journal of Acupuncture-Moxibustion》 CSCD 2018年第2期39-43,83,共6页
To summarize and analyze the acupoint selection rules in acupuncture-moxibustion for stable angina pectoris. Clinical studies and literature on acupuncture-moxibustion for stable angina pectoris with definite acupoint... To summarize and analyze the acupoint selection rules in acupuncture-moxibustion for stable angina pectoris. Clinical studies and literature on acupuncture-moxibustion for stable angina pectoris with definite acupoint selection were included through retrieving China National Knowledge Infrastructure(CNKI),Wanfang Database and VIP in order to analyze the characteristics and rules of acupoint selection in acupuncture-moxibustion treatment for stable angina pectoris. It has been found that the acupoint selection of acupuncture-moxibustion prescriptions for stable angina pectoris focused on specific acupoints.The top 5 acupoints with the highest using frequency included Neiguan(内关PC 6),Danzhdng(膻中CV17),Xinshu(心俞BL 15),Ziusanli(足三里ST 36) and Sanyinjiao(三阴交SP 6). Acupuncture-moxibustion treatment of stable angina pectoris involved 12 meridians, mainly including the hand-jueyin pericardium meridian, the foot-taiyang bladder meridian, conception vessel, the foot-yangming stomach meridian, the foot-taiyin spleen meridian, and the hand-shaoyin heart meridian, etc., embodying the characteristics and rules of acupoint selection such as "highlighting the special treatment effect of acupoints" "selecting acupoints along the pericardium meridian, bladder meridian and conception vessel, combining the anterior and the posterior acupoints", "selecting the distal acupoints of spleen and stomach meridians, and focusing on specific acupoints", etc. 展开更多
关键词 Stable angina pectoris ACUPUNCTURE-MOXIBUSTION Acupoint selection characteristics
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