lonic liquids with stimuli-responsive characteristics are an essential branch in the comprehensive ionic liquids'family,which can meet the controllable and reversible needs in practical applications with different...lonic liquids with stimuli-responsive characteristics are an essential branch in the comprehensive ionic liquids'family,which can meet the controllable and reversible needs in practical applications with different stimulation means.In this review,we summarize the recent research progress of these stimuli-responsive ionic liquids,mainly focusing on their chemical structures,properties,responsive mechanism,aggregation structures,and phase behaviors,which were driven by external stimuli,such as CO2,magnetism,light,temperature,redox,and pH.Then,the particular or potential applications of stimuli-responsive ionic liquids are expounded in various fields of science,including catalytic reaction,extraction,separation,nano-material preparation,and gas absorption.In the end,the challenges and strategies of the subject are briefly presented.It is expected that this review will contribute to the rational design and applications of stimu-liresponsive ionic liquids in the future.展开更多
基金the Na-tional Natural Science Foundation of China(Nos.21922813,21776278,and 21736003)the Beijing Natural Science Foundation(2182068)+1 种基金DNL Cooperation Fund,CAS(DNL180202)Youth Innovation Promotion Association,CAS(2017066)。
文摘lonic liquids with stimuli-responsive characteristics are an essential branch in the comprehensive ionic liquids'family,which can meet the controllable and reversible needs in practical applications with different stimulation means.In this review,we summarize the recent research progress of these stimuli-responsive ionic liquids,mainly focusing on their chemical structures,properties,responsive mechanism,aggregation structures,and phase behaviors,which were driven by external stimuli,such as CO2,magnetism,light,temperature,redox,and pH.Then,the particular or potential applications of stimuli-responsive ionic liquids are expounded in various fields of science,including catalytic reaction,extraction,separation,nano-material preparation,and gas absorption.In the end,the challenges and strategies of the subject are briefly presented.It is expected that this review will contribute to the rational design and applications of stimu-liresponsive ionic liquids in the future.
