Increasing the phonon scattering center by adding nanoparticles to thermoelectric materials is an effective method of regulating the thermal conductivity.In this study,a series of Ca3 Co_(4)O_(9)/x wt.%CNTs(x=0,3,5,7,...Increasing the phonon scattering center by adding nanoparticles to thermoelectric materials is an effective method of regulating the thermal conductivity.In this study,a series of Ca3 Co_(4)O_(9)/x wt.%CNTs(x=0,3,5,7,10)polycrystalline ceramic thermoelectric materials by adding carbon nanotubes(CNTs)were prepared with sol-gel method and cold-pressing sintering technology.The results of x-ray diffraction and field emission scanning electron microscopy show that the materials have a single-phase structure with high orientation and sheet like microstructure.The effect of adding carbon nanotubes to the thermoelectric properties of Ca_(3)Co_(4)O_(9)was systematically measured.The test results of thermoelectric properties show that the addition of carbon nanotubes reduces the electrical conductivity and Seebeck coefficient of the material.Nevertheless,the thermal conductivity of the samples with carbon nanotubes addition is lower than that of the samples without carbon nanotubes.At 625 K,the thermal conductivity of Ca3 Co_(4)O_(9)/10 wt.%CNTs sample is reduced to0.408 W·m^(-1)·K^(-1),which is about 73%lower than that of the original sample.When the three parameters are coupled,the figure of merit of Ca_(3)Co_(4)O_(9)/3 wt.%CNTs sample reaches 0.052,which is 29%higher than that of the original sample.This shows that an appropriate amount of carbon nanotubes addition can reduce the thermal conductivity of Ca_(3)Co_(4)O_(9)ceramic samples and improve their thermoelectric properties.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51836009)。
文摘Increasing the phonon scattering center by adding nanoparticles to thermoelectric materials is an effective method of regulating the thermal conductivity.In this study,a series of Ca3 Co_(4)O_(9)/x wt.%CNTs(x=0,3,5,7,10)polycrystalline ceramic thermoelectric materials by adding carbon nanotubes(CNTs)were prepared with sol-gel method and cold-pressing sintering technology.The results of x-ray diffraction and field emission scanning electron microscopy show that the materials have a single-phase structure with high orientation and sheet like microstructure.The effect of adding carbon nanotubes to the thermoelectric properties of Ca_(3)Co_(4)O_(9)was systematically measured.The test results of thermoelectric properties show that the addition of carbon nanotubes reduces the electrical conductivity and Seebeck coefficient of the material.Nevertheless,the thermal conductivity of the samples with carbon nanotubes addition is lower than that of the samples without carbon nanotubes.At 625 K,the thermal conductivity of Ca3 Co_(4)O_(9)/10 wt.%CNTs sample is reduced to0.408 W·m^(-1)·K^(-1),which is about 73%lower than that of the original sample.When the three parameters are coupled,the figure of merit of Ca_(3)Co_(4)O_(9)/3 wt.%CNTs sample reaches 0.052,which is 29%higher than that of the original sample.This shows that an appropriate amount of carbon nanotubes addition can reduce the thermal conductivity of Ca_(3)Co_(4)O_(9)ceramic samples and improve their thermoelectric properties.
