Fluorinated polymers are important materials that are widely used in many areas as taking the advantage of inertness to chemical corrosion,prominent weather resista nee,low flammability,and good thermal stability.Poly...Fluorinated polymers are important materials that are widely used in many areas as taking the advantage of inertness to chemical corrosion,prominent weather resista nee,low flammability,and good thermal stability.Poly(vinylidene fluoride)(PVDF)based fluoropolymers is the most commontype of commercial fluoropolymer especially used as dielectric materials.However,there are always some shortcomings in practical applications,so it is necessary to modify PVDF-based fluoropolymers for better application.Controlled/living radical polymerization(CRP)and related techniques have become a powerful approach to tailoring the chemical and physical properties of materials and have given rise to great advances in modification of PVDF-based fluoropolymers.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(Nos.92066204,52003214,51773166 and 51603167)China Postdoctoral Science Foundation Funded Project(Nos.2019M663699 and 2020T130507)+3 种基金Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology(No.201805056ZD7CG40)Natural Science Foundation of Jiangsu Province(No.BK2020245)Suzhou Science and Technology Project(No.SYG202028)the Fundamental Research Funds for the Central Universities(No.xzy012020035).
文摘Fluorinated polymers are important materials that are widely used in many areas as taking the advantage of inertness to chemical corrosion,prominent weather resista nee,low flammability,and good thermal stability.Poly(vinylidene fluoride)(PVDF)based fluoropolymers is the most commontype of commercial fluoropolymer especially used as dielectric materials.However,there are always some shortcomings in practical applications,so it is necessary to modify PVDF-based fluoropolymers for better application.Controlled/living radical polymerization(CRP)and related techniques have become a powerful approach to tailoring the chemical and physical properties of materials and have given rise to great advances in modification of PVDF-based fluoropolymers.