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氧化钨和磷钨酸对LiNi_(0.96)Co_(0.02)Mn_(0.02)O_(2)材料的表面包覆改性研究
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作者 赵刚 龚正良 +1 位作者 李益孝 杨勇 《电化学(中英文)》 CAS 北大核心 2023年第10期29-36,共8页
随着电动汽车的高速发展,对锂离子电池的能量密度、循环性能和成本提出了更高的要求,目前已有的高镍材料LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)能量密度可以达到760 Wh·kg^(-1),已成为锂离子正极材料发展的重要方向。超高镍三... 随着电动汽车的高速发展,对锂离子电池的能量密度、循环性能和成本提出了更高的要求,目前已有的高镍材料LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)能量密度可以达到760 Wh·kg^(-1),已成为锂离子正极材料发展的重要方向。超高镍三元正极材料(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.90)具有超过210 mAh·g^(–1)比容量,因而可实现更高的能量密度,但目前关于超高镍材料的研究工作仍然比较少。超高镍正极材料的研究极具实用意义,因此,本文选择LiNi_(0.96)Co_(0.02)Mn_(0.02)O_(2)(NCM96)这一超高镍材料进行研究。为了提升超高镍三元正极材料NCM96的电化学性能,本工作采用了氧化钨和磷钨酸来对其进行包覆改性,并系统研究了材料改性前后的结构、形貌及电化学性能。其中,氧化钨包覆能有效提升三元材料的电化学性能,但目前尚未有利用氧化钨对超高镍正极材料进行包覆改性的报道。此外,磷钨酸是一种可以同时实现氧化钨和磷酸盐双重包覆的物质,双重包覆有望实现比单一元素包覆更优的电化学性能。本工作通过NCM96前驱体与磷钨酸和氧化钨液相共混,烘干后混锂烧结实现氧化钨和磷钨酸包覆。研究结果表明,两种表面改性方法对超高镍三元正极材料首圈放电比容量影响都较小,且能有效改善材料的长期循环性能。对比两种改性材料的高温电化学性能,发现经磷钨酸包覆改性后的材料其高温循环性能优于氧化钨包覆改性,说明磷钨酸的P/W双元素改性优于WO3的W单元素改性。 展开更多
关键词 锂离子电池 超高镍低钴三元正极材料 表面包覆 氧化钨包覆 磷钨酸包覆
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Strategic games on a hierarchical network model 被引量:2
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作者 yi-xiao li Xiao-gang JIN +1 位作者 Fan-sheng KONG Hui-lan LUO 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第2期271-278,共8页
Among complex network models,the hierarchical network model is the one most close to such real networks as world trade web,metabolic network,WWW,actor network,and so on.It has not only the property of power-law degree... Among complex network models,the hierarchical network model is the one most close to such real networks as world trade web,metabolic network,WWW,actor network,and so on.It has not only the property of power-law degree distribution,but also the scaling clustering coefficient property which Barabási-Albert(BA)model does not have.BA model is a model of network growth based on growth and preferential attachment,showing the scale-free degree distribution property.In this paper,we study the evolution of cooperation on a hierarchical network model,adopting the prisoner's dilemma(PD)game and snowdrift game(SG)as metaphors of the interplay between connected nodes.BA model provides a unifying framework for the emergence of cooperation.But interestingly,we found that on hierarchical model,there is no sign of cooperation for PD game,while the fre-quency of cooperation decreases as the common benefit decreases for SG.By comparing the scaling clustering coefficient prop-erties of the hierarchical network model with that of BA model,we found that the former amplifies the effect of hubs.Considering different performances of PD game and SG on complex network,we also found that common benefit leads to cooperation in the evolution.Thus our study may shed light on the emergence of cooperation in both natural and social environments. 展开更多
关键词 Complex network Hierarchical network model Barabási-Albert (BA) model Prisoner's dilemma (PD) game Snowdrift game (SG)
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Fluorinated graphite nanosheets for ultrahigh-capacity lithium primary batteries 被引量:5
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作者 Xiao-Xia Yang Guan-Jun Zhang +5 位作者 Bao-Sheng Bai Yu li yi-xiao li Yong Yang Xian Jian Xi-Wen Wang 《Rare Metals》 CSCD 2021年第7期1708-1718,共11页
For better performances of Ni-based catalysts at low temperatures,Ni/SiC catalyst doped with a little amount of additive La was successfully prepared.The catalytic CO methanation activity tests showed that 3%La-Ni/SiC... For better performances of Ni-based catalysts at low temperatures,Ni/SiC catalyst doped with a little amount of additive La was successfully prepared.The catalytic CO methanation activity tests showed that 3%La-Ni/SiC catalyst was excellent at a low reaction temperature(95.9%CO conversion and 85.1%CH4 selectivity at250℃)with a superior stability compared with Ni/SiC(3.4%CO conversion and 0%CH4 selectivity at 250℃).This can be attributed to that the addition of La can markedly improve the dispersibility of active metal Ni and reduce the particle sizes of Ni nanoparticles or clusters,and can also regulate the interaction between active components and supports.Moreover,the high thermal conductivity and thermal stability could avoid the generation of hot spots in the catalyst bed.These results will promote the development of highly active Ni-based catalysts for the low-temperature methanation reaction. 展开更多
关键词 Graphite nanosheets Carbon fluoride Primary battery ELECTROLYTE Soft pack battery
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AdaPIP: Adaptive picture-in-picture guidance for 360° film watching
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作者 yi-xiao li Guan Luo +3 位作者 Yi-Ke Xu Yu He Fang-Lue Zhang Song-Hai Zhang 《Computational Visual Media》 SCIE EI CSCD 2024年第3期487-503,共17页
360°videos enable viewers to watch freely from different directions but inevitably prevent them from perceiving all the helpful information.To mitigate this problem,picture-in-picture(PIP)guidance was proposed us... 360°videos enable viewers to watch freely from different directions but inevitably prevent them from perceiving all the helpful information.To mitigate this problem,picture-in-picture(PIP)guidance was proposed using preview windows to show regions of interest(ROIs)outside the current view range.We identify several drawbacks of this representation and propose a new method for 360° film watching called AdaPIP.AdaPIP enhances traditional PIP by adaptively arranging preview windows with changeable view ranges and sizes.In addition,AdaPIP incorporates the advantage of arrow-based guidance by presenting circular windows with arrows attached to them to help users locate the corresponding ROIs more efficiently.We also adapted AdaPIP and Outside-In to HMD-based immersive virtual reality environments to demonstrate the usability of PIP-guided approaches beyond 2D screens.Comprehensive user experiments on 2D screens,as well as in VR environments,indicate that AdaPIP is superior to alternative methods in terms of visual experiences while maintaining a comparable degree of immersion. 展开更多
关键词 360°videos picture-in-picture(PIP) virtual reality(VR) visual guidance
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